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The handbook of soap manufacture

INDEX.

Reading edition

A.

Acetic Acid, 10

Acid, Acetic, 10

---- Arachidic, 10

---- Behenic, 10

---- Butyric, 10

---- Capric, 10

---- Caproic, 10

---- Caprylic, 10

---- Carnaubic, 10

---- Cerotic, 10

---- Daturic, 10

---- Doeglic, 11

---- Elæomargaric, 12

---- Elæostearic, 12

---- Erucic, 11

---- Ficocerylic, 10

---- Hyænic, 10

---- Hypogæic, 11

---- Isolinolenic, 12

---- Isovaleric, 10

---- Jecoric, 12

---- Lauric, 10

---- Lignoceric, 10

---- Linolenic, 12

---- Linolic, 12

---- Margaric, 10

---- Medullic, 10

---- Melissic, 10

---- Moringic, 11

---- Myristic, 10

---- Oleic, 11

---- Palmitic, 10

---- Physetoleic, 11

---- Pisangcerylic, 10

---- Psyllostearylic, 10

---- Rapic, 11

---- Ricinoleic, 13

---- Saponification, 19-21

---- Stearic, 10

---- Tariric, 12

---- Telfairic, 12

---- Theobromic, 10

---- Tiglic, 11

---- value, 118, 128

Acids, Classification of fatty, 10

---- Fatty, 9-13

---- ---- Combination with Alkali, 45, 46

Acids, Fatty, Preparation by acid process, 19-21

---- ---- ---- by ferment process, 16

---- ---- ---- by Twitchell's process, 20

---- Saturated fatty, 11

---- Unsaturated fatty, 11

Albumen in soap, 90

Alcohols, Estimation of, 128

Aldehydes, Estimation of, 129

Alkali, Caustic and carbonated, 38, 39, 123-126

Alkali in soap, Determination of, 131, 132

Amyl salicylate, 107

Andiroba oil, 32

Animal charcoal, 115

---- fats, Treatment of, 43

Anise (star) oil, 96

Anisic aldehyde, 108

Arachidic acid, 10

Arachis oil, 28

Artificial perfumes, 107-110

Ash, Soda, 39, 124, 125

Aspic oil, 96

Aqueous saponification, 14

Aubépine, 108

B.

Bacteria, Decomposition of fats by, 18

Baobab-seed oil, 36

Bar soap, 54, 55

Barring soap, 68

Bay oil, 97

Behenic acid, 10

Benzyl acetate, 108

Bergamot oil, 97

---- ---- (artificial), 109

Biniodide soaps, 87

Birch-tar soap, 88

Bitter almond oil, 97

Bleaching palm oil, 41

---- rosin, 43

Boiling-on-strength, 51

Bois de Rose Femelle oil, 99

Bone-fat, 30

---- ---- treatment of, 43

Borax in soap, 88

Boric acid in soap, 88

Boric acid in soap, Determination of, 135

Borneo tallow, 32

Brine, 39

Bromine absorption of oils and fats, 122

Brown Windsor soap, 78, 98

Butter goa, 33

---- kokum, 33

---- shea, 31

Butyric acid, 10

Butyrin, 8

C.

Calico-printer's soap, 93

Cananga oil, 98

Candle-nut oil, 33

Capric acid, 10

Caprin, 8

Caproic acid, 10

Caproin, 8

Caprylic acid, 10

Caprylin, 8

Carapa oil, 32

Caraway oil, 98

Carbolic acid in soap, Determination of, 134

Carbolic soap, 88

Carbonate potash, 39, 125, 126

---- soda, 39, 124, 125

Carnaubic acid, 10

Cassia oil, 98

Castor oil, 30

Caustic potash, 39, 123

---- soda, 39, 123

Cayenne linaloe oil, 99

Cedarwood oil, 98

Cerotic acid, 10

Charcoal, Animal, 115

Chinese vegetable tallow, 31

Cholesterol in unsaponified matter, 120

Cinnamon oil, 98

Citral, 108

Citronella oil, 99

Citronellal, 108

Cleansing soap, 60, 61

Close-piling soap, 71

Clove oil, 99

Coal tar soaps, 88

Cocoa-nut oil, 25, 26

Cohune-nut oil, 34

Cold process soap-making, 46, 47

Colouring soap, 66, 80, 82

Compressing soap, 83, 85

Concrete orris oil, 100

Constitution of oils and fats, 6, 7

Conversion of oleic acid into solid acids, 11, 12

Cooling soap, 74, 76

Coprah oil, 25, 26

Cotton-seed oil, 27, 42

---- ---- Refining, 42

---- soapstock, 40

---- stearine, 28

Coumarin, 108

Crude glycerine, 113, 136-139

Crutching soap, 63

Curcas oil, 33

Curd mottled soap, 52, 53

Curd soaps, 52

Cutting and stamping toilet soap, 85

D.

