I.—PHÆNOGAMOUS OR FLOWERING PLANTS. (continued 16)
Reading edition
Barus Camphor, Borneo Camphor, Malayan Camphor, Dryobalanops Camphor—This, as already explained, is the substance to which the earliest notices of camphor refer. The tree which affords it is Dryobalanops aromatica Gärtn. (D. Camphora Colebrooke), of the order Dipterocarpeæ, one of the most majestic objects of the vegetable kingdom.[1909] The trunk is very tall, round, and straight, furnished near the base with huge buttresses; it rises 100 to 150 feet without a branch, then producing a dense crown of shining foliage, 50 to 70 feet in diameter, on which are scattered beautiful white flowers of delicious fragrance. The tree is indigenous to the Dutch Residencies on the north-west coast of Sumatra, between 0° and 3° N. lat., from Ayer Bangis to Barus and Singkel, and to the northern part of Borneo, and the small British island of Labuan.
The camphor is obtained from the trunk, in longitudinal fissures of which it is found in a solid crystalline state, and extracted by laboriously splitting the wood. It can only be got by the destruction of the entire tree;—in fact, many trees afford none, so that to avoid the toil of useless felling, it is now customary to try them by cutting a hole in the side of the trunk, but the observation so made is often fallacious. Spenser St. John, British Consul in Borneo, was told that trees in a state of decay often contain the finest camphor.[1910] The camphor when collected is carefully picked over, washed and cleaned, and then separated into three qualities, the best being formed of the largest and purest crystals, while the lowest is greyish and pulverulent.
Dryobalanops attaining more than 150 feet in height, the quantity of camphor which it yields must necessarily be greatly variable. The statements are from about 3 to 11 lb.
A good proportion of the small quantity produced is consumed in the funeral rites of the Batta princes, whose families are often ruined by the lavish expense of providing the camphor and buffaloes which the custom of their obsequies requires. The camphor which is exported is eagerly bought for the China market, but some is also sent to Japan, Laos, Cochin China, Cambodia, and Siam.
The quantity annually shipped from Borneo was reckoned by Motley in 1851 to be about 7 peculs (933 lbs.). The export from Sumatra was estimated by De Vriese at 10 to 15 quintals per annum.[1911] The quantity imported into Canton in 1872 was returned as 23⁷/₁₀ peculs (3,159 lb.), value 42,326 taels, equivalent to about 80s. per lb.[1912] In the Annual Statement of the Trade of Bombay for the year 1872-3, 2 cwt. of Malayan Camphor is stated to have been imported; it was valued at 9,141 Rs. (£914). In the “Indian tariff,” 1875, the duty is fixed per cwt. at 40 rupees for crude camphor, 65 rupees for refined camphor, and 80 rupees per pound for Baros camphor (“Bhemsaini camphor”). The price in Borneo in 1851 of camphor of fine quality was 30 dollars per catty, or about 95s. per lb.: consequently the drug never finds its way into European commerce.
Borneo Camphor, also termed by chemists Borneol or Camphyl Alcohol, is somewhat harder than common camphor, also a little heavier so that it sinks in water. It is less volatile, and does not crystallize on the interior of the bottle in which it is kept; and it requires for fusion a higher temperature, namely 198° C. It has a somewhat different odour, resembling that of common camphor with the addition of patchouli or ambergris. The composition of borneol is represented by the formula C₁₀H₁₇(OH). It may be converted by the action of nitric acid into common camphor, which it nearly resembles in most of its physical properties. Conversely, borneol may also be prepared from common camphor. By continued oxydation borneol yields camphoric acid.
Camphor Oil of Borneo—Besides camphor, the Dryobalanops furnishes another product, a liquid termed Camphor Oil, which must not be confounded with the camphor oil that drains out of crude laurel camphor. This Bornean or Sumatran Camphor Oil is obtained by tapping the trees, or in felling them (see also p. 229). In the latter way, Motley in cutting down a tree in Labuan in May, 1851, pierced a reservoir in the trunk from which about five gallons of camphor oil were obtained, though much could not be caught.[1913] The liquid was a volatile oil holding in solution a resin, which after a few days’ exposure to the air, was left in a syrupy state. This camphor oil, which is termed Borneene, is isomeric with oil of turpentine, C₁₀H₁₆, yet in the crude state holding in solution borneol and resin. By fractional distillation, it may be separated into two portions, the one more volatile than the other but not differing in composition.
Camphor Oil of Formosa, which has been already referred to as draining out of the crude camphor of Cinnamomum Camphora, is a brown liquid holding in solution an abundance of common camphor, which it speedily deposits in crystals when the temperature is slightly reduced. From Borneo Camphor Oil it may be distinguished by its odour of sassafras. We find no optical difference in the rotatory power of the oils; both are dextrogyre to the same extent, which is still the case if the camphor from the lauraceous camphor oil is separated by cooling. Borneo camphor oil, for a sample of which we are indebted to Prof. de Vriese, deposits no camphor even when kept at -15° C.
Ngai Camphor, Blumea Camphor—It has been known for many years that the Chinese are in the habit of using a third variety of camphor, having a pecuniary value intermediate between that of common camphor and of Borneo camphor. This substance is manufactured at Canton and in the island of Hainan, the plant from which it is obtained being Blumea balsamifera DC., a tall herbaceous Composita, of the tribe Inuloideæ, called in Chinese Ngai, abundant in Tropical Eastern Asia.
The drug has been supplied to us[1914] in two forms,—crude and pure,—the first being in crystalline grains of a dirty white, contaminated with vegetable remains; the second in colourless crystals as much as an inch in length. By sublimation the substance may be obtained in distinct, brilliant crystals, agreeing precisely with those of Borneo camphor, which they also resemble in odour and hardness, as well as in being a little heavier than water and not so volatile as common camphor.
The chemical examination of Ngai camphor, performed by Plowman,[1915] under the direction of Prof. Attfield, has proved that it has the composition C₁₀H₁₈O, like Borneo camphor. But the two substances differ in optical properties,[1916] an alcoholic solution of Ngai camphor being levogyre in about the same degree that one of Borneo camphor is dextrogyre. By boiling nitric acid, Borneo camphor is transformed into common (dextrogyre) camphor, whereas Ngai camphor affords a similar yet levogyre camphor, in all probability identical with the stearoptene of Chrysanthemum Parthenium Pers.
As Ngai camphor is about ten times the price of Formosa camphor, it never finds its way to Europe as an article of trade. In China it is consumed partly in medicine and partly in perfuming the fine kinds of Chinese ink. The export of this camphor by sea from Canton is valued at about £3,000 a year; it is also exported from Kiung-chow, in the island of Hainan.
CORTEX CINNAMOMI.
Cortex Cinnamomi Zeylanici; Cinnamon; F. Cannelle de Ceylan; G. Zimmt, Ceylon Zimmt, Kaneel.
Botanical Origin—Cinnamomum zeylanicum Breyne,—a small evergreen tree, richly clothed with beautiful, shining leaves usually somewhat glaucous beneath, and having panicles of greenish flowers of disagreeable odour.
It is a native of Ceylon, where, according to Thwaites, it is generally distributed through the forests up to an elevation of 3,000 feet, and one variety even to 8,000 feet. It is exceedingly variable in stature, and in the outline, size and consistence of the leaf; and several of the extreme forms are very unlike one another and have received specific names. But there are also numerous intermediate forms; and in a large suite of specimens, many occur of which it is impossible to determine whether they should be referred to this species or to that. Thwaites[1917] is of opinion that some still admitted species, as C. obtusifolium Nees and C. iners Reinw., will prove on further investigation to be mere forms of C. zeylanicum.
Beddome,[1918] Conservator of Forests in Madras, remarks that in the moist forests of South-western India there are 7 or 8 well-marked varieties which might easily be regarded as so many distinct species, but for the fact that they are so connected inter se by intermediate forms, that it is impossible to find constant characters worthy of specific distinction. They grow from the sea-level up to the highest elevations, and, as Beddome thinks, owe their differences chiefly to local circumstances, so that he is disposed to class them simply as forms of C. zeylanicum.
History—(For that of the essential oil of cinnamon see page 526). Cinnamon was held in high esteem in the most remote times of history. In the words of the learned Dr. Vincent, Dean of Westminster,[1919] it seems to have been the first spice sought after in all oriental voyages. Both cinnamon and cassia are mentioned as precious odoriferous substances in the Mosaic writings and in the Biblical books of Psalms, Proverbs, Canticles, Ezekiel and Revelations, also by Theophrastus, Herodotus, Galen, Dioscorides, Pliny, Strabo and many other writers of antiquity: and from the accounts which have thus come down to us, there appears reason for believing that the spices referred to were nearly the same as those of the present day. That cinnamon and cassia were extremely analogous, is proved by the remark of Galen, that the finest cassia differs so little from the lowest quality of cinnamon, that the first may be substituted for the second, provided a double weight of it be used.
It is also evident that both were regarded as among the most costly of aromatics, for the offering made by Seleucus II. Callinicus, king of Syria, and his brother Antiochus Hierax, to the temple of Apollo at Miletus, b.c. 243, consisting chiefly of vessels of gold and silver, and olibanum, myrrh (σμύρνη), costus (page 382), included also two pounds of Cassia (κασία), and the same quantity of Cinnamon (κιννάμωμον).[1920]
In connexion with this subject there is one remarkable fact to be noticed, which is that none of the cinnamon of the ancients was obtained from Ceylon. “In the pages of no author,” says Tennent,[1921] “European or Asiatic, from the earliest ages to the close of the thirteenth century, is there the remotest allusion to cinnamon as an indigenous production, or even as an article of commerce in Ceylon.” Nor do the annuals of the Chinese, between whom and the inhabitants of Ceylon, from the 4th to the 8th centuries, there was frequent intercourse and exchange of commodities, name Cinnamon as one of the productions of the island. The Sacred Books and other ancient records of the Singhalese are also completely silent on this point.
Cassia, under the name of Kwei, is mentioned in the earliest Chinese herbal,—that of the emperor Shen-nung, who reigned about 2700 b.c., in the ancient Chinese[1922] Classics, and in the Rh-ya, a herbal dating from 1200 b.c. In the Hai-yao-pên-ts’ao, written in the 8th century, mention is made of Tien-chu kwei. Tien-chu is the ancient name for India: perhaps the allusion may be to the cassia bark of Malabar.
In connexion with these extremely early references to the spice, it may be stated that a bark supposed to be cassia is mentioned as imported into Egypt together with gold, ivory, frankincense, precious woods, and apes, in the 17th century b.c.[1923]
The accounts given by Dioscorides, Ptolemy and the author of the Periplus of the Erythrean Sea, indicate that cinnamon and cassia were obtained from Arabia and Eastern Africa; and we further know that the importers were Phœnicians, who traded by Egypt and the Red Sea with Arabia. Whether the spice under notice was really a production of Arabia or Africa, or whether it was imported thither from Southern China (the present source of the best sort of cassia), is a question which has excited no small amount of discussion.
