IMPROVEMENTS IN THE MANUFACTURE OF PORTLAND CEMENT.1

IMPROVEMENTS IN THE MANUFACTURE OF PORTLAND CEMENT.¹

By FREDERICK RANSOMS, A.I.C.E.

So much has been said and written on and in relation to Portland cement that further communications upon the subject may appear to many of the present company to be superfluous. But is this really so? The author thinks not, and he hopes by the following communication, to place before this meeting and the community at large some facts which have up to the present time, or until within a very recent date, been practically disregarded or overlooked in the production of this very important and valuable material, so essential in carrying out the great and important works of the present day, whether of docks and harbors, our coast defenses, or our more numerous operations on land, including the construction of our railways, tunnels, and bridges, aqueducts, viaducts, foundations, etc. The author does not propose to occupy the time of this meeting by referring to the origin or the circumstances attendant upon the early history of this material, the manufacture of which has now assumed such gigantic proportions—these matters have already been fully dealt with by other more competent authorities; but rather to direct the attention of those interested therein to certain modifications, which he considers improvements, by means of which a large proportion of capital unnecessarily involved in its manufacture may be set free in the future, the method of manufacture simplified, the cost of manipulation reduced, and stronger and more uniformly reliable cement be placed within the reach of those upon whom devolves the duty and responsibility of constructing works of a substantial and permanent character; but in order to do this it will be necessary to allude to certain palpable errors and defects which, in the author's opinion, are perpetuated, and are in general practice at the present day.

Portland cement is, as is well known, composed of a mixture of chalk, or other carbonate of lime, and clay—such as is obtained on the banks of the Thames or the Medway—intimately mixed and then subjected to heat in a kiln, producing incipient fusion, and thereby forming a chemical combination of lime with silica and alumina, or practically of lime with dehydrated clay. In order to effect this, the usual method is to place the mechanically mixed chalk and clay (technically called slurry), in lumps varying in size, say, from 4 to 10 lb., in kilns with alternate layers of coke, and raise the mass to a glowing heat sufficient to effect the required combination, in the form of very hard clinker. These kilns differ in capacity, but perhaps a fair average size would be capable of producing about 30 tons of clinker, requiring for the operation, say, from 60 to 70 tons of dried slurry, with from 12 to 15 tons of coke or other fuel. The kiln, after being thus loaded, is lighted by means of wood and shavings at the base, and, as a matter of course, the lumps of slurry at the lower part of the kiln are burned first, but the moisture and sulphurous gases liberated by the heat are condensed by the cooler layers above, and remain until the heat from combustion, gradually ascending, raises the temperature to a sufficient degree to drive them further upward, until at length they escape at the top of the kiln. The time occupied in loading, burning, and drawing a kiln of 30 tons of clinker averages about seven days. It will be readily understood that the outside of the clinker so produced must have been subjected to a much greater amount of heat then was necessary, before the center of such clinker could have received sufficient to have produced the incipient fusion necessary to effect the chemical combination of its ingredients; and the result is not only a considerable waste of heat, but, as always occurs, the clinker is not uniformly burnt, a portion of the outer part has to be discarded as overburnt and useless, while the inner part is not sufficiently burnt, and has to be reburned afterward. Moreover, the clinker, which is of excessively hard character, has to be reduced by means of a crusher to particles sufficiently small to be admitted by the millstones, where it is ground into a fine powder, and becomes the Portland cement of commerce.

This process of manufacture is almost identical in principle and in practice with that described and patented by Mr. Joseph Aspden in the year 1824; and though various methods have been patented for utilizing the waste heat of the kilns in drying the slurry previous to calcination, still the main feature of burning the material in mass in large and expensive kilns remained the same, and is continued in practice to the present day. The attention of the author was directed to this subject some time since in consequence of the failure of a structure in which Portland cement formed an essential element, and he had not proceeded far in his investigation of the cause of the failure when he was struck with what appeared to him to be the unscientific method adopted in its manufacture, and the uncertain results that must necessarily accrue therefrom. Admitting, in the first place, that the materials employed were considered the best and most economical for the purpose readily accessible, viz., chalk and an alluvial deposit found in abundance on the banks of the Thames and the Medway, and being intimately mixed together in suitable proportions, was it necessary, in order to effect the chemical combination of the ingredients at an intense heat, to employ such massive and expensive structures of masonry, occupying such an enormous space of valuable ground, with tall chimney stacks for the purpose of discharging the objectionable gases, etc., at such a height, in order to reduce the nuisance to the surrounding neighborhood? Again, was it possible to effect the perfect calcination of the interior of the lumps alluded to without bestowing upon the outer portions a greater heat than was necessary for the purpose, causing a wasteful expenditure of both time and fuel? And further, as cement is required to be used in the state of powder, could not the mixture of the raw materials be calcined in powder, thereby avoiding the production of such a hard clinker, which has afterward to be broken up and reduced to a fine powder by grinding in an ordinary mill?