Daturic acid, 10

Decolorisation, Glycerine, 115

Decomposition of fats by bacteria, 18

Detergent action of soap, 4, 5

Diglycerides, 7

Dika fat, 36

Disinfectant soaps, 66

Distearine, 7

Distillation, glycerine, 114

Distilled glycerine, 114

Doeglic acid, 11

Double distilled glycerine, 115

Dregs in fats and oils, Determination of, 120, 121

Drying soap, 71, 78-80

Dynamite glycerine, 115

E.

Elaidin reaction, 12

Electrical production of soap, 59

Elæomargaric acid, 12

Elæostearic acid, 12

Enzymes, Action of, 15-18

Erucic acid, 11

Essential oils, 96-107

---- ---- Examination of, 127-130

Ester value, 119, 128

Ether soap, 90

Eucalyptus oil, 100

Evaporation to crude glycerine, 112, 113

F.

Fat, Bone, 30

---- Dika, 36

---- Maripa, 34

---- Marrow, 30

---- Niam, 34

---- Tangkallah, 37

---- Treatment of bone, 43

Fats, Decomposition by bacteria of, 18

---- Treatment of animal, 43

---- Waste, 30

Fats and oils, Determination of acid value of, 118

---- ---- ---- of bromine absorption of, 122

---- ---- ---- of dregs, etc., in, 120, 121

---- ---- ---- of free acidity of, 117

---- ---- ---- of iodine absorption of, 121, 122

---- ---- ---- of saponification

---- ---- ---- equivalents of, 118

---- ---- ---- of saponification value, 118

---- ---- ---- of specific gravity of, 117 of titre of, 122, 123

---- ---- ---- of unsaponifiable matter in, 119

---- ---- ---- of water in, 120

---- ---- ---- Yield of glycerine from, 116

Fatty acids, 9-13, 31

---- ---- Classification of, 10

---- ---- Direct combination with alkali of, 45, 46

---- ---- in soap, Determination of, 131

---- ---- ---- Examination of, 133, 134

---- ---- Preparation by acid process, 19-21

---- ---- ---- by ferment process, 16

---- ---- ---- by Twitchell's process, 20

---- ---- Saturated, 11

---- ---- Unsaturated, 11

Fennel oil, 100

Ferment process for preparation of fatty acids, 16

Ferments, action of, 15-18

Ficocerylic acid, 10

Filling soap, 65

Fish oils, 30

"Fitting," 51

Floating soap, 90, 91

Fluorides in soap, 88

Formaldehyde soap, 88

Framing soap, 66

Free alkali in soap, Estimation of, 132

---- caustic in soap, Neutralising, 66

---- fat in soap, Determination of, 133

---- fatty acids, Determination of, 117

G.

Geraniol, 108

Geranium oils, 101

Geranium-sur-rose oil, 101

Ginger-grass oil, 101

Glycerides, 7, 8

Glycerine, Chemically pure, 115

---- Crude, 113, 136-139

---- decolorisation, 115

---- distillation, 114

---- Distilled, 114

---- dynamite, 115

---- in soap, Determination of, 134, 135

---- manufacture, 111-114

---- saponification, 116

---- soaps, 89

---- Yield of, from fats and oils, 116

Glycerol determination, acetin method, 136

---- ---- bichromate method, 137, 138

---- in lyes, Estimation of, 135

Goa-butter, 33

"Graining-out," 50

Grease, Animal, 30

---- Bone, 30

---- Kitchen, 30

---- Skin, 30

Guaiac wood oil, 101

H.

Halphen's reaction, 134

Heliotropin, 108

Hemp-seed oil, 29

Hyacinth, 108

Hyænic acid, 10

Hydrated soaps, 48, 49

Hydrolysis accelerated by heat and electricity, 14, 15

---- accelerated by use of chemical reagents, 19-23

---- accelerated with acid, 19, 21

---- Enzymic, 15-18

---- of oils and fats, 13-23

---- of soap, 3

Hypogæic acid, 11

I.

Ichthyol soap, 89

Inoy-kernel oil, 37

Iodine absorption of rose oil, 130

---- absorption of oils and fats, 121,122:

---- soap, 89

Ionone, 108

Isolinolenic acid, 12

Isovaleric acid, 10

Isovalerin, 8

J.

