LESSON XVIII

MINERAL SPECIES TO WHICH THE VARIOUS GEMS BELONG AND THE CHEMICAL COMPOSITION THEREOF

Although we have a very large number of different kinds of precious and semi-precious stones, to judge by the long list of names to be found in books on gems, yet all these stones can be rather simply classified on the basis of their chemical composition, into one or another of a comparatively small number of mineral species. While jewelers seldom make use of a knowledge of the chemistry of the precious stones in identifying them, nevertheless such a knowledge is useful, both by way of information, and because it leads to a better and clearer understanding of the many similarities among stones whose color might lead one to regard them as dissimilar.

Mineral Species. We must first consider what is meant by a "mineral species" and find out what relation exists between that subject and chemical composition. Now by a "mineral species" is understood a single substance, having (except for mechanically admixed impurities) practically a constant chemical composition, and having practically identical physical properties in all specimens of it.

Diamond and Corundum. A chemist would call a true mineral a pure substance, just as sugar and salt are pure substances to the chemist. Thus diamond is a "mineral species," as is also corundum. There are many different colors of both diamond and corundum, but these different colors are believed to be due to the presence in the pure substance of impurities in small amounts. Thus every diamond consists mainly of pure carbon, and all the corundum gems (ruby and the various colors of sapphire) consist mainly of pure oxide of aluminum. The properties of all diamonds are practically alike and so are the properties of all the corundum gems whether red (ruby), blue (sapphire), yellow (Oriental topaz), green (Oriental emerald), or purple (Oriental amethyst).

Thus all diamonds, of whatever color, belong to the one species, diamond, and in this case the usual custom in naming them agrees with the facts. Similarly all sapphires, of whatever color, belong to the mineral species "corundum." Thus a ruby is a red corundum.

The old French traveler and gem merchant, Tavernier, tells us that in the seventeenth century, when he visited the mines of Pegu, the natives knew of the similarity of the corundum gems and even called all by one name, with other names attached to designate the color. Singularly enough, the common name used by them was ruby rather than sapphire, as now. Thus they called blue corundum gems blue rubies; yellow corundums, yellow rubies, etc.

It is easily seen that if one recognizes the similar nature of all the many colors and shades of corundum that the number of things that one has to remember in order to be well acquainted with these stones is considerably diminished. Thus, instead of having a whole series of specific gravities to remember one has only to remember that all the corundum gems have a specific gravity of approximately 4. Similarly they are all of practically the same refractive index (1.761-1.770, being doubly refracting) that they all exhibit dichroism when at all deeply colored, etc.

Having thus indicated what we mean by mineral species and having illustrated the matter by the cases of diamond and corundum and further having stated that all diamonds are composed of pure carbon (except for traces of impurities) and all corundum gems mainly of oxide of aluminum, we may proceed to consider other mineral species and find out what gems they afford us.

Carbon, the only Element Furnishing a Gem. It will be noted that the first species considered, diamond, consisted of but a single element, carbon. It is thus exceedingly simple in composition, being not only a pure substance but, in addition, an elementary substance. Corundum, the second species considered, was a little more complex, having two elements, aluminum and oxygen, in its make-up, but completely and definitely combined in a new compound that resembles neither aluminum nor oxygen. It is thus a compound substance. No other element than carbon affords any gem-stone when by itself.

Oxides of Metals. There is, however, another oxide, in addition to aluminum oxide, that furnishes gem material. It is silicon oxide, containing the two elements silicon and oxygen. Silicon itself is a dark, gray, crystalline element that seems half metallic, half non-metallic in its properties. It is never found by itself in nature but about twenty-eight per cent. of the crust of the earth is composed of it in compound forms, and one of the most abundant of these is quartz, which is a mineral species, and which contains just silicon and oxygen. That is, it is oxide of silicon. Now quartz is colorless when pure (rock crystal), but it is frequently found colored purple (probably by oxide of manganese) and it is then called amethyst by the jeweler. At other times its color is yellow (due to oxide of iron) and then the jeweler is prone to call it "topaz," although properly speaking that name should, as we shall soon see, be reserved for an entirely different mineral species. Chalcedony too (which when banded furnishes us our agates, and when reddish our carnelian) is a variety of quartz, and prase is only quartz colored green by fibers of actinolite within it.