We are in favour of the second alternative,—firstly, because no substance of the nature of cinnamon is known to be produced in Arabia or Africa; and secondly, because the commercial intercourse which was undoubtedly carried on by China with India and Arabia, and which also existed between Arabia, India and Africa, is amply sufficient to explain the importation of Chinese produce.[1924] That the spice was a production of the far East is moreover implied by the name Darchini (from dar, wood or bark, and Chini, Chinese) given to it by the Arabians and Persians.
If this view of the case is admissible, we must regard the ancient cinnamon to have been the substance now known as Chinese Cassia lignea or Chinese Cinnamon, and cassia as one of the thicker and perhaps less aromatic barks of the same group, such in fact as are still found in commerce.
Of the circumstances which led to the collection of cinnamon in Ceylon, and of the period at which it was commenced, nothing is known. That the Chinese were concerned in the discovery is not an unreasonable supposition, seeing that they traded to Ceylon, and were in all probability acquainted with the cassia-yielding species of Cinnamomum of Southern China, a tree extremely like the cinnamon tree of Ceylon.
Whatever may be the facts, the early notices of cinnamon as a production of Ceylon are not prior to the 13th century. The very first, according to Yule,[1925] is a mention of the spice by Kazwini, an Arab writer of about a.d. 1275, very soon after which period it is noticed by the historian of the Egyptian Sultan Kelaoun, a.d. 1283. The prince of Ceylon is stated to have sent an ambassador, Al-Hadj-Abu-Othman, to the Sultan’s court. It was mentioned that Ceylon produced elephants, Bakam (the wood of Cæsalpinia Sapan L.—see page 216), pearls and also cinnamon.[1926]
A still more positive evidence is due to the Minorite friar, John of Montecorvino, a missionary who visited India. This man, in a letter under date December 20th, 1292 or 1293, written at “Mabar, città dell’ India di sopra,” and still extant in the Medicean library at Florence, says that the cinnamon tree is of medium bulk, and in trunk, bark and foliage, like a laurel, and that great store of its bark is carried forth from the island which is near by Malabar.[1927]
Again, it is mentioned by the Mahomedan traveller Ibn Batuta about a.d. 1340,[1928] and a century later by the Venetian merchant Nicolo di Conti, whose description of the tree is very correct.[1929]
The circumnavigation of the Cape of Good Hope led to the real discovery of Ceylon by the Portuguese in 1505, and to their permanent occupation of the island in 1536, chiefly for the sake of the cinnamon. It is from the first of these dates that more exact accounts of the spice began to reach Europe. Thus in 1511 Barbosa distinguished the fine cinnamon of Ceylon from the inferior Canella trista of Malabar. Garcia de Orta, about the middle of the same century, stated that Ceylon cinnamon was forty times as dear as that of Malabar. Clusius, the translator of Garcia, saw branches of the cinnamon tree as early as 1571 at Bristol and in Holland.
At this period cinnamon was cut from trees growing wild in the forests in the interior of Ceylon, the bark being exacted as tribute from the Singhalese kings by the Portuguese. A peculiar caste called chalias, who are said to have emigrated from India to Ceylon in the 13th century, and who in after-times became cinnamon-peelers, delivered the bark to the Portuguese. The cruel oppression of these chalias was not mitigated by the Dutch, who from the year 1656 were virtually masters of the whole seaboard, and conceded the cinnamon trade to their East India Company as a profitable monopoly, which the Company exercised with the greatest severity.[1930] The bark previous to shipment was minutely examined by special officers, to guard against frauds on the part of the chalias.
About 1770 De Koke conceived the happy idea, in opposition to the universal prejudice in favour of wild-growing cinnamon, of attempting the cultivation of the tree. This project was carried out under Governors Falck and Van der Graff with extraordinary success, so that the Dutch were able, independently of the kingdom of Kandy, to furnish about 400,000 lb. of cinnamon annually, thereby supplying the entire European demand. In fact, they completely ruled the trade, and would even burn the cinnamon in Holland, lest its unusual abundance should reduce the price.
After Ceylon had been wrested from the Dutch by the English in 1796, the cinnamon trade became the monopoly of the English East India Company, who then obtained more cinnamon from the forests, especially after the year 1815, when the kingdom of Kandy fell under British rule. But though the chalias had much increased in numbers, the yearly production of cinnamon does not appear to have exceeded 500,000 lb. The condition of the unfortunate chalias was not ameliorated until 1833, when the monopoly granted to the Company was finally abolished, and Government, ceasing to be the sole exporters of cinnamon, permitted the merchants of Colombo and Galle to share in the trade.
Cinnamon however was still burdened with an export duty equal to a third or a half of its value; in consequence of which and of the competition with cinnamon raised in Java, and with cassia from China and other places, the cultivation in Ceylon began to suffer. This duty was not removed until 1853.
The earliest notice of cinnamon in connexion with Northern Europe that we have met with, is the diploma granted by Chilperic II., king of the Franks, to the monastery of Corbie in Normandy, a.d. 716, in which provision is made for a certain supply of spices and grocery, including 5 lb. of Cinnamon.[1931]
The extraordinary value set on cinnamon at this period is remarkably illustrated by some letters written from Italy, in which mention is here and there incidentally made of presents of spices and incense.[1932] Thus in a.d. 745, Gemmulus, a Roman deacon, sends to Boniface, archbishop of Mayence (“cum magnâ reverentiâ”), 4 ounces of Cinnamon, 4 ounces of Costus, and 2 pounds of Pepper. In a.d. 748, Theophilacias, a Roman archdeacon, presents to the same bishop similar spices and incense. Lullus, the successor of Boniface, sends to Eadburga, abbatissa Thanetensis,[1933] circa a.d. 732-751—“unum graphium argenteum et storacis et cinnamomi partem aliquam”; and about the same date, another present of cinnamon to archbishop Boniface is recorded. Under date a.d. 732-742, a letter is extant of three persons to the abbess Cuneburga, to whom the writers offer—“turis et piperis et cinnamomi permodica xenia, sed omni mentis affectione destinata.”
In the 9th century, Cinnamon, pepper, costus, cloves, and several indigenous aromatic plants were used in the monastery of St. Gall in Switzerland as ingredients for seasoning fish.[1934]
Of the pecuniary value of this spice in England, there are many notices from the year 1264 downwards.[1935] In the 16th century it was probably not plentiful, if we may judge from the fact that it figures among the New Year’s gifts to Philip and Mary (1556-57), and to Queen Elizabeth (1561-62).[1936]
Production and Commerce[1937]—The best cinnamon is produced, according to Thwaites,[1938] from a cultivated or selected form of the tree (var. α.), distinguished by large leaves of somewhat irregular shape. But the bark of all the forms possesses the odour of cinnamon in a greater or less degree. It is not however always possible to judge of the quality of the bark from the foliage, so that the peelers when collecting from uncultivated trees, are in the habit of tasting the bark before commencing operations, and pass over some trees as unfit for their purpose. The bark of varieties β. multiflorum and γ. ovalifolium is of very inferior quality, and said to be never collected unless for the purpose of adulteration.
The best variety appears to find the conditions most favourable to its culture, in the strip of country, 12 to 15 miles broad, on the south-west coast of Ceylon, between Negumbo, Colombo and Matura, where the tree is grown up to an elevation of 1500 feet. A very sandy clay soil, or fine white quartz, with a good sub-soil and free exposure to the sun and rain, are the circumstances best adapted for the cultivation. The management of the plantations resembles that of oak coppice in England. The system of pruning checks the plant from becoming a tree, and induces it to form a stool from which four or five shoots are allowed to grow; these are cut at the age of 1½ to 2 years, when the greyish-green epidermis begins to turn brown by reason of the formation of a corky layer. They are not all cut at the same time, but only as they arrive at the proper state of maturity; they are then 6 to 10 feet high and 1 to 2 inches thick. In some of the cinnamon gardens at Colombo, the stools are very large and old, dating back, it is supposed, from the time of the Dutch.
In consequence of the increased flow of sap which occurs after the heavy rains in May and June, and again in November and December, the bark at those seasons is easily separated from the wood, so that a principal harvest takes place in the spring, and a smaller one in the latter part of the year.
The shoots having been cut off by means of a long sickle-shaped hook called a catty, and stripped of their leaves, are slightly trimmed with a knife, the little pieces thus removed being reserved and sold as Cinnamon Chips. The bark is next cut through at distances of about a foot, and slit lengthwise, when it is easily and completely removed by the insertion of a peculiar knife termed a mama, the separation being assisted, if necessary, by strongly rubbing with the handle. The pieces of bark are now carefully put one into another, and the compound sticks firmly bound together into bundles. Thus they are left for 24 hours or more, during which a sort of “fermentation” (?) goes on which facilitates the subsequent removal part. This is accomplished by placing each quill on a stick of wood of suitable thickness, and carefully scraping off with a knife the outer and middle cortical layer. In a few hours after this operation, the peeler commences to place the smaller tubes within the larger, also inserting the small pieces so as to make up an almost solid stick, of about 40 inches in length. The cinnamon thus prepared is kept one day in the shade, and then placed on wicker trays in the sun to dry. When sufficiently dry, it is made into bundles of about 30 lb. each.[1939]
The cinnamon gardens of Ceylon were estimated in 1860-64 to occupy an area of about 14,400 acres; in the catalogue of the British Colonies, Paris Exhibition, 1878, about 2 millions of acres are stated to be under cultivation in the island, 26,000 acres with cinnamon.[1940]
The exports of cinnamon from Ceylon have been as follows:—
1871 1872 1875
1,359,327 lb., 1,267,953 lb., 1,500,000 lb.
value £67,966. value £64,747.
At present the cultivation of coffee is displacing that of cinnamon, the exports of the former in 1875 being 928,606 cwts. valued at 4¼ millions sterling. Of the crop of 1872 there were 1,179,516 lb. of cinnamon shipped to the United Kingdom, 53,439 lb. to the United States of North America, and 10,000 lb. to Hamburg.
Besides the above-named exports of cinnamon, the official statistics[1941] record the export of “Cinnamon Bark”—8846 lb. in 1871—23,449 lb. in 1872. This name includes two distinct articles, namely Cinnamon Chips, and a very thick bark derived from old stems. The Cinnamon Chips which, as explained on the previous page, are the first trimmings of the shoots, are very aromatic; they used to be considered worthless, and were thrown away. The second article, to which in the London drug sales the name “Cinnamon Bark” is restricted, is in flat or slightly channelled fragments, which are as much as ⁴/₁₀ of an inch in thickness, and remind one of New Granada cinchona bark. It is very deficient in aromatic qualities, and quite unfit for use in pharmacy.