Jasmine, 109

Jecoric acid, 12

K.

Kananga oil, 98

Kapok oil, 32

"Kastilis," 88

Kokum butter, 33

L.

Lard, 25

Lauric acid, 10

Laurin, 8

Lavender oils, 101

Lemon-grass oil, 102

Lemon oil, 102

Lignoceric acid, 10

Lime oil, 102

---- saponification, 22

Linaloe oil, 102

Linalol, 109

Linalyl acetate, 109

Linolenic acid, 12

Linolic acid, 12

Linseed oil, 29

Lipase, 18

Liquoring of soaps, 64

Lyes, analysis of, 135

---- Determination of glycerol in, 135

---- Evaporation of, 112

---- Treatment of, 111, 112

Lysol soap, 89

M.

Mafura tallow, 35

Magnesia, Hydrolysis by, 22

Maize oil, 28

Margaric acid, 10

Margosa oil, 35

Marine animal oils, 30

---- soap, 49

Maripa fat, 34

Marjoram oil, 103

Medicated soaps, 86-90

Medullic acid, 10

Melissic acid, 10

Melting point, 130

Mercury soaps, 87

Milled toilet soaps, 78

Milling soap, 80, 81

---- soap-base, 54, 78

Mineral oil, saponifying, 58, 59

Mirbane oil or nitrobenzene, 109

Mixed glycerides, 8

Monoglycerides, 7

Monostearin, 7

Moringic acid, 11

Mottled soaps, 52, 53

---- ---- Pickling, 54

Moulds, Soap, 72, 85, 86

Mowrah-seed oil, 31

Musk (artificial), 109

Myristic acid, 8

Myristin, 8

N.

Naphthol soap, 89

Neroli Bigarade oil, 103

---- oil (artificial), 109

Neutralising free caustic in soap, 66, 80

Niam fat, 34

Nigre, 56

Nigres, Utilisation of, 56

Niobe oil or ethyl benzoate, 110

Nitrobenzene, 109

O.

Oeillet, 10

Oil, Andiroba, 32

---- Arachis, 28

---- Aspic (lavender spike), 96

---- Baobab-seed, 36

---- Bay, 97

---- Bergamot, 97

---- Bitter almond, 97

---- Bleaching palm, 41

---- Bois de Rose Femelle, 99

---- Cananga, 98

---- Candle-nut, 33

---- Carapa, 32

---- Caraway, 98

---- Cassia, 98

---- Castor, 30

---- Cayenne linaloe, 99

---- Cedarwood, 98

---- Cinnamon, 98

---- Citronella, 99

---- Clove, 99

---- Cocoa-nut, 25, 26

---- Cohune-nut, 34, 35

---- Concrete orris, 100

---- Coprah, 25, 26

---- Cotton-seed, 27, 42

---- Curcas, 33

---- Eucalyptus, 100

---- Fennel, 100

---- Geranium, 101

---- Ginger-grass, 101

---- Guaiac-wood, 101

---- Hemp-seed, 29

---- Inoy-kernel, 37

---- Kananga, 98

---- Kapok, 32

---- Lemon, 102

---- Lemon-grass, 102

---- Lime, 102

---- Linaloe, 102

---- Linseed, 29

---- Maize, 28

---- Margosa, 35

---- Marjoram, 103

---- Mowrah-seed, 31

---- Neroli Bigarade, 103

---- Olive, 26

---- Olive-kernel, 27

---- Orange, 163

---- Palm, 27, 41

---- Palm-nut, 26

---- Palmarosa, 103

---- Patchouli, 103

---- Peppermint, 103, 104

---- Persimmon-seed, 36

---- Peru-balsam, 104

---- Petit-grain, 104

---- Pongam, 35

---- Refining cotton-seed, 42

---- Rose, 105

---- Rosemary, 105

---- Safflower, 33, 34

---- Sandalwood, 105, 106

---- Saponifying mineral, 58, 59

---- Sassafras, 106

---- Sesame, 28, 29

---- Star-anise, 96

---- Sunflower, 29

---- Thyme, 106

---- Verbena, 106

---- Vetivert, 106-107

---- Wheat, 36

---- Wild mango, 36

---- Wintergreen, 107

---- Ylang-ylang, 107

Oils and fats, Constitution of, 6, 7

---- ---- Examination of, 117-123

---- ---- Hydrolysis of, 13-22

---- Fish and marine animal, 30

---- Lavender, 101

---- Refractive Index of, 122

---- treatment of vegetable, 43

Oleic acid, 11

---- ---- into solid acids, Conversion of, 11, 12

Olein, 8, 9, 31

---- Cocoa-nut, 31

---- Palm-nut, 31

Oleodidaturin, 8

Oleodipalmitin, 8

Oleodistearin, 8

Oleopaimitostearin, 8

Olive-kernel oil, 27

Olive oil, 26

Open-piling soap, 71

Optical rotation, 127

Orange oil, 103

Orchidée, 107

Orris oil, concrete, 100

P.