The foregoing are some of the defects which the author applied himself to remove, and he now desires to draw attention to the way in which the object has been attained by the substitution of a revolving furnace for the massive cement kilns now in general use, and by the application of gaseous products to effect calcination, in the place of coke or other solid fuel. The revolving furnace consists of a cylindrical casing of steel or boiler plate supported upon steel rollers (and rotated by means of a worm and wheel, driven by a pulley upon the shaft carrying the worm), lined with good refractory fire brick, so arranged that certain courses are set so as to form three or more radial projecting fins or ledges. The cylindrical casing is provided with two circular rails or pathways, turned perfectly true, to revolve upon the steel rollers, mounted on suitable brickwork, with regenerative flues, by passing through which the gas and air severally become heated, before they meet in the combustion chamber, at the mouth of the revolving furnace. The gas may be supplied from slack coal or other hydrocarbon burnt in any suitable gas producer (such, for instance, as those for which patents have been obtained by Messrs. Brook & Wilson, of Middlesbrough, or by Mr. Thwaite, of Liverpool), which producer may be placed in any convenient situation.

The cement mixture or slurry, instead of being burnt in lumps, is passed between rollers or any suitable mill, when, it readily falls into coarse dry powder, which powder is thence conveyed by an elevator and fed into the revolving furnace by means of a hopper and pipe, which, being set at an angle with the horizon, as it turns gradually conveys the cement material in a tortuous path toward the lower and hotter end, where it is discharged properly calcined. The material having been fed into the upper end of the cylinder falls through the flame to the lower side of it; the cylinder being in motion lifts it on its advancing side, where it rests against one of its projecting fins or ledges until it has reached such an angle that it shoots off in a shower through the flame and falls once more on the lower side. This again causes it to travel in a similar path, and every rotation of the cylinder produces a like effect, so that by the time it arrives at the lower and hotter end it has pursued a roughly helical path, during which it has been constantly lifted and shot through the flame, occupying about half an hour in its transit.

To some who have been accustomed to the more tedious process of kiln burning, the time thus occupied may appear insufficient to effect the combinations necessary to produce the required result; but it will be seen that the conditions here attained are, in fact, those best suited to carry out effectively the chemical changes necessary for the production of cement. The raw material being in powder offers every facility for the speedy liberation of water and carbonic acid, the operation being greatly hastened by the velocity of the furnace gases through which the particles pass. That such is practically the case is shown by the following analysis of cement so burnt in the revolving furnace or cylinder:

Per cent.

Carbonic acid, anhydrous

Sulphuric acid, anhydrous0.26

Silica soluble24.68

Silica insoluble

Alumina and oxide of iron10.56

Lime61.48

Magnesia, water, and alkalies2.02

———

Again, fineness of the particles results in their being speedily heated to a uniform temperature, so that they do not serve as nuclei for the condensation of the moisture existing in the furnace gas. The calcined material, on reaching the lower end of the furnace, is discharged on to the floor or on to a suitable "conveyer," and removed to a convenient locality for cooling and subsequent grinding or finishing. It, however, is not in the condition of hard, heavy clinkers, such as are produced in the ordinary cement kiln, which require special machinery for breaking up into smaller pieces before being admitted between the millstones for the final process of grinding; nor does it consist of an overburnt exterior and an underburnt core or center portion; but it issues from the cylindrical furnace in a condition resembling in appearance coarse gunpowder, with occasional agglutinations of small friable particles readily reduced to fine powder in an ordinary mill, requiring but small power to work, and producing but little wear and tear upon the millstones. The operation is continuous. The revolver or furnace, once started, works on night and day, receiving the adjusted quantity of powdered material at the upper or feed end, and delivering its equivalent in properly burnt cement at the opposite end, thus effecting a great saving of time, and preventing the enormous waste of heat and serious injury to the brickwork, etc., incidental to the cooling down, withdrawing the charge, and reloading the ordinary kiln.