In most other countries into which Cinnamomum zeylanicum has been transplanted, it has been found that, partly from its tendency to pass into new varieties and partly perhaps from want of careful cultivation and the absence of the skilled cinnamon-peeler, it yields a bark appreciably different from that of Ceylon. Of other cinnamon-producing districts, those of Southern India may be mentioned as affording the Malabar or Tinnevelly, and the Tellicherry Cinnamon of commerce, the latter being almost as good as the cinnamon of Ceylon.[1942] The cultivation in Java commenced in 1825. The plant, according to Miquel, is a variety of C. zeylanicum, distinguished by its very large leaves which are frequently 8 inches long by 5 inches broad. The island exported in 1870, 1109 peculs (147,866 lb.); in 1871 only 446 peculs (59,466 lb.).[1943]
Cinnamon is also grown in the French colony of Guyana and in Brazil, but on an insignificant scale. The samples of the bark from those countries which we have examined are quite unlike the cinnamon of Ceylon. That of Brazil in particular has evidently been taken from stems several years old.
The importations of cinnamon into the United Kingdom from Ceylon are shown by the following figures:—
1867 1869 1870 1871 1872 1876
859,034 lb. 2,611,473 lb. 2,148,405 lb. 1,430,518 lb. 1,015,461 lb. 1,339,060 lb.
During 1872, 56,000 lb. of cinnamon were imported from other countries.
Description—Ceylon cinnamon of the finest description is imported in the form of sticks, about 40 inches in length and ⅜ of an inch in thickness, formed of tubular pieces of bark about a foot long, dexterously arranged one within the other, so as to form an even rod of considerable firmness and solidity. The quills of bark are not rolled up as simple tubes, but each side curls inwards so as to form a channel with in-curving sides, a circumstance that gives to the entire stick a somewhat flattened cylindrical form. The bark composing the stick is extremely thin, measuring often no more than ¹/₁₁₁₁ of an inch in thickness. It has a light brown, dull surface, faintly marked with shining wavy lines, and bearing here and there scars or holes at the points of insertion of leaves or twigs. The inner surface of the bark is of a darker hue. The bark is brittle and splintery, with a fragrant odour, peculiar to itself and the allied barks of the same genus. Its taste is saccharine, pungent, and aromatic.
The bales of cinnamon which arrive in London are always re-packed in the dock warehouses, in doing which a certain amount of breakage occurs. The spice so injured is kept separate and sold as Small Cinnamon, and is very generally used for pharmaceutical purposes. It is often of excellent quality.
Microscopic Structure—By the peeling above described, Ceylon cinnamon is deprived of the suberous coat and the greater part of the middle cortical layer, so that it almost consists of the mere liber (endophlœum). Three different layers are to be distinguished on a transverse section of this tissue:—
1. The external surface which is composed of one to three rows of large thick-walled cells, forming a coherent ring; it is only interrupted by bundles of liber-fibres, which are obvious even to the unaided eye; they compose in fact the wavy lines mentioned in the last page.
2. The middle layer is built up of about ten rows of parenchymatous thin-walled cells, interrupted by much larger cells containing deposits of mucilage, while other cells, not larger than those of the parenchyme itself, are loaded with essential oil.
3. The innermost layer exhibits the same thin-walled but smaller cells, yet intersected by narrow, somewhat darker, medullary rays, and likewise interrupted by cells containing either mucilage or essential oil.
Instead of bundles of liber-fibres, fibres mostly isolated are scattered through the two inner layers, the parenchyme of which abounds in small starch granules accompanied by tannic matter. On a longitudinal section, the length of the liber-fibres becomes more evident, as well as oil-ducts and gum-ducts.
Chemical Composition—The most interesting and noteworthy constituent of cinnamon is the essential oil, which the bark yields to the extent of ½ to 1 per cent., and which is distilled in Ceylon,—very seldom in England. It was prepared by Valerius Cordus, who stated,[1944] somewhat before 1544, that the oils of cinnamon and cloves belong to the small number of essential oils which are heavier than water, “fundum petunt.” About 1571 the essential oils of cinnamon, mace, cloves, pepper, nutmegs and several others, were also distilled by Guintherus of Andernach,[1945] and again, about the year 1589, by Porta.[1946]
In the latter part of the last century, it used to be brought to Europe by the Dutch. During the five years from 1775 to 1779 inclusive, the average quantity annually disposed of at the sales of the Dutch East India Company was 176 ounces. The wholesale price in London between 1776 and 1782 was 21s. per ounce; but from 1785 to 1789, the oil fetched 63s. to 68s., the increase in value being doubtless occasioned by the war with Holland commenced in 1782. The oil is now largely produced in Ceylon, from which island the quantity exported in 1871 was 14,796 ounces; and in 1872, 39,100 ounces.[1947] The oil is shipped chiefly to England.
Oil of cinnamon is a golden yellow liquid, having a sp. gr. of 1·035, a powerful cinnamon odour, and a sweet and aromatic but burning taste. It deviates a ray of polarized light a very little to the left. The oil consists chiefly of Cinnamic Aldehyde, C₆H₅(CH)₂COH, together with a variable proportion of hydrocarbons. At a low temperature it becomes turbid by the deposit of a camphor, which we have not examined. The oil easily absorbs oxygen, becoming thereby contaminated with resin and cinnamic acid, C₆H₅(CH)₂COOH.
Cinnamon contains sugar, mannite, starch, mucilage, and tannic acid. The Cinnamomin of Martin (1868) has been shown by Wittstein to be very probably mere mannite. The effect of iodine on a decoction of cinnamon will be noticed under the head of Cassia Lignea. Cinnamon afforded to Schätzler (1862) 5 per cent. of ash consisting chiefly of the carbonates of calcium and potassium.
Uses—Cinnamon is used in medicine as a cordial and stimulant, but is much more largely consumed as a spice.
Adulteration—Cassia lignea being much cheaper than cinnamon, is very commonly substituted for it. So long as the bark is entire, there is no difficulty in its recognition, but if it should have been reduced to powder, the case is widely different. We have found the following tests of some service, when the spice to be examined is in powder:—Make a decoction of powdered cinnamon of known genuineness; and one of similar strength of the suspected powder. When cool and strained, test a fluid ounce of each with one or two drops of tincture of iodine. A decoction of cinnamon is but little affected, but in that of cassia a deep blue-black tint is immediately produced (see further on, Cort. Cassiæ). The cheap kinds of cassia, known as Cassia vera, may be distinguished from the more valuable Chinese Cassia, as well as from cinnamon, by their richness in mucilage. This can be extracted by cold water as a thick glairy liquid, giving dense ropy precipitates with corrosive sublimate or neutral acetate of lead, but not with alcohol.
Other products of the Cinnamon Tree.
Essential Oil of Cinnamon Leaf (Oleum Cinnamomi foliorum)—This is a brown, viscid, essential oil, of clove-like odour, which is sometimes exported from Ceylon. It has been examined by Stenhouse (1854), who found it to have a sp. gr. of 1·053, and to consist of a mixture of Eugenol (p. 284) with a neutral hydrocarbon having the formula C₁₀H₁₆. It also contains a small quantity of benzoic acid.
Essential Oil of Cinnamon Root (Oleum Cinnamomi radicis)—A yellow liquid, lighter than water, having a mixed odour of camphor and cinnamon, and a strong camphoraceous taste. Both this oil and that of the leaf were described by Kämpfer (1712) and by Seba in 1731,[1948] and perhaps by Garcia de Orta so early as 1563. Solid camphor may also be obtained from the root. A water distilled from the flowers, and a fatty oil expressed from the fruits are likewise noticed by old writers, but are unknown to us.
CORTEX CASSIÆ LIGNEÆ.
Cassia Lignea, Cassia Bark.
Botanical Origin—Various species of Cinnamomum occurring in the warm countries of Asia from India eastward, afford what is termed in commerce Cassia Bark. The trees are extremely variable in foliage, inflorescences and aromatic properties, and the distinctness of several of the species laid down even in recent works is still uncertain.
The bark which bears par excellence the name of Cassia or Cassia lignea, and which is distinguished on the Continent as Chinese Cinnamon, is a production of the provinces of Kwangtung, Kwangsi and Kweichau in Southern China. The French expedition of Lieut. Garnier for the exploration of the Mekong and of Cochin China (1866-68) found cassia growing in about N. lat. 19° in the forests of the valley of the Se Ngum, one of the affluents on the left bank of the Mekong near the frontiers of Annam. A part of this cassia is carried by land into China, while another part is conveyed to Bangkok.[1949] Although it is customary to refer it without hesitation to a tree named Cinnamomum Cassia, we find no warrant for such reference: no competent observer has visited and described the cassia-yielding districts of China proper, and brought therefrom the specimens requisite for ascertaining the botanical origin of the bark.[1950]
Cassia lignea is also produced in the Khasya mountains in Eastern Bengal, whence it is brought down to Calcutta for shipment.[1951] In this region there are three species of Cinnamomum, growing at 1000 to 4000 feet above the sea-level, and all have bark with the flavour of cinnamon, more or less pure: they are C. obtusifolium Nees, C. pauciflorum Nees, and C. Tamala Fr. Nees et Eberm.
Cinnamomum iners Reinw., a very variable species occurring in Continental India, Ceylon, Tavoy, Java, Sumatra and other islands of the Indian Archipelago, and possibly in the opinion of Thwaites a mere variety of C. zeylanicum, but according to Meissner well distinguished by its paler, thinner leaves, its nervation, and the character of its aroma, would appear to yield the cassia bark or wild cinnamon of Southern India.[1952]
C. Tamala Fr. Nees et Eberm., which besides growing in Khasya is found in the contiguous regions of Silhet, Sikkim, Nepal, and Kumaon, and even reaches Australia, probably affords some cassia bark in Northern India.
Large quantities of a thick sort of cassia have at times been imported from Singapore and Batavia, much of which is produced in Sumatra. In the absence of any very reliable information as to its botanical sources, we may suggest as probable mother plants, C. Cassia Bl. and C. Burmanni Bl., var. α. chinense, both stated by Teijsmann and Binnendijk to be cultivated in Java.[1953] The latter species, growing also in the Philippines, most probably affords the cassia bark which is shipped from Manila.
History—In the preceding article we have indicated (p. 520) the remote period at which cassia bark appears to have been known to the Chinese; and have stated the reasons that led us to believe the cinnamon of the ancients was that substance. It must, however, be observed that Theophrastus, Dioscorides, Pliny, Strabo and others, as well as the remarkable inscription on the temple of Apollo at Miletus, represent cinnamon and cassia as distinct, but nearly allied substances. While, on the other hand, the author of the Periplus of the Erythrean Sea, in enumerating the products shipped from the various commercial ports of Eastern Africa[1954] in the first century, mentions Cassia (κμσία or κασσία) of various kinds, but never employs the word Cinnamon (κινναμώμον).
