Volume 5 — LESSON IV
Reading edition
CHEMISTRY OF FOODS
Four general classes of food
The chemistry of carbon compounds and the general composition of plant and of animal substances were discussed in Lesson III. We are now prepared to take up the chemistry of food. The chemistry of food substances will be considered under the common divisions of carbohydrates, fats, proteids, and mineral salts. (See "Classification of Organic Carbon Compounds," Lesson III, p. 89.)
Classes vs. groups of related compounds
In the food tables and analyses commonly published, the above terms are used with very little explanation, and read by the average person with meager comprehension. When one reads that a food is composed of glucose, citric acid, or globulin, he is likely to become confused, not being able to understand how a food at one time can be said to be composed of carbohydrates, proteids, and fats, and at another time to be composed of other substances. The explanation is that the first classification does not refer to definite chemical substances, but to groups of related compounds having properties in common.
The different methods of analyzing food
There is still another way of giving the chemical composition of a food, namely, to specify the chemical elements that it contains. It will be remembered that the relation between chemical elements and chemical compounds was explained in the first lesson. As an example, I will take the analysis of milk. We will first say that milk contains a certain percentage of protein, carbohydrates, and fat. We might then say that the proteid of milk is part casein and part albumin, and that the albumin contains certain percentages of oxygen, sulfur, etc.; also that the chief carbohydrate in milk is milk-sugar, which in turn is composed of carbon, hydrogen, and oxygen. Or, we could consider the milk as a whole, without dividing it into groups, and give the per cent of each chemical element in the milk. Thus, the carbon of the proteid, milk-sugar, and fat would be all considered together, and show a certain per cent of carbon in the milk as a whole.
CARBOHYDRATES
The word carbohydrate means carbon combined with water; that is, the element carbon is combined with hydrogen and oxygen, which exist in the carbohydrate compound in the same proportion as they exist in water.
The carbohydrates are closely related chemically to the aldehydes and the alcohols, so far as their composition is concerned (See "Aldehydes and Ethers," Lesson III, p. 93), but this does not imply that they have the same physiological effect in the animal body.
CLASSIFICATION OF CARBOHYDRATES
The carbohydrates are divided by the chemist into three classes known as
a Monosaccharids
b Disaccharids
c Polysaccharids
The principal subdivisions found in these classes of carbohydrate foods are given in the following table, arranged in the order of their importance:
MonosaccharidsDisaccharidsPolysaccharids
1 Glucose or grape-sugar1 Cane-sugar 1 Starch
(formerly called dextrose)
2 Pentoses2 Maltose2 Glycogen
(of which there are several) 3 Lactose3 Cellulose
3 Levulose 4 Gums
4 Galactose 5 Inulin
a MONOSACCHARIDS
1 GLUCOSE OR GRAPE-SUGAR (C6H12O6)
Glucose or grape-sugar is the most important sugar known from the standpoint of the physiological chemist. This sugar is normally found in considerable quantities in human blood, and is absolutely essential to the life-process, a fact which forms an amusing contrast with the popular conception of the term glucose as something injurious or poisonous.
Sources of glucose
Glucose is found in honey, and in nearly all fruits, grains, and sweets. (For "Sweets" see Lesson VIII, Vol. II, p. 324). It may be taken into the human body directly from such fruits, or it may originate by the digestion of other carbohydrates.
Pure glucose crystallizes and resembles cane-sugar, but is not so sweet. The glucose of commerce, sold as sirup, is a product manufactured from corn, or other starches, and will be considered more in detail under the heading starch. (See "Polysaccharids," p. 114).
2 PENTOSES (C5H10O5)
Sources of pentoses
Pentoses form a group of sugars, the chemical formula of which contains five atoms of carbon. Each different pentose could be studied in detail by the chemist, but the pentoses are of no particular interest to the food scientist. They exist, however, in the coarse parts of plants, such as stalks and leaves, and are of considerable importance in animal feeding. From the standpoint of human food we will remember that the carbohydrates of green plants contain a percentage of these pentoses, but as they are never removed from the plant separately, as are other sugars, we must consider their physiological effect in the particular plant rather than separately.
3 LEVULOSE (C6H12O6)
This is the companion sugar to glucose and exists in many fruits. Levulose is often called "fruit-sugar." The composition of levulose is exactly the same as glucose, but the atoms are combined in different ways.
Levulose, for all practical purposes, may be considered the equivalent of glucose in the human body. It is sweeter than glucose and more closely resembles cane-sugar.