Palm oil, 27, 41

---- ---- Bleaching, 41

Palmarosa oil, 103

Palmitic acid, 10

Palmitin, 8

Palmitodistearin, 8

Palm-nut oil, 26

Pasting or saponification, 49

Patchouli oil, 103

Patent textile soaps, 94

Pearl-ash, Analysis of, 125, 126

Peppermint oil, 103, 104

Perfumer's soaps, 77, 78

Perfumes, Artificial and synthetic, 107-110

---- Soap, 95-110

Perfuming soaps, 94

Persimmon seed oil, 36

Peru-balsam oil, 104

Petit-grain oil, 104

Phenols, Determination of, 129

Physetoleic acid, 11

Phytosterol in unsaponifiable matter, 120

Pickling mottled soap, 54

Pisangcerylic acid, 10

Polishing soaps, 94

Pongam oil, 35

Potash, Carbonate, 39, 125, 126

---- Caustic, 89, 123

Potassium chloride, 126

---- Determination of, 126, 132

Powders, Soap, 94

Psyllostearylic acid, 10

R.

Rancidity, 18, 24

Rapic acid, 11

Refining cotton-seed oil, 42

Refractive index of oils and fats, 122

Remelted soaps, 77, 78

Resinate of soda, 43, 44

Ricinoleic acid, 13

Ricinolein, 8

Rose oil, 105

---- ---- (artificial), 110

Rosemary oil, 105

Rosin, 37, 38, 43, 44, 55

---- Bleaching, 43

---- Determination of, 133, 134

---- treatment, 43, 44

S.