The common cat's-eye and the tiger's-eye are varieties of quartz enclosing fibrous minerals or replacing them while still keeping the arrangement that they had. "Venus hair stone" is quartz containing needle-like crystals of rutile, and "iris" is quartz that has been crackled within, so as to produce rainbow colors, because of the effects of thin layers of material. Aventurine quartz (sometimes called goldstone) has spangles of mica or of some other mineral enclosed in it. The jaspers are mainly quartz with more of earthy impurity than the preceding stones.

Thus all this long list of stones of differing names can be classified under the one mineral species, quartz. Together they constitute the quartz gems. In properties they are essentially alike, having specific gravity 2.66, hardness 7, slight double refraction, etc., the slight differences that exist being due only to the presence of varying amounts of foreign matter.

Opal. The opal may be considered along with the quartz gems, because, like them, it is composed mainly of oxide of silicon, but the opal also has water combined with the silicon oxide (not merely imprisoned in it). Thus opal is a hydrous form of silica (hydrous comes from the Greek word for water).

Spinel. All our other stones are of more complicated chemical composition than the preceding. Coming now to mineral species which have three chemical elements in them we may consider first spinel, which has the two metallic elements aluminum and magnesium and the non-metallic element oxygen in it. It is virtually a compound of the two oxides, aluminum oxide and magnesium oxide. The variously colored spinels, like the various corundums, all have the same properties, thus they are all of hardness 8 or a little higher, they all have single refraction, and all have specific gravity 3.60.

Chrysoberyl. Another mineral species which, like spinel, has just three elements in its composition is chrysoberyl. This mineral contains the metals aluminum and beryllium combined with the non-metal oxygen. Thus it is really to be regarded as a compound of the two oxides, aluminum oxide and beryllium oxide. This species furnishes us Alexandrite, chrysoberyl cat's-eye and less valuable chrysoberyls of yellowish-green color. All are of the one species, the marked color difference being due to the presence of different impurities. The cat's-eye effect in one of the varieties is due to the internal structure rather than to the nature of the material.

The Silicates. Nearly all of the remaining precious stones belong to a great group of mineral species known as the silicates. These are so called because they consist largely of oxide of silicon (the material above referred to under quartz gems). This oxide of silicon is not free and separate in the silicates but is combined chemically with other oxides, chiefly with metallic oxides. Thus there are many different silicates because, in the earth, many different metallic oxides have combined with silicon oxide. Also in many cases two or three or even more metallic oxides have combined with silicon oxide to make single new compounds.

Glass, a Mixture of Silicates. Those who are familiar with glass making may receive some help at this point by remembering that the various glasses are silicates, for they are made by melting sand (which is nearly pure oxide of silicon) with various metallic oxides. With lime (calcium oxide) and soda (which yields sodium oxide) we get soda-lime glass (common window glass). Lead oxide being added to the mixture a dense, very brilliant, but soft glass (flint glass) results. Cut glass dishes and "paste" gems are made of this flint glass. Now the glasses, although they are silicates, are not crystalline, but rather they are amorphous, that is, without any definite structure. Nature's silicates, on the other hand, are usually crystallized or at least crystalline in structure. (In a few cases we find true glasses, volcanic glass, or obsidian, for example.)

Having thus introduced the silicates we may now consider which ones among the many mineral silicates furnish us with precious or semi-precious stones.