4 GALACTOSE (C6H12O6)
Galactose, which is of the same composition as levulose, is another companion sugar to glucose, and is formed by the digestion of lactose or milk-sugar.
b DISACCHARIDS
1 CANE-SUGAR (C12H22O11)
Just as there are three monosaccharid sugars with six carbon atoms each, so there are three disaccharid sugars which have twelve carbon atoms each. The first of these is cane-sugar. It is commercially made from either sugar-cane or sugar-beets, and is identical in chemical composition from either source.
Cane sugar, when digested in the human body, or by artificial means, combines with water, and forms glucose and levulose, as shown by the following equation:
C12H22O11 + H2O = C6H12O6 + C6H12O6 Cane-sugar + Water = Glucose + Levulose
2 MALTOSE (C12H22O11)
Maltose—how formed
Maltose is the second member of the disaccharid group, and is of the same composition as the other two. Maltose derives its name from malt. It is formed from the starch of grains by a process of digestion which may be performed in the animal body, or by the process of malting. Maltose, like cane-sugar, can be further digested into monosaccharid sugars, but upon such digestion, instead of forming two separate simple sugars, it is wholly converted into glucose.
The reader will now understand the meaning of the terms monosaccharid, disaccharid, and polysaccharid. MONO, which means one, is the simplest form of carbohydrates. Disaccharids (DI, meaning two), split up to form two simple sugars. Polysaccharids (POLY, meaning many) are complex compounds which form many simple sugars.
3 LACTOSE (C12H22O11)
Lactose exists in milk and has the same formula as cane-sugar. Milk contains about five per cent of this sugar.
When lactose is digested it combines with water as does cane-sugar, but instead of yielding glucose and levulose, it yields glucose and galactose.
c POLYSACCHARIDS
1 STARCH
The chemical formula of starch and other polysaccharids is written (C6H10O5)n. This means that the proportion of the elements is according to the figures given, but the number of atoms that are supposed to be combined is many times greater than five, and is not accurately known. This is purely theoretical, and of no practical importance, except that it shows that the polysaccharid is capable of being digested or broken up into many simple carbohydrate compounds.
Sources of starch
Starch is the most abundant carbohydrate known. It is the chief constituent of all cereals, and is found in large quantities in green fruits and tuberous plants. Starch occurs in small granules, varying greatly in size in different foods.
Potato starch
Potatoes are composed chiefly of starch and water. The starch grains of potatoes can almost be distinguished with the naked eye. These starch granules are not atoms or molecules in the chemical sense, but are small receptacles in which starch has been deposited by the growing plant. When cooked or boiled in water these starch grains swell into a mushy, pasty or gelatinous mass; when cooked in dry heat until they begin to turn brown, they are changed into a compound related to the gum group, known as dextrin.
Solubility of starch
Starch does not dissolve in water as do sugars. If starch is treated with digestive fluids, such as saliva, or with certain acids, it goes through a complex process of digestion in which it is first turned into soluble starch, then into the various forms of dextrin or gums, and finally into maltose or malt-sugar.
How corn-starch is changed into glucose
Corn-starch, treated with weak sulfuric acid, changes the starch into glucose. The ordinary glucose or corn-sirup is not all changed by this process, into pure glucose, but contains some maltose and other gummy compounds; hence it will not crystallize or granulate into pure sugar. After the acid has changed the starch into glucose it (the acid) is neutralized with an alkali. A crude compound is thus formed, which settles to the bottom of the tank, and from which the glucose can be easily separated. Commercial glucose is now very extensively used in the manufacture of various food products, especially confectionery. Pure glucose is a wholesome food, but there is some danger that the commercial product may (due to carelessness in manufacturing, or to the use of cheap and impure acid) contain various mineral poisons. Government testing of glucose and similar manufactured products is, in the writer's opinion, fully as essential as the government inspection of packing-house products.
How starch is changed into maltose
Just as glucose may be manufactured from starch treated with dilute acids, so maltose may be made by treating starch with malt. The brewing of beer depends upon the chemical changes induced in starch by malt. Barley is ordinarily used for this purpose. The barley is sprouted in a warm, damp room, and a process of starch digestion begins, which is necessary in order that the young barley sprouts may grow. This changes the starch into maltose. The digestive principle developed in the barley-malt may be utilized to malt other grains by mixing them with the sprouted barley.
Maltose in foods
If this process of malting is stopped at the proper time, and the sugar dissolved, and extracted, a product is formed consisting chiefly of the sugar maltose. This is the basis of malt extract, malt honey, and many similar foods put on the market, which are claimed by the manufacturers to have wonderful dietetic and curative values.
2 GLYCOGEN
Glycogen—how formed and where stored
Glycogen is commonly called animal-starch. It exists in the liver in small quantities. All carbohydrates are digested in the alimentary canal and absorbed into the blood in the form of simple sugars of the glucose group. When these sugars reach the liver they are again built up into a complex carbohydrate very similar to starch in composition. This glycogen or animal-starch is stored in the liver until the body has need of it, when it is changed into glucose and given back to the body in the form of energy. (See "Metabolism of Carbohydrates," Lesson VI, p. 202).