In the list of productions of India on which duty was levied at the Roman custom-house at Alexandria, circa a.d. 176-180, Cinnamomum is mentioned as well as Cassia turiana, Xylocassia and Xylocinnamomum.[1955] Of the distinction here drawn between cinnamon and cassia we can give no explanation; but it is worthy of note that twigs and branches of a Cinnamomum are sold in the Chinese drug shops, and may not improbably be the xylocassia or xylocinnamon of the ancients.[1956] The name Cassia lignea would seem to have been originally bestowed on some such substance, rather than as at present on a mere bark. The spice was also undoubtedly called Cassia syrinx and Cassia fistularis (p. 221),—names which evidently refer to a bark which had the form of a tube. In fact there may well have been a diversity of qualities, some perhaps very costly. It is remarkable that such is still the case in China, and that the wealthy Chinese employ a thick variety of cassia, the price of which is as much as 18 dollars per catty, or about 56s. per lb.[1957]
Whether the Aromata Cassiæ, which were presented to the Church at Rome under St. Silvester, a.d. 314-335, was the modern cassia bark, is rather doubtful. The largest donation, 200 lb., which was accompanied by pepper, saffron, storax, cloves, and balsam, would appear to have arrived from Egypt.[1958] Cassia seems to have been known in Western Europe as early as the 7th century, for it is mentioned with cinnamon by St. Isidore, archbishop of Seville.[1959] Cassia is named in one of the Leech-books in use in England prior to the Norman conquest.[1960] The spice was then sold in London as Canel in 1264, at 10d. per lb., sugar being at the same time 12d., cumin 2d., and ginger 18d.[1961] In the Boke of Nurture,[1962] written in the 15th century by John Russell, chamberlain to Humphry, duke of Gloucester, cassia is spoken of as resembling cinnamon, but cheaper and commoner, exactly as at the present day.
Production—We have no information whether the tree which affords the cassia bark of Southern China is cultivated, or whether it is exclusively found wild.
The Calcutta cassia bark collected in the Khasya mountains and brought to Calcutta is afforded by wild trees of small size. Dr. Hooker who visited the district with Dr. Thomson in 1850, observes that the trade in the bark is of recent introduction.[1963] The bark which varies much in thickness, has been scraped of its outer layer.
Cassia is extensively produced in Sumatra, as may be inferred from the fact that Padang in that island, exported of the bark in 1871, 6127 peculs (817,066 lb.), a large proportion of which was shipped to America.[1964] Regarding the collection of cassia on the Malabar coast, in Java and in the Philippines, no particular account has, so far as we know, been published. Spain imported from the Philippines by way of Cadiz in 1871, 93,000 lb. of cassia.[1965]
Description—Chinese Cassia lignea, otherwise called Chinese Cinnamon, which of all the varieties is that most esteemed, and approaching most nearly to Ceylon cinnamon, arrives in small bundles about a foot in length and a pound in weight, the pieces of bark being held together with bands of bamboo.
The bark has a general resemblance to cinnamon, but is in simple quills, not inserted one within the other. The quills moreover are less straight, even and regular, and are of a darker brown; and though some of the bark is extremely thin, other pieces are much stouter than fine cinnamon,—in fact, it is much less uniform. The outer coat has been removed with less care than that of Ceylon cinnamon, and pieces can easily be found with the corky layer untouched by the knife.
Cassia bark breaks with a short fracture. The thicker bark cut transversely shows a faint white line in the centre running parallel with the surface. Good cassia in taste resembles cinnamon, than which it is not less sweet and aromatic, though it is often described as less fine and delicate in flavour.
An unusual kind of cassia lignea is imported since 1870 from China and offered in the London market as China Cinnamon,[1966] though it is not the bark that bears this name in continental trade. The new drug is in unscraped quills, which are mostly of about the thickness of ordinary Chinese cassia lignea; it has a very saccharine taste and pungent cinnamon flavour.
The less esteemed kinds of cassia bark, which of late years have been poured into the market in vast quantity, are known in commerce as Cassia lignea, Cassia vera or Wild Cassia, and are further distinguished by the names of the localities whence shipped, as Calcutta, Java, Timor, etc.
The barks thus met with vary exceedingly in colour, thickness and aroma, so that it is vain to attempt any general classification. Some have a pale cinnamon hue, but most are of a deep rich brown. They present all variations in thickness, from that of cardboard to more than a quarter of an inch thick. The flavour is more or less that of cinnamon, often with some unpleasant addition suggestive of insects of the genus Cimex. Many, besides being aromatic, are highly mucilaginous, the mucilage being freely imparted to cold water. Finally, we have met with some thick cassia bark of good appearance that was distinguished by astringency and the almost entire absence of aroma.
Microscopic Structure—A transverse section of such pieces of Chinese Cassia lignea as still bear the suberous envelope, exhibits the following characters. The external surface is made up of several rows of the usual cork-cells, loaded with brown colouring matter. In pieces from which the cork-cells have been entirely scraped, the surface is formed of the mesophlœum, yet by far the largest part of the bark belongs to the liber or endophlœum. Isolated liber-fibres and thick-walled cells (stone-cells) are scattered even through the outer layers of a transverse section. In the middle zone they are numerous, but do not form a coherent sclerenchymatous ring as in cinnamon (p. 526). The innermost part of the liber shares the structural character of cinnamon with differences due to age, as for instance the greater development of the medullary rays. Oil-cells and gum-ducts are likewise distributed in the parenchyme of the former.
The “China Cinnamon” of 1870 (p. 530) comes still nearer to Ceylon cinnamon, except that it is coated. A transverse section of a quill, not thicker than one millimetre, exhibits the three layers described as characterizing that bark. The sclerenchymatous ring is covered by a parenchyme rich in oil-ducts, so that it is obvious that the flavour of this drug could not be improved by scraping. The corky layer is composed of the usual tabular cells. The liber of this drug in fact agrees with that of Ceylon cinnamon.
In Cassia Barks of considerable thickness, the same arrangement of tissues is met with, but their strong development causes a certain dissimilarity. Thus the thick-walled cells are more and more separated one from another, so as to form only small groups. The same applies also to the liber-fibres, which in thick barks are surrounded by a parenchyme, loaded with considerable crystals of oxalate of calcium. The gum-ducts are not larger, but are more numerous in these barks, which swell considerably in cold water.
Chemical Composition—Cassia bark owes its aromatic properties to an essential oil, which, in a chemical point of view, agrees with that of Ceylon cinnamon. The flavour of cassia oil is somewhat less agreeable, and as it exists in the less valuable sorts of cassia, decidedly different in aroma from that of cinnamon. We find the sp. gr. of a Chinese cassia oil to be 1·066, and its rotatory power in a column 50 mm. long, only 0°·1 to the right, differing consequently in this respect from that of cinnamon oil (p. 526).
Oil of cassia sometimes deposits a stearoptene, which when purified is a colourless, inodorous substance, crystallizing in shining brittle prisms.[1967] We have never met with it.
If thin sections of cassia bark are moistened with a dilate solution of perchloride of iron, the contents of the parenchymatous part of the whole tissue assume a dingy brown colour; in the outer layers the starch granules even are coloured. Tannic matter is consequently one of the chief constituents of the bark; the very cell-walls are also imbued with it. A decoction of the bark is turned blackish-green by a persalt of iron.
If cassia bark (or Ceylon cinnamon) is exhausted by cold water, the clear liquid becomes turbid on addition of iodine; the same occurs if a concentrated solution of iodide of potassium is added. An abundant precipitate is produced by addition of iodine dissolved in the potassium salt. The colour of iodine then disappears. There is consequently a substance present which unites with iodine; and in fact, if to a decoction of cassia or cinnamon the said solution of iodine is added, it strikes a bright blue coloration, due to starch. But the colour quickly disappears, and becomes permanent only after much of the test has been added. We have not ascertained the nature of the substance that thus modifies the action of iodine: it can hardly be tannic matter, as we have found the reaction to be the same when we used bark that had been previously repeatedly treated with spirit of wine and then several times with boiling ether.
The mucilage contained in the gum-cells of the thinner quills of cassia is easily dissolved by cold water, and may be precipitated together with tannin by neutral acetate of lead, but not by alcohol. In the thicker barks it appears less soluble, merely swelling into a slimy jelly.
Commerce—Cassia lignea is exported from Canton in enormous and increasing quantities. The shipments which in 1864 amounted to 13,800 peculs, reached 40,600 in 1869,[1968] 61,220 in 1871, and 76,464 peculs (10,195,200 lb.) value £267,703, in 1872.[1969] In 1874 the exports were 54,268 peculs (1 pecul = 133⅓ lb.) and 58,313 peculs in 1878; from the other ports of China cassia is not shipped to any extent. England usually receives no more than about 1,000,000 lb. of cassia, of which only 40,000 lb. appear to be consumed in the country. Hamburg imports about 2,000,000 lb. annually immediately from China. Yet in 1878 the quantity imported into London was 26,744 peculs (3,500,000 lb.), that received at Hamburg 13,548 peculs.
Cassia lignea is exported in chests containing 2 peculs each.
Oil of cassia was shipped from the south of China to the United Kingdom, to the extent in 1869 of 47,517 lb.; in 1870, of 28,389 lb.[1970] Hamburg is also a very important place for this oil; in the official statistics of that port for 1875 the imports from China are stated to have amounted to 30,000 lb., besides 10,000 lb. imported from Great Britain; in 1876 Hamburg imported 5,900 lb. from China and 17,000 lb. from England.
Uses—The same as those of cinnamon.
Allied Products.
Cassia Twigs—The branches of the cassia trees, alluded to at page 529, would appear to be collected from the same trees which yield the cassia lignea. Garnier (l.c. at p. 528) says that the youngest branches are made into fagots, adding that they have the odour of bugs.
Cassia twigs are not as yet exported to Europe, but they constitute a very important article of the trade of the interior of China. In 1872 no less than 456,533 lb. of this Wood of Cassia or Cassia Twigs were shipped from Canton, for the most part to other Chinese ports.—The imports of Hankow, in 1874, of these twigs were 1925 peculs (259,667 lb.) valued at 5677 taels (1 tael about equal to 5s. 11d.).[1971]
In the Paris Exhibition of 1878 we had the opportunity of examining some bundles of cassia twigs from western Kwangtung. The branches were as much as 2 feet in length and of the thickness of a finger. We found their bark to possess the usual flavour of cassia lignea.