Cement, when taken from the furnace, weighed 110 lb. per bushel. Cement, when ground, leaving 10 percent. on sieve with 2,500 holes to the inch, weighed 121 lb. per bushel, and when cold 118 lb. per bushel. When made into briquettes, the tensile breaking strain upon the square inch:

At4 dayswas410lb. per square inch.

At6 days"610"

At14 days"810"

At49 days"900"

At76 days"1,040"

A cylindrical furnace, such as the author has described, is capable of turning out at least 20 tons of good cement per day of twenty-four hours, with a consumption of about 3 tons of slack coal. It will be readily understood that these furnaces can be worked more economically in pairs than singly, as they can be so arranged that one producer may furnish a sufficient quantity of gas for the supply of two cylinders, and the same labor will suffice; but in order to provide for possible contingencies the author advises that a spare gas producer and an extra furnace should be in readiness, so that by a simple arrangement of valves, etc., two cylinders may always be in operation, while from any cause one may be undergoing temporary repairs, and by this means any diminution in the output may be avoided.

The author considers it unnecessary here to discuss either the advantages or the economy of fuel effected by the employment of gas producers for such a purpose. These have been abundantly proved in steel and glass making industries, where a saving of from 50 to 70 per cent. of the fuel formerly employed has been made. Their cost is small, they occupy little room, they can be placed at any reasonable distance from the place where the gas is to be burnt; any laborer can shovel the slack into them, and they do not require constant skilled supervision. It is claimed by the author of this paper that the following are among the many advantages derivable from the adoption of this method of manufacturing Portland cement, as compared with the old system:

(1) Economy of space—the furnaces, with their appurtenances, requiring only about one-fourth the space of what would be occupied by the ordinary kilns for producing the same quantity of finished cement.

(2) Continuous working, and consequent economy of fuel lost by cooling and subsequent reheating of the kiln walls.

(3) Economy of repairs, which are of a simple and comparatively inexpensive character, and of much less frequent occurrence, as the continuous heat avoids the racking occasioned by the alternate heating and cooling.

(4) Economy in first cost.

(5) Economy in grinding, a friable granular substance being produced instead of a hard clinker, whereby crushers are quite abolished, and the wear and tear of millstones greatly reduced.

(6) Economy of labor, the conveyance to and removal from, the revolving furnace being conducted automatically by mechanical elevators and conveyers.

(7) Improved quality of the cement, from non-mixture with fuel, ash, or other impurities, and no overburning or underburning of the material.

(8) Thorough control, from the facility of increasing or diminishing the flow of crushed slurry and of regulating the heat in the furnace as desirable.

(9) Absence of smoke and deleterious gases.

It is well known that in some localities the materials from which Portland cement is made are of such a powdery character that they have to be combined or moulded into balls or bricks previous to calcination in the ordinary way, thus entailing expense which would be entirely obviated by the adoption of the patent revolving furnace, as has been proved by the author in producing excellent cement with a mixture of slag sand from the blast furnaces of the Cleveland iron district, with a proper proportion of chalk or limestone, which, in consequence of the friable nature of the compound, he was unable to burn in the ordinary cement kiln, but which, when burnt in the revolving furnace, gave the most satisfactory results. The cement so made possessed extraordinary strength and hardness, and it has been a matter of surprise that iron masters and others have not adopted such a means of converting a waste material—which at the present time entails upon its producers constant heavy outlay for its removal—into a remunerative branch of industry by the expenditure of a comparatively small amount of capital. The demand for Portland cement has increased and is still increasing at a rapid ratio. It is being manufactured upon a gigantic scale.

Great interests are involved; large sums of money are being expended in the erection and maintenance of expensive plant for its production; and the author submits that the development of any method which will improve the quality and at the same time reduce the cost of manufacture of this valuable material will tend to increase the prosperity of one of our great national industries, and stimulate commercial enterprise. Works are in progress for manufacturing cement by this improved process, and the author trusts the time is not far distant when the unsightly structures which now disfigure the banks of some of our rivers will be abolished—the present cement kilns, like the windmills once such a common feature of our country, being regarded as curiosities of the past, and cement manufacturers cease to be complained of as causing nuisances to their neighbors.

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