Beryl, Emerald, and Aquamarine. First in value among the silicates is beryl, which, when grass green, we call emerald. The aquamarine and golden beryl too belong to this same species. Beryl is a silicate of aluminum and beryllium. That is, it is a compound in which oxide of silicon is united with the oxides of aluminum and of beryllium. There are thus four chemical elements combined in the one substance and it is hence more complicated in its composition than any of the gems that we have yet considered. It is worthy of note that aluminum occurs in the majority of precious stones, the only species so far considered that lack it being diamond, and the quartz gems.

Perhaps the silicates that are next in importance to the jeweler, after beryl, are those which form the garnets of various types. There are four principal varieties of garnet (although specimens of garnet frequently show a crossing or blending of the types).

Garnets. The types are (1) Almandite garnet; (2) Pyrope garnet; (3) Hessonite garnet; and (4) Andradite garnet. These are all silicates, the almandite garnets being silicates of iron and aluminum; the pyrope garnets are silicates of magnesium and aluminum; the hessonite garnets, silicates of calcium and aluminum, and the andradite garnets, silicates of calcium and iron.

The so-called almandine garnets of the jeweler are frequently of the almandite class and tend to purplish red. The pyrope garnets are, as the name literally implies, of fire red color, as a rule, but they also may be purplish in color. The hessonite garnets are frequently brownish red and are sometimes called "cinnamon stones." The andradite garnets furnish the brilliant, nearly emerald green demantoids (so often called "olivine" by the trade).

Thus all the garnets are silicates and yet we have these four principal mineral species, which, however, are more closely related to each other in crystal form, in character of composition and in general properties, than is usual among the other silicates. Specimens which have any one of the four types of composition unblended with any of the other types would be found to be exactly alike in properties. As was suggested above, however, there is a great tendency to blend and this is well illustrated by the magnificent rhodolite garnets, of rhododendron hue which were found in Macon County, North Carolina. These had a composition between almandite and pyrope, that is, they had both magnesium and iron with aluminum and silica.

The true topaz next calls for consideration as it too is a silicate. The metallic part consists of aluminum, and there are present also the non-metals fluorine and hydrogen. Here we have five elements in the one substance. Various specimens of this species may be wine yellow, light blue, or bluish green, pink or colorless, yet they all have essentially the same properties.

Tourmaline is about as complicated a mineral as we have. It is a very complex silicate, containing aluminum, magnesium, sodium (or other alkali metal, as, for example, lithium), iron, boron, and hydrogen. As Ruskin says of it in his The Ethics of the Dust, when Mary asks "and what is it made of?" "A little of everything; there's always flint (silica) and clay (alumina) and magnesia in it and the black is iron, according to its fancy; and there's boracic acid, if you know what that is: and if you don't, I cannot tell you to-day and it doesn't signify; and there's potash and soda; and on the whole, the chemistry of it is more like a mediæval doctor's prescription, than the making of a respectable mineral." The various tourmalines very closely resemble each other in their properties, the slight differences corresponding to differences in composition do not alter the general nature of the material.

Moonstone belongs to a species of mineral known as feldspar. The particular feldspar that furnishes most of the moonstone is orthoclase, a silicate of potassium and aluminum. Another feldspar sometimes seen as a semi-precious stone is Labradorite. Amazonite, also, is a feldspar. Sunstone is a feldspar which includes tiny flakes or spangles of some other mineral.

The mineral species olivine gives us peridot. It is a silicate of magnesium.

Zircon is itself a species of mineral and is a silicate of zirconium. The names hyacinth, jacinth, and jargoon are applied to red, yellow, and colorless zircon in the order as given.

Jade may be of any of several different species of minerals, all of which are very tough. The principal jades belong, however, to one or the other of two species, jadeite and nephrite. Jadeite is a sodium aluminum silicate and nephrite, a calcium magnesium silicate.

Leaving the silicates we find very few gem minerals remaining. The phosphates furnish us turquoise, a hydrous aluminum phosphate, with copper and iron. Variscite is also a phosphate (a hydrated aluminum phosphate).

The carbonates give us malachite and azurite, both carbonates of copper with combined water, the malachite having more water.