Cassia Buds, Flores Cassiæ—These are the immature fruits of the tree yielding Chinese cassia lignea, and have been used in Europe since the middle ages. In the journal of expenses (a.d. 1359-60) of John, king of France, when a prisoner at Somerton Castle in England, there are several entries for the spice under the name of Flor de Canelle; it was very expensive, costing from 8s. to 13s. per lb., or more than double the price of mace or cloves. On one occasion two pounds of it had to be obtained for the king’s use from Bruges.[1972] From the Form of Cury[1973] written in 1390, it appears that cassia buds (“Flō de queynel”) were used in preparing the spiced wine called Hippocras.
Cassia buds are shipped from Canton, but the exports have much declined. Rondot, writing in 1848,[1974] estimated them as averaging 400 peculs (53,333 lb.) a year. In 1866 there were shipped from Canton only 233 peculs (31,066 lb.); in 1867, 165 peculs (22,000 lb.)[1975] The quantity of cassia buds imported into the United Kingdom in 1870 was 29,321 lb.;[1976] the spice is sold chiefly by grocers. The great market for this drug is Hamburg, where in 1876, according to the official statistics, 1324 cwt. of cassia buds were imported.
In Southern India, the more mature fruits of one of the varieties of Cinnamomum iners Reinw. are collected for use, but are very inferior to the Chinese cassia buds.
Folia Malabathri or Folia Indi—is the name given to the dried, aromatic leaves of certain Indian species of Cinnamomum, formerly employed[1977] in European medicine, but now obsolete. Under the name Taj-pat, the leaves are still used in India; they are collected in Mysore from wild trees.
Ishpingo—This is the designation in Quito of the calyx of a tree of the laurel tribe, used in Ecuador and Peru in the place of cinnamon. Though but little known in Europe, it has a remarkable history.
The existence of a spice-yielding region in South America, having come to the ears of the Spanish conquerors, was regarded as a matter of interest. It would appear that cinnamon was enumerated in the earliest accounts among the precious products of the New World.[1978] Such high importance was attached to it that in Ecuador an expedition was fitted out. The direction of the enterprise was confided to Gonzalo Pizarro, who with 340 soldiers, and more than 4000 Indians, laden with supplies, quitted the city of Quito on Christmas Day, 1539. The expedition, which lasted two years, resulted in the most lamentable failure, only 130 Spaniards surviving the hardships of the journey. In the account of it given by Garcilasso de la Vega, the cinnamon tree is described as having large leaves like those of a laurel, with fruits resembling acorns growing in clusters.[1979] Fernandez de Oviedo[1980] has also given some particulars regarding the spice, together with a figure fairly representing its remarkable form; and the subject has been noticed by several other Spanish writers, including Monardes.[1981]
Notwithstanding the celebrity thus conferred on the spice, and the fact that the latter gives its name to a large tract of country,[1982] and is still the object of a considerable traffic, the tree itself is all but unknown to science. Meissner places it doubtfully under the genus Nectandra, with the specific name cinnamomoides, but confesses that its flowers and fruits are alike unknown.[1983]
The spice, for an ample specimen of which we have to thank Dr. Destruge, of Guayaquil, consists of the enlarged and matured woody calyx, 1½ to 2 inches in diameter, having the shape of a shallow funnel, the open part of which is a smooth cup (like the cup of an acorn), surrounded by a broad, irregular margin, usually recurved. The outer surface is rough and veiny, and the whole calyx is dark brown, and has a strong, sweet, aromatic taste, like cinnamon, for which in Ecuador it is the common substitute.
Dr. Destruge has also furnished us with a specimen of the bark, which is in very small uncoated quills, exactly simulating true cinnamon. We are not aware whether the bark is thus prepared in quantity.
CORTEX BIBIRU.
Cortex Nectandræ; Greenheart Bark, Bibiru or Bebeeru Bark.
Botanical Origin—Nectandra Rodiæi Schomburgk—The Bibiru or Greenheart is a large forest tree,[1984] growing on rocky soils in British Guiana, twenty to fifty miles inland. It is found in abundance on the hill sides which skirt the rivers Essequibo, Cuyuni, Demerara, Pomeroon and Berbice. The tree attains a height of 80 to 90 feet, with an undivided erect trunk, furnishing an excellent timber which is ranked in England as one of the eight first-class woods for shipbuilding, and is to be had in beams of from 60 to 70 feet long.
History—In 1769 Bancroft, in his History of Guiana, called attention to the excellent timber afforded by the Greenheart or Sipeira. About the year 1835 it became known that Hugh Rodie, a navy surgeon who had settled in Demerara some twenty years previously, had discovered an alkaloid of considerable efficacy as a febrifuge, in the bark of this tree.[1985] In 1843 this alkaloid, to which Rodie had given the name Bebeerine, was examined by Dr. Douglas Maclagan; and the following year the tree was described by Schomburgk under the name of Nectandra Rodiæi.[1986]
Description—Greenheart bark occurs in long heavy flat pieces, not unfrequently 4 inches broad and ³/₁₀ of an inch thick, externally of a light greyish brown, with the inner surface of a more uniform cinnamon hue and with strong longitudinal striæ. It is hard and brittle; the fracture coarse-grained, slightly foliaceous, and only fibrous in the inner layer. The grey suberous coat is always thin, often forming small warts, and leaving when removed longitudinal depressions analogous to the digital furrows of Flat Calisaya Bark (p. 353), but mostly longer. Greenheart bark has a strong bitter taste, but is not aromatic. Its watery infusion is of a very pale cinnamon brown.
Microscopic Structure—The general features of this bark are very uniform, almost the whole tissue having been changed into thick-walled cells. Even the cells of the corky layer show secondary deposits; the primary envelope has entirely disappeared, and no transition from the suberous coat to liber is obvious.
The prevalent forms of the tissue are the stone-cells and very short liber-fibres, intersected by small medullary rays and crossed transversely by parenchyme or small prosenchyme cells with walls a little less thickened, so as to appear in a transverse section as irregular squares or groups. The only cells of a peculiar character are the sharp-pointed fibres of the inner liber, which are curiously saw-shaped, being provided with numerous protuberances and sinuosities.
The very small lumen of the thick-walled cells contains a dark brown mass which is coloured greenish-black by sulphate of iron; the same coloration takes place throughout the less dense tissue surrounding the the groups of stone-cells, and may in each case be due to tannic matter.
Chemical Composition—Greenheart bark contains an alkaloid which has long been regarded as peculiar, under the name of Bibirine or Bebirine. It was however shown by Walz in 1860 to be apparently identical with Buxine, a substance discovered as early as 1830 in the bark and leaves of the Common Box, Buxus sempervirens L. In 1869 the observation of Walz was to some extent confirmed by one of us,[1987] who further demonstrated that Pelosine, an alkaloid occurring in the stems and roots of Cissampelos Pareira L. and Chondodendron tomentosum Ruiz et Pavon (p. 28), is undistinguishable from the alkaloids of greenheart and box.
The alkaloid of bibiru bark, which may be conveniently prepared from the crude sulphate used in medicine under the name of Sulphate of Bibirine, is a colourless amorphous substance, the composition of which is indicated by the formula C₁₈H₂₁NO₃. It is soluble in 5 parts of absolute alcohol, in 13 of ether, and in 1400 (1800, Walz) of boiling water, the solution in each case having a decidedly alkaline reaction on litmus. It dissolves readily in bisulphide of carbon, as well as in dilute acids. The salts hitherto known are uncrystallizable. The solution of a neutral acetate affords an abundant white precipitate on the addition of an alkaline phosphate, nitrate or iodide, of iodohydrargyrate or platino-cyanide of potassium, perchloride of mercury, or of nitric or iodic acid.
Maclagan, one of the earliest investigators of greenheart, has obtained in co-operation with Gamgee[1988] certain alkaloids from the wood of the tree, to one of which these chemists have assigned the formula C₂₀H₂₃NO₄ and the name Nectandria. Two other alkaloids, the characters of which have not yet been fully investigated, are stated to have been obtained from the same source.
Bibiric Acid, which Maclagan obtained from the seeds, is described as a colourless, crystalline, deliquescent substance, fusing at 150° C. and volatile at 200° C., then forming needle-shaped groups.
Commerce—The supplies of greenheart bark are extremely uncertain, and the drug is scarcely to be found in the market. It has been imported in barrels containing 80 to 84 lb. each, or in bags holding ½ to ¾ cwt.
Uses—The bark has been recommended as a bitter tonic and febrifuge, but is hardly ever employed except in the form of what is called Sulphate of Bibirine, which, as we have said, is crude Sulphate of Buxine.[1989] It is a dark amorphous substance which, having while in a syrupy state been spread out on glazed plates, is obtained in thin translucent laminæ. We find it to yield scarcely one-third of its weight of the pure alkaloid.
RADIX SASSAFRAS.
Sassafras Root; F. Bois de Sassafras, Lignum Sassafras; G. Sassafrasholz.
Botanical Origin—Sassafras officinalis Nees (Laurus Sassafras L.), a tree growing in North America, from Canada, southward to Florida and Missouri. In the north it is only a shrub, or a small tree 20 to 30 feet high, but in the Middle and Southern United States, and especially in Virginia and Carolina, it attains a height of 40 to 100 feet. The leaves are of different forms, some being ovate and entire, and others two- or three-lobed, the former, it is said, appearing earlier than the latter.
History—Monardes relates that the French during their expedition to Florida (1562-1564) cured their sick with the wood and root of a tree called Sassafras, the use of which they had learnt from the Indians.[1990] Laudonnière, who was a member of that expedition, and diligently set forth the wonders of Florida, observes that, among forest trees, the most remarkable for its timber and especially for its fragrant bark, is that called by the savages Pavame and by the French Sassafras.[1991]
The drug was known in Germany, at least since 1582, under the above names or also by that of Lignum Floridum or Fennel-wood, Xylomarathrum.[1992]
The sassafras tree had been introduced into England in the time of Gerarde (circa 1597), who speaks of a specimen growing at Bow. At that period the wood and bark of the root were used chiefly in the treatment of ague.
In 1610, a paper of instructions from the Government of England to that of the new colony of Virginia, mentions among commodities to be sent home, “Small sassafras Rootes” which are “to be drawen in the winter and dryed and none to be medled with in the somer;—and yet is worthe £50 and better per tonne.”[1993] The shipments were afterwards much overdone, for in 1622 complaint is made that other things than tobacco and sassafras[1994] were neglected to be shipped.
Angelus Sala, an Italian chemist living in Germany about the year 1610-1630, in distilling sassafras noticed that the oil was heavier than water;[1995] it was quoted in 1683 in the tariff of the apothecary of the elector of Saxony, at Dresden.[1996] John Maud in 1738 obtained crystals of safrol as long as 4 inches;[1997] in 1844 they were examined by Saint-Evre.