Safflower oil, 33, 34

Safrol, 110

Salt, 39, 126

---- Determination of, 124, 125, 126, 132

Sandalwood oil, 105, 106

Santalol, 110

Saponification, 13-22, 49

---- accelerated by heat and electricity, 14, 15

---- accelerated by use of chemical reagents, 19, 23

---- accelerated with Twitchell's reagent, 20

---- Acid, 19, 21

---- Aqueous, 14

---- by ferment process, 20

---- equivalent, 118

---- Glycerine, 116

---- Lime, 22

---- under pressure, 47

---- value, 118, 128

Saponifying mineral oil, 58, 59

Sassafras oil, 106

Saturated acids, 11

Scouring soaps, 92, 93

Sesame oil, 28, 29

Settled soap, Treatment of, 60-76

Shaving soaps, 91

Shea butter, 31

Silicate of soda in soap, 65

Silicates of soda and potash, 127, 138

Silk scouring soaps, 93

---- dyer's soap, 93, 94

Slabbing soap, 68

Soap, Albumen in, 90

---- Analysis of, 130-35

---- Bar, 54, 55

---- Barring, 68

---- -base, Milling, 54, 78

---- Biniodide, 87

---- Birch-tar, 88

---- Borax, 88

---- Boric acid in, 88

---- ---- ---- ---- Determination, 135

---- Carbolic, 88

---- Classification of, 45

---- Cleansing, 60, 61

---- Coal-tar, 88

---- Cold process, 46, 47

---- Compressing, 83, 85

---- Cooling, 74-76

---- Crutching, 63

---- Curd, 52

---- Curd mottled, 53

---- Definition of, 1, 2

---- Detergent action of, 4, 5

---- Determination of carbolic acid in, 134

---- ---- of fatty acids in, 131

---- ---- of free alkali in, 132

---- ---- of free fat in, 133

---- ---- of glycerine in, 134, 135

---- ---- of total alkali in, 131

---- ---- of water in, 133

---- Drying, 71, 78-80

---- Electrical production of, 59

---- Ether, 90

---- Examination of fatty acids 133, 134

---- Filling, 65

---- Fluorides in, 90

---- formaldehyde, 88

---- frame, 66

---- framing, 66

---- from fatty acids, 45, 46

---- Glycerine, 89

---- Hydrated, 48, 49

---- Hydrolysis of, 3

---- Ichthyol, 89

---- Iodine, 89

---- Lysol, 89

---- Marine, 49

---- Milling, 80, 81

---- Monopole, 94

---- Mottled, 52, 53

---- moulds, 72, 85, 86

---- Naphthol, 89

---- Neutralising, colouring and perfuming, 66, 80, 82

---- Open and close piling, 71

---- perfumes, 95-110

---- Pickling mottled, 54

---- powders, 94

---- Properties of, 2

---- Salicylic acid, 88

---- Settling of, 55

---- Slabbing, 68

---- Soft, 41

---- Stamping, 71, 72, 85, 86

---- Sulphur, 89

---- Terebene, 90

---- Thymol, 90

---- Transparent, 57, 58

---- Treatment of settled, 60-76

---- Yellow household, 54, 55

Soap-making, 45-59

---- ---- Blue and grey mottled, 53

---- ---- "Boiling-on-strength," 51

---- ---- Cold process, 46, 47

---- ---- Combination of fatty acids with alkali, 45, 46

---- ---- Curd, 52

---- ---- Curd, Mottled, 53

---- ---- "Fitting," 51

---- ---- "Graining-out" or separation, 50

---- ---- Hydrated, 49

---- ---- "Pasting" or saponification, 49

---- ---- Soft, 48

---- ---- Transparent, 57, 58

---- ---- under pressure, 47

Soaps, Calico-printer's, 93

---- Disinfectant, 66

---- Floating, 90, 91

---- Liquoring of, 64, 65

---- Medicated, 86-90

---- Milled toilet, 78

---- Miscellaneous, 94

---- Perfumer's, 77, 78

---- Polishing, 94

---- Remelted, 77, 78

---- Scouring, 92

---- Shaving, 91

---- Silicating, 65

---- Silk dyer's, 93, 94

---- Textile, 91-94

---- Toilet, 77, 78

---- Woollen dyer's, 92

Soap-stock, 40

Soda ash, 39, 124, 125

---- ---- Caustic, 39, 125

---- Carbonate, 39, 124, 125

---- Caustic, 39, 123

---- Resinate, 43, 44

Soft soap-making, 48

Solidifying-point, 130

Specific gravity, Determination of, 117, 127

Stamping soap, 71, 72, 85, 86

Starch, Detection of, 121, 135

Steapsin, 18

Stearic acid, 10

Stearin, 8, 9

Stearine, Cotton-seed, 28

Stearodipalmitin, 8

Sulphides and sulphites, Determination of, 125

Sulphur soap, 89

Sunflower oil, 29

Superfatting material, 83

Synthetic perfumes, 107-110

T.

Table of caustic potash solutions, 151

---- of caustic soda solutions, 149, 150

---- of comparative densities, 147

---- of thermometric equivalents, 148

Tablet soap, 55

Talc, 65

Tallow, 24

---- Borneo, 32

---- Chinese vegetable, 31

---- Mafura, 35

Tangkallah fat, 37

Tariric acid, 12

Telfairic acid, 12

Terebene, 110

---- soap, 90

Terpineol, 110

Textile soaps, 91-94

---- ---- Patent, 94

Theobromic acid, 10

Thyme oil, 106

Thymol soap, 90

Tiglic acid, 11

Titre test, 122, 123

Toilet soaps, 77, 78

---- ---- Compressing, 83, 85

---- ---- Milled, 78

---- ---- Milling, 80, 81

---- ---- Stamping, 85, 86

Transparent soaps, 57, 58

Treatment of animal fats, 43

---- ---- bone fat, 43

---- ---- lyes, 111, 112

---- ---- rosin, 43

---- ---- settled soap, 60-76

---- ---- Vegetable oils, 43

Trèfle, 107

Triglycerides, 7, 8

Trilaurin, 9

Triolein, 9

Tripalmitin, 9

Tristearin, 7, 9

Twitchell's process, 22

U.

Unsaponifiable matter, Constitution of, 119, 120

---- ---- Determination of, 119

Unsaturated acids, 11

Utilisation of nigres, 56

V.

Vanillin, 110

Vegetable oils, Treatment of, 43

---- tallow, Chinese, 31

Verbena oil, 106

Vetivert oil, 106

Violet soap, 54

Volhard's method for chloride determination, 132

W.

Waste fats, 30

Water, 39

---- ---- in fats, Determination of, 120

---- ---- in soap, Determination of, 133

Wheat oil, 36

Wild mango oil, 36

Wintergreen oil, 107

Wool scouring soaps, 92

Woollen dyer's soap, 92

Y.

Ylang-ylang oil, 107

Z.

Zinc oxide, Hydrolysis by, 22

---- soap, 87

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