Description—Sassafras is imported in large branching logs, which often include the lower portion of the stem, 6 to 12 inches in diameter.[1998]
The roots proper, which diminish in size down to the thickness of a quill, are covered with a dull, rough, spongy bark. This bark has an inert, soft corky layer, beneath which is a firmer inner bark of brighter hue, rich in essential oil. The wood of the root is light and easily cut, in colour of a dull reddish-brown, and with a fragrant odour and spicy taste similar to that of the bark but less strong. It is usually sold in the shops rasped into shavings.
The bark of the root (Cortex sassafras) is a separate article of commerce, but not much used in England. It consists of channelled, flattish, or curled, irregular fragments seldom exceeding 4 inches long by 3 inches broad and generally much smaller, and from ¹/₁₆ to ¼ of an inch in thickness. The inert outer layer has been carefully removed, leaving a scarred, exfoliating surface. The inner surface is finely striated and exhibits very minute shining crystals. The bark has a short, corky fracture, and in colour is a bright cinnamon brown of various shades. It has a strong and agreeable smell, with an astringent, aromatic, bitterish taste.
Microscopic Structure—The wood of the root exhibits, in transverse section, concentric rings transversed by narrow medullary rays. Each ring contains a number of large vessels in its inner part, and more densely packed cells in its outer. The prevailing part of the wood consists of prosenchyme cells. Globular cells, loaded with yellow essential oil, are distributed among the woody prosenchyme. The latter as well as the medullary rays abounds in starch.
The bark is rich in oil-cells and also contains cells filled with mucilage; it owes its spongy appearance and exfoliation to the formation of secondary cork bands (rhytidoma) within the mesophlœum and even in the liber. The cortical tissue abounds in red colouring matter, and further contains starch and, less abundantly, oxalate of calcium.
Chemical Composition—The wood of the root yields 1 to 2 per cent. of volatile oil,[1999] and the root-bark twice as much. The stem and leaves of the tree contain but a very small quantity. The oil, which as found in commerce is all manufactured in America, has the specific odour of sassafras, and is colourless, yellow, or reddish-brown, according, as the distillers assert, to the character of the root employed. As the colour of the oil does not affect its flavour and market value, no effort is made to keep separate the different varieties of root.
Oil of Sassafras has a sp. gr. of 1·087 to 1·094, increasing somewhat by age (Procter). When cooled, it deposits crystals of Safrol or Sassafras Camphor. This body, which we obtained in the form of hard, four- or six-sided prisms with the odour of sassafras, often attaining more than 4 inches in length and 1 inch in diameter, belongs to the monosymmetric system, as shown by Arzruni.[2000] Safrol, C₁₀H₁₀O₂, liquefies at 8°·5 C. (47° F.), having at 12° C. a sp. gr. of 1·11; it boils at 232° C., and is devoid of rotatory power, nor is it soluble in alkalis. The researches of Grimaux and Ruotte (1869) show the oil to contain nine-tenths of its weight of Safrol which they observed only in the liquid state.
Another constituent of sassafras oil has been termed by Grimaux and Ruotte Safrene; it boils at 155° to 157° C., has a sp. gr. of 0·834 and the formula C₁₀H₁₆. It has the same odour as safrol, but deviates the plane of polarization to the right.
It was further found by the same observers that the crude oil contains an extremely small quantity of a substance of the phenol class, which can be removed by caustic lye and separated by an acid.
We succeeded in obtaining this substance by using that portion of the crude oil from which the safrol had separated. The phenol remains in the mother-liquor after it has again been cooled and has afforded a new crystallization of safrol. The phenol thus obtained assumes a beautiful greenish blue hue on addition of an alcoholic solution of perchloride of iron.
The Sassarubin and Sassafrin of Hare (1837) are impure products of the decomposition of sassafras oil by means of sulphuric acid.
The bark and also to some extent the wood, in both cases of the root, contain tannic acid which produces a blue colour with persalts of iron. By oxidation, we must suppose, it is converted into the red colouring matter deposited in the bark and, in smaller quantity, in the heartwood of old trees. The young wood is nearly white. The said red substance probably agrees with that to which Reinsch in 1845 and 1846 gave the name of Sassafrid, and is doubtless analogous to cinchona-red and ratanhia-red. Reinsch obtained it to the extent of 9·2 per cent.
Production and Commerce—Baltimore is the chief mart for sassafras root, bark and oil, which are brought thither from within a circuit of 300 miles. The roots are extracted from the ground by the help of levers, partly barked and partly sent untouched to the market, or are cut up into chips for distillation on the spot. Of the bark as much as 100,000 lb. were received in Baltimore in 1866. The quantity of oil annually produced previous to the war is estimated at 15,000 to 20,000 lb. There are isolated small distillers in Pennsylvania and West New Jersey, who are allowed by the owners of a “sassafras wilderness” to remove from the ground the roots and stumps without charge. Sassafras root is not medicinal in the United States, the more aromatic root-bark being reasonably preferred.[2001]
Uses—Sassafras is reputed to be sudorific and stimulant, but in British practice it is only given in combination with sarsaparilla and guaiacum. Shavings of the wood are sold to make Sassafras Tea.
In America the essential oil is used to give a pleasant flavour to effervescing drinks, tobacco and toilet soaps.[2002]
Substitutes—The odour of sassafras is common to several plants of the order Lauraceæ. Thus the bark of Mesphilodaphne Sassafras Meissn., a tree of Brazil, resembles in odour true sassafras. We have seen a very thick sassafras bark brought from India, the same we suppose as that which Mason[2003] describes as abundantly produced in Burma.
The bark of Atherosperma moschatum Labillardière, an Australian tree, is occasionally exported from Australia under the name of Sassafras bark. It has the odour of the true drug, but differs from it by its grey colour.
The large separate cotyledons of two lauraceous trees of the Rio Negro, doubtfully referred by Meissner to the genus Nectandra, furnish the so-called Sassafras Nuts or Puchury or Pilchurim Beans of Brazil, occasionally to be met with in old drug warehouses.
On the Orinoko and in Guiana an oleo-resin, called Sassafras Oil or Laurel Oil, is obtained by boring into the stem of Oreodaphne opifera Nees, which sometimes contains a cavity holding a large quantity of this fluid.[2004] A similar oil (Aceite de Sassafras) is afforded on the Rio Negro by Nectandra Cymbarum Nees.[2005]
THYMELEÆ.
CORTEX MEZEREI.
Mezereon Bark; F. Ecorce de Mézéréon, Bois gentil; G. Seidelbast-Rinde.
Botanical Origin—Daphne Mezereum L., an erect shrub, 1 to 3 feet high, the branches of which are crowded with purple flowers in the early spring, before the full expansion of the oblong, lanceolate, deciduous leaves. The flowers are succeeded by red berries. It is a native of the hilly parts of almost the whole of Europe, from Italy to the Arctic regions, and extends eastward to Siberia. In Britain it occurs here and there in a few of the southern and midland counties, and even reaches Yorkshire and Westmoreland, but there is reason to think it is not truly indigenous. Gerarde, who was well acquainted with it, did not regard it as a British plant.
History—The Arabian physicians used a plant called Mázariyún, the effects of which they compared to those of euphorbium; it was probably a species of Daphne. The word mázariyún is, we are told by competent Arabic scholars, not of Arabic origin, but in all probability derived from the Greek idiom, in which however we are unable to trace its origin. D. Mezereum was known to the early botanists of Europe, as Daphnoides Chamælæa, Thymelæa, Chamædaphne. Tragus described it and figured it in 1546 under the name of Mezereum Germanicum. The bark had a place in the German pharmacy of the 17th century under the name of cortex Coccognidii s. Mezerei; the berries were the Cocca gnidia s. knidia of the old pharmacy.
Description—Mezereon has a very tough and fibrous bark easily removed in long strips which curl inwards as they dry; it is collected in winter and made up into rolls or bundles. The bark, which rarely exceeds ¹/₂₀ of an inch in thickness, has an internal greyish or reddish-brown corky coat which is easily separable from a green inner layer, white and satiny on the side next the wood. That of younger branches is marked with prominent leaf-scars. The bark is too tough to be broken, but easily tears into fibrous strips. When fresh, it has an unpleasant odour which is lost in drying; its taste is persistently burning and acrid. Applied in a moist state to the skin, it occasions, after some hours, redness and even vesication.
Microscopic Structure—The cambial zone is formed of about ten rows of delicate unequal cells. The libre consists chiefly of simple fibres alternating with parenchymatous bundles, and traversed by medullary rays. The fibres are very long,—frequently more than 3 mm., and from 5 to 10 mkm. in diameter, their walls being always but little thickened. In the outer part of the liber there occur bundles of thick-walled bast-tubes, while chlorophyll and starch granules appear generally throughout the middle cortical layer. The suberous coat is made up of about 30 dense rows of thin-walled tabular cells, which examined in a tangential section, have an hexagonal outline. Small quantities of tannic matter are deposited in the cambial and suberous zones.
Chemical Composition—The acrid principle of mezereon is a resinoid substance contained in the inner bark; it has not yet been examined. The fruits were found by Martius (1862) to contain more than 40 per cent. of a fatty, vesicating oil, which appears to be likewise present in the bark.
The name Daphnin has been given to a crystallizable substance obtained by Vauquelin in 1808 from Daphne alpina, and afterwards found by C. G. Gmelin and Baer in the bark of D. Mezereum. Zwenger in 1860 ascertained it to be a glucoside of bitter taste, having the composition C₁₅H₁₆O₉ + 2 OH₂, the same as that of Æsculin, the fluorescing principle occurring in the bark of Æsculus Hippocastanum and the root-bark of Gelsemium nitidum Michaux (G. sempervirens Aiton).—Coccognin, isolated in 1870 by Casselmann from the fruits of D. Mezereum, appears to be closely allied to if not identical with daphnin.
When daphnin is boiled with dilute hydrochloric or sulphuric acid, it furnishes Daphnetin, C₉H₆O₄ + OH₂, described by Zwenger as crystallizing in colourless prisms. By dry distillation of an alcoholic extract of mezereon bark, the same chemist obtained Umbelliferone (p. 322).
Uses—Mezereon taken internally is supposed to be alterative and sudorific, and useful in venereal, rheumatic and scrofulous complaints; but in English medicine it is never now given except as an ingredient of the Compound Decoction of Sarsaparilla. An ethereal extract of the bark has been introduced (1867) as an ingredient of a powerful stimulating liniment. On the Continent, the bark itself, soaked in vinegar and water, is applied with a bandage as a vesicant.
Substitutes—Owing to the difficulty of procuring the bark of the root of D. Mezereum, the herbalists who supply the London druggists have been long in the habit of substituting that of D. Laureola L., an evergreen species, not uncommon in woods and hedge-sides in several parts of England. The British Pharmacopœia (1864 and 1867) permits Cortex Mezerei to be obtained indiscriminately from either of these species, and does not follow the London College in insisting on the bark of the root alone. That of the stem of D. Laureola corresponds in structure with the bark of the true mezereon, but wants the prominent leaf-scars that mark the upper branches of the latter; it is reputed to be somewhat less acrid than mezereon bark. The mezereon bark of English trade is now mostly imported from Germany, and seems to be derived from D. Mezereum.
In France, use is made of the stem-bark of D. Gnidium L., a shrub growing throughout the whole Mediterranean region as far as Morocco. The bark is dark grey or brown, marked with numerous whitish leaf-scars, which display a very regular spiral arrangement. The leaves themselves, some of which are occasionally met with in the drug, are sharply mucronate and very narrow. As to structural peculiarities, the bark of D. Gnidium has the medullary rays more obvious and more loaded with tannic matters than those of D. Mezereum; but the middle cortical layer is less developed. The bark, which is called Ecorce de Gaoru, is employed as an epispastic.
ARTOCARPACEÆ.
CARICÆ.
Fructus Caricæ, Fici; Figs; F. Figues; G. Feigen.
Botanical Origin—Ficus Carica L., a deciduous tree, 15 to 20 feet in height, with large rough leaves, forming a handsome mass of foliage.
The native country of the fig stretches from the steppes of the Eastern Aral, along the south and south-west coast of the Caspian Sea (Ghilan, Mazanderan, and the Caucasus), through Kurdistan, to Asia Minor and Syria. In these countries the fig-tree ascends into the mountain region, growing undoubtedly wild in the Taurus at an elevation of 4,800 feet.[2006]
The fig-tree is repeatedly mentioned in the Scriptures, where with the vine it often stands as the symbol of peace and plenty. The fig was not known in Greece, the Archipelago, and the neighbouring coasts of Asia Minor during the Homeric age, though both were very common in the time of Plato. The fig-tree was early introduced into Italy, whence it reached Spain and Gaul. In the opinion of palæontologists the fig-tree was originally indigenous to the last named Mediterranean regions.
Charlemagne, a.d. 812, ordered its cultivation in Central Europe. It was brought to England in the reign of Henry VIII. by Cardinal Pole, whose trees still exist in the garden of Lambeth Palace. But it had certainly been in cultivation at a much earlier period, for the historian Matthew Paris relates[2007] that the year 1257 was so inclement that apples and pears were scarce in England, and that figs, cherries, and plums totally failed to ripen.
At the present day the fig-tree is found cultivated in most of the temperate countries both of the Old and New World.[2008] It is met with in the plains of north-western India, and in the outer hills of the north-western Himalaya as high as 5,000 feet; also in the Dekkan, and in Beluchistan and Afghanistan.
History—Figs were a valued article of food among the ancient Hebrews[2009] and Greeks, as they are to the present day in the warmer countries bordering the Mediterranean.[2010] In the time of Pliny many varieties were in cultivation. The Latin word Carica was first used to designate the dried fig of Caria, a strip of country in Asia Minor opposite Rhodes, an esteemed variety of the fruit corresponding to the Smyrna fig of modern times.
In a diploma granted by Chilperic II., king of the Franks, to the monastery of Corbie, a.d. 716, mention is made of “Karigas” in connection with dates, almonds and olives, by which we think dried figs (Caricæ) were intended.[2011] Dried figs were a regular article of trade during the middle ages, from the southern to the northern parts of Europe. In 1380 the citizens of Bruges, in regulating the duties which the “Lombards,” i.e. Italians, had to pay for their imports, quoted also figs from Cyprus and from Marbella, a place south-west of Malaga.[2012]
In England the average price between a.d. 1264 and 1398 was about 1¾d. per lb., raisins and currants being 2¾d.[2013]
Description—A fig consists of a thick, fleshy, hollow receptacle of a pear-shaped form, on the inner face of which grow a multitude of minute fruits.[2014] This receptacle, which is provided with an orifice at the top, is at first green, tough and leathery, exuding when pricked a milky juice. The orifice is surrounded, and almost closed by a number of thick, fleshy scales, near which and within the fig, the male flowers are situated, but they are often wanting or are not fully developed. The female flowers stand further within the receptacle, in the body of which they are closely packed; they are stalked, have a 5-leafed perianth and a bipartite stigma. The ovary, which is generally one-celled, becomes when ripe a minute, dry, hard nut, popularly regarded as a seed.
As the fig advances to maturity, the receptacle enlarges, becomes softer and more juicy, a saccharine fluid replacing the acrid milky sap. It also acquires a reddish hue, while its exterior becomes purple, brown, or yellow, though in some varieties it continues green. The fresh fig has an agreeable and extremely saccharine taste, but it wants the juiciness and refreshing acidity that characterize many other fruits.
If fig is not gathered its stalk loses its firmness, the fruit hangs pendulous from the branch, begins to shrivel and become more and more saccharine by loss of water, and ultimately, if the climate is favourable, it assumes the condition of a dried fig. On the large scale however, figs are not dried on the tree, but are gathered and exposed to the sun and air in light trays till they acquire the proper degree of dryness. They can only be preserved in those regions where the summer and autumn are very warm and dry.
Dried figs are termed by the dealers either natural or pulled. The first are those which have not been compressed in the packing, and still retain their original shape.[2015] The second are those which after drying have been made supple by squeezing and kneading, and in that state packed with pressure into drums and boxes.
Smyrna figs, which are the most esteemed sort, are of the latter kind. They are of irregular, flattened form, tough, translucent, covered with a saccharine efflorescence; they have a pleasant fruity smell and luscious taste. Figs of inferior quality, as those called in the market Greek Figs, differ chiefly in being smaller and less pulpy.
Microscopic Structure—The outer layer of a dried fig is made up of small, thick-walled and densely packed cells, so as to form a kind of skin. The inner lax parenchyme consists of larger thin-walled cells, traversed by vascular bundles and large, slightly branched, laticiferous vessels. The latter contain a granular substance not soluble in water. In the parenchyme, stellate crystals of oxalate of calcium occur, but in no considerable number.
Chemical Composition—The chemical changes which take place in the fig during maturation are important, but no researches have yet been made for their elucidation. The chief chemical substance in the ripe fig is grape sugar, which constitutes from 60 to 70 per cent. of the dried fruit. Gum and fatty matter appear to be present only in very small quantity. We have observed that unripe figs are rich in starch.
Production and Commerce—Dried figs were imported into the United Kingdom in 1872 to the amount of 141,847 cwt., of which 91,721 cwt. were shipped from Asiatic Turkey, the remainder being from Portugal, Spain, the Austrian territories and other countries. In 1876 the imports were 163,763 cwt., valued at £318,717.
Kalamata, in the Gulf of Messenia, Greece, and Cosenza in the Italian province of Calabria citeriore, are also particularly known as supplying figs to some parts of continental Europe. In 1876 the exports of Kalamata to Trieste were 9½ millions of kilogrammes.
Uses—Dried figs are thought to be slightly laxative, and as such are occasionally recommended in habitual constipation. They enter into the composition of Confectio Sennæ.
MORACEÆ.
FRUCTUS MORI.
Baccæ Mori, Mora; Mulberries; F. Mûres; G. Maulbeeren.
Botanical Origin—Morus nigra L., a handsome bushy tree, about 30 feet in height, growing wild in Northern Asia Minor, Armenia, and the southern Caucasian regions as far as Persia. In Italy, it was employed for feeding the silkworm until about the year 1434, when M. alba L. was introduced from the Levant,[2016] and has ever since been commonly preferred. Yet in Greece, in many of the Greek islands, Calabria and Corsica, the species planted for the silkworm is still M. nigra.
The mulberry tree is now cultivated throughout Europe, yet, excepting in the regions named, by no means abundantly. It ripens its fruit in England, as well as in Southern Sweden and Gottland, and in Christiania (Schübeler).
History—The mulberry tree is mentioned in the Old Testament,[2017] and by most of the early Greek and Roman writers. Among the large number of useful plants ordered by Charlemagne (a.d. 812) to be cultivated on the imperial farms, the mulberry tree (Morarius) did not escape notice.[2018] We meet with it also in a plan sketched a.d. 820, for the gardens of the monastery of St. Gall in Switzerland.[2019] The cultivation of the mulberry in Spain is implied by a reference to the preparation of Syrup of Mulberries in the Calendar of Cordova,[2020] which dates from the year 961.
A curious reference to mulberries, proving them to have been far more esteemed in ancient times than at present, occurs in the statutes of the abbey of Corbie of Normandy, in which we find a Brevis de Melle, showing how much honey the tenants of the monastic lands were required to pay annually, followed by a statement of the quantity of Mulberries which each farm was expected to supply.[2021]
Description—The tree bears unisexual catkins; the female, of an ovoid form, consists of numerous flowers with green four-lobed perianths and two linear stigmas. The lobes of the perianth overlapping each other become fleshy, and by their lateral aggregation form the spurious berry, which is shortly stalked, oblong, an inch in length, and, when ripe, of an intense purple. By detaching a single fruit, the lobes of the former perianth may be still discerned. Each fruit encloses a hard lenticular nucule, covering a pendulous seed with curved embryo and fleshy albumen.
Mulberries are extremely juicy and have a refreshing, subacid, saccharine taste; but they are devoid of the fine aroma that distinguishes many fruits of the order Rosaceæ.
Chemical Composition—In an analysis made by H. van Hees (1857) 100 parts of mulberries yielded the following constituents:—
Glucose and uncrystallizable sugar 9·19
Free acid (supposed to be malic) 1·86
Albuminous matter 0·39
Pectic matter, fat, salts, and gum 2·03
Ash 0·57
Insoluble matters
(the seeds, pectose, cellulose, &c.) 1·25
Water 84·71
With regard to the results of researches on other edible fruits, made about the same time in the laboratory of Fresenius, it would appear that the mulberry is one of the most saccharine, being only surpassed by the cherry (10·79 of sugar) and grape (10·6 to 19·0).[2022] It is richer in sugar than the following, namely:—
Raspberries, yielding 4 per cent. of sugar and 1·48 of (malic) acid.
Strawberries ” 5·7 ” ” 1·31 ” ”
Whortleberries ” 5·8 ” ” 1·34 ” ”
Currants ” 6·1 ” ” 2·04 ” ”
The amount of free acid in the mulberry is not small, nor is it excessive. The small proportion of insoluble matters is worthy of notice in comparison, for instance with the whortleberry, which contains no less than 13 per cent. The colouring matter of the mulberry has not been examined. The acid is probably not simply malic, but in part tartaric.
Uses—The sole use in medicine of mulberries is for the preparation of a syrup employed to flavour or colour any other medicines. In Greece, the fruit is submitted to fermentation, thereby furnishing an inebriating beverage.
CANNABINEÆ.
HERBA CANNABIS.
Cannabis Indica; Indian Hemp; F. Chanvre Indien; G. Hanfkraut.
Botanical Origin—Cannabis sativa L., Common Hemp, an annual diœcious plant, native of Western and Central Asia, cultivated in temperate as well as in tropical countries.
It grows wild luxuriantly on the banks of the lower Ural and Volga near the Caspian Sea, extending thence to Persia, the Altai range, and Northern and Western China. It is found in Kashmir and on the Himalaya, growing 10 to 12 feet high, and thriving vigorously at an elevation of 6000 to 10,000 feet. It likewise occurs in Tropical Africa, on the eastern and western coasts as well as in the central tracts watered by the Congo and Zambesi, but whether truly indigenous is doubtful. It has been naturalized in Brazil, north of Rio de Janeiro, the seeds having been brought thither by the negroes from Western Africa. The cultivation of hemp is carried on in many parts of continental Europe, but especially in Central and Southern Russia.
The hemp plant grown in India exhibits certain differences as contrasted with that cultivated in Europe, which were noticed by Rumphius in the 17th century, and which (about a.d. 1790), induced Lamarck to claim for the former plant the rank of a distinct species, under the name of Cannabis indica. But the variations observed in the two plants are of so little botanical importance and are so inconstant, that the maintenance of C. indica as distinct from C. sativa has been abandoned by general consent.
In a medicinal point of view, there is a wide dissimilarity between hemp grown in India and that produced in Europe, the former being vastly more potent. Yet even in India there is much variation, for, according to Jameson, the plant grown at altitudes of 6000 to 8000 feet affords the resin known as Charas, which cannot be obtained from that cultivated on the plains.[2023]
History—Hemp has been propagated on account of its textile fibre and oily seeds from a remote period.
The ancient Chinese herbal called Rh-ya, written about the 5th century b.c., notices the fact that the hemp plant is of two kinds, the one producing seeds, the other flowers only.[2024] In Susruta, Charaka and other early works on Hindu medicine, hemp (B’hanga) is mentioned as a remedy. Herodotus states that hemp grows in Scythia both wild and cultivated, and that the Thracians made garments from it which can hardly be distinguished from linen. He also describes how the Scythians expose themselves as in a bath to the vapour of the seeds thrown on hot coals.[2025]
The Greeks and Romans appear to have been unacquainted with the medicinal powers of hemp, unless indeed the care-destroying Νηπενθές should, as Royle has supposed, be referred to this plant. According to Stanislas Julien,[2026] anæsthetic powers were ascribed by the Chinese to preparations of hemp as early as the commencement of the 3rd century.
The employment of hemp both medical and dietetic appears to have spread slowly through India and Persia to the Arabians, amongst whom the plant was used in the early middle ages. The famous heretical sect of Mahomedans, whose murderous deeds struck terror into the hearts of the Crusaders during the 11th and 12th centuries, derived their name of Hashishin, or, as it is commonly written, assassins, from hashísh the Arabic for hemp,[2027] which in certain of their rites they used as an intoxicant.[2028] In 1286 of our era, the Sultan of Egypt, Bibars al Bondokdary, prohibited the sale of hashish, the monopoly of which had been leased before.[2029]
The use of hemp (bhang) in India was particularly noticed by Garcia de Orta[2030] (1563), and the plant was subsequently figured by Rheede, who described the drug as largely used on the Malabar coast. It would seem about this time to have been imported into Europe, at least occasionally, for Berlu in his Treasury of Drugs, 1690, describes it as coming from Bantam in the East Indies, and “of an infatuating quality and pernicious use.“
It was Napoleon’s expedition to Egypt that was the means of again calling attention to the peculiar properties of hemp, by the accounts of De Sacy (1809) and Rouger (1810). But the introduction of the Indian drug into European medicine is of still more recent date, and is chiefly due to the experiments made in Calcutta by O’Shaughnessy in 1838-39.[2031] Although the astonishing effects produced in India by the administration of preparations of hemp are seldom witnessed in the cooler climate of Britain, the powers of the drug are sufficiently manifest to give it an established place in the pharmacopœia.
Production—Though hemp is grown in many parts of India, yet as a drug it is chiefly produced in a limited area in the districts of Bogra and Rājshāhi, north of Calcutta, where the plant is cultivated for the purpose in a systematic manner. The retail sale, like that of opium and spirits, is restricted by a license, which in 1871-2 produced to the Government of Bengal about £120,000, while upon opium (chiefly consumed in Assam) the amount raised was £310,000.[2032] Bhang is one of the principal commodities imported into India from Turkestan.
Description—The leaves of hemp have long stalks with small stipules at their bases, and are composed of 5 to 7 lanceolate-acuminate leaflets, sharply serrate at the margin. The loose panicles of male flowers, and the short spikes of female flowers, are produced on separate plants, from the axils of the leaves. The fruits, called Hemp-seeds, are small grey nuts or achenes, each containing a single oily seed. In common with other plants of the order, hemp abounds in silica which gives a roughness to its leaves and stems. In European medicine, the only hemp employed is that grown in India, which occurs in two principal forms, namely:—
1. Bhang, Siddhī or Sabzī (Hindustani); Hashish or Qinnaq (Arabic). This consists of the dried leaves and small stalks, which are of a dark green colour, coarsely broken, and mixed with here and there a few fruits. It has a peculiar but not unpleasant odour, and scarcely any taste. In India, it is smoked either with or without tobacco, but more commonly it is made up with flour and various additions into a sweetmeat or majun,[2033] of a green colour. Another form of taking it is that of an infusion, made by immersing the pounded leaves in cold water.
2. Ganja (Hindustani); Qinnab (Arabic); Guaza[2034] of the London drug-brokers. These are the flowering or fruiting shoots of the female plant, and consist in some samples of straight, stiff, woody stems some inches long, surrounded by the upward branching flower-stalks; in others of more succulent and much shorter shoots, 2 to 3 inches long, and of less regular form. In either case, the shoots have a compressed and glutinous appearance, are very brittle, and of a brownish-green hue. In odour and in the absence of taste ganja resembles bhang. It is said that after the leaves which constitute bhang have been gathered, little shoots sprout from the stem, and that these picked off and dried form what is called ganja.[2035]
Chemical Composition—The most interesting constituents of hemp, from a medical point of view, are the resin and volatile oil.
The former was first obtained in a state of comparative purity by T. and H. Smith in 1846.[2036] It is a brown amorphous solid, burning with a bright white flame and leaving no ash. It has a very potent action when taken internally, two-thirds of a grain acting as a powerful narcotic, and one grain producing complete intoxication. From the experiments of Messrs. Smith, it seems to us impossible to doubt that to this resin the energetic effects of cannabis are mainly due.
When water is repeatedly distilled from considerable quantities of hemp, fresh lots of the latter being used for each operation, a volatile oil lighter than water is obtained, together with ammonia. This oil, according to the observations of Personne (1857), is amber-coloured, and has an oppressive hemp-like smell. It sometimes deposits an abundance of small crystals. With due precautions it may be separated into two bodies, the one of which, named by Personne Cannabene,[2037] is liquid and colourless, with the formula C₁₈H₂₀; the other, which is called Hydride of Cannabene, is a solid, separating from alcohol in platy crystals to which Personne assigns the formula C₁₈H₂₂. He asserts that cannabene has indubitably a physiological action, and even claims it as the sole active principle of hemp. Its vapour he states to produce when breathed a singular sensation of shuddering, a desire of locomotion, followed by prostration and sometimes by syncope.[2038] Bohlig in 1840 observed similar effects from the oil, which he obtained from the fresh herb, just after flowering, to the extent of 0·3 per cent.
It remains to be proved whether an alkaloid is present in hemp, as suggested by Preobraschensky.[2039]
The other constituents of hemp are those commonly occurring in other plants. The leaves yield nearly 20 per cent. of ash.
As to the resin of Indian hemp, Bolas and Francis in treating it with nitric acid, converted it into Oxycannabin, C₂₀H₂₀N₂O₇. This interesting substance may, they say, be obtained in large prisms from a solution in methylic alcohol. It melts at 176° C. and then evaporates without decomposition; it is neutral.[2040] One of us (F.) has endeavoured to obtain it from the purified resin of charas, but without success.
Uses—Hemp is employed as a soporific, anodyne, antispasmodic, and as a nervous stimulant. It is used in the form of alcoholic extract, administered either in a solid or liquid form. In the East it is consumed to an enormous extent by Hindus and Mahomedans, who either smoke it with tobacco, or swallow it in combination with other substances.[2041]
Charas.
No account of hemp as a drug would be complete without some notice of this substance, which is regarded as of great importance by Asiatic nations.
Charas or Churrus is the resin which exudes in minute drops from the yellow glands, with which the plant is provided in increasing number according to the elevated temperature (and altitude?) of the country where it grows. The varieties of hemp richest in resin, at least in the Laos country in the Malayan Peninsula, scarcely attain the height of 3 feet, and show densely curled leaves.[2042] Charas is collected in several ways:—one is by rubbing the tops of the plants in the hands when the seeds are ripe, and scraping from the fingers the adhering resin. Another is thus performed:—men clothed in leather garments walk about among growing hemp, in doing which the resin of the plant attaches itself to the leather, whence it is from time to time scraped off. A third method consists in collecting, with many precautions to avoid its poisonous effects, the dust which is caused when heaps of dry bhang are stirred about.[2043]
By whichever of these processes obtained, charas is of necessity a foul and crude drug, the use of which is properly excluded from civilized medicine. As before remarked (p. 547) it is not obtainable from hemp grown indiscriminately in any situation even in India, but is only to be got from plants produced at a certain elevation on the hills.
The best charas, which is that brought from Yarkand, is a brown, earthy-looking substance, forming compact yet friable, irregular masses of considerable size. Examined under a strong pocket lens, it appears to be made up of minute, transparent grains of brown resin, agglutinated with short hairs of the plant. It has a hemp-like odour, with but little taste even in alcoholic solution. A second and a third quality of Yarkand charas represent the substance in a less pure state. Charas viewed under the microscope exhibits a crystalline structure, due to inorganic matter. It yields from ¼ to ⅓ of its weight of an amorphous resin, which is readily dissolved by bisulphide of carbon or spirit of wine. The resin does not redden litmus, nor is it soluble in caustic potash. It has a dark brown colour, which we have not succeeded in removing by animal charcoal. The residual part of charas yields to water a little chloride of sodium, and consists in large proportion of carbonate of calcium and peroxide of iron. These results have been obtained in examining samples from Yarkand.[2044] Other specimens which we have also examined, have the aspect of a compact dark resin.