3 CELLULOSE
Cellulose—its purpose, source, and importance
Cellulose, from the standpoint of human nutrition, is not a food product, being insoluble by the digestive juices, but it is very important in the digestion and the alimentation of other foods. Its chief purpose is to excite stomach and intestinal peristalsis. All plant products in their natural form contain some cellulose, though the percentage is very small in such grains as rice and barley. The bran of wheat or of corn is chiefly cellulose. Wood is almost pure cellulose.
Cellulose can be digested by strong acids into simple carbohydrates, in the same way that starch may be. Sugar can be manufactured from wood or rags, but the process is yet too expensive to be applied commercially. Some of us may live to see the time when the chief food of mankind will be manufactured from scrap lumber and waste paper. Bacteria have the power of digesting cellulose. The bacterial action or fermentation in the human intestines may cause a small amount of cellulose to be digested, but the quantity is of no consequence from a nutritive point of view.
4 GUMS
The gums include a group of rather complex carbohydrates which are intermediate between starches and sugars. From plants are derived many varieties of gums which have various commercial uses in the market, such as gum arabic.
I have already spoken of the formation of dextrin from starch. Dextrin has no particular dietetic qualities that do not exist in starch. It is, in fact, starch arrested at an intermediate point of digestion.
Pectins in fruits
Pectins are a group of gummy substances found in fruits, especially green fruits which are in the process of being formed into sugar. These pectins form the basis of fruit jellies. Green grapes, as every housewife knows, will make better jelly than ripe grapes. This is because the pectins in ripe grapes have been transformed into sugar. The pectins in fruit are in most cases wholesome enough, though it would seem the better part of wisdom to eat all fruits in the ripened state, after Nature has completed her work.
5 INULIN
Inulin is a compound closely related to starch, and upon digestion with acids, yields levulose just as starch yields glucose. It is of no particular interest to the food chemist, as it exists in but very small quantities in starch, and has no distinct dietetic value.
FATS AND OILS
Composition and formation of fats and oils
The fats and oils in food products, whether of plant or animal origin, contain the elements carbon, hydrogen, and oxygen. These fats are formed by uniting the fatty acids with glycerin, which belongs to the alcohol group. The particular fat that is formed takes its name from the acid which enters into its composition; thus stearic acid unites with glycerin to form the fat stearin.
The following table gives the names of a few of the more common fatty acids and their corresponding fats:
Stearic acid ... ... Stearin
Palmitic acid ... ...Palmitin
Oleic acid ... ...Olein
Butyric acid ... ...Butyrin
Distinction between tallow and lard
A fat from any source will usually contain several of these chemical compounds. The ordinary animal fats, such as tallow and lard, are formed chiefly of the two fats stearin and olein. The different proportions of these fats will determine the melting point or hardness of the mixed product. Olein is a liquid at ordinary temperature, while stearin is solid. The reason that tallow is a firmer fat than lard or butter is because it contains a larger per cent of stearin.
Olive-oil, cottonseed-oil, and other vegetable oils contain large per cents of olein, which accounts for their being liquid at ordinary temperature.
Dairy butter vs. artificial butter
Butyrin is a fat found in small quantities in dairy butter, and does not exist in cottonseed-oil and other fats from which oleomargarin is manufactured. This is the reason that artificial butter lacks the flavor of the dairy product, and this is remedied to some extent by churning the fats of the cottonseed-oil and tallow with fresh cream, which imparts a small quantity of the butyrin and similar compounds to the oleomargarin and gives the characteristic flavor of butter.
Oils as active poisons
Besides the more common fats herein mentioned there are many other fats that exist in certain vegetable oils in small proportions. These fats give the oils their characteristic properties, and may render them unfit for food. Some oils are active poisons, such as croton-oil, which is the most powerful physic known. The power of all physics and cathartic drugs is measured by the active poisons they contain.
Packing-house uses of stearin and olein
When fats are heated to a high temperature they decompose and form various products, some of which are irritating and poisonous to the human system. In the manufacture of packing-house and cottonseed products the stearin is often separated from the olein. The granular appearance of pure leaf lard is due to crystals of stearin. In the packing-house stearin is separated from the tallow in large quantities. The stearin is used to make candles, etc., while the olein is used for food purposes in this country in the form of oleomargarin, while in Europe it is used under its right name as a cooking product. It is equally as wholesome, if not more so, than lard.
Rancid fats made edible
Fats may become rancid; this is caused by the decomposition of fat due to its uniting with the oxygen of the air. Rancid fats and nut-kernels can be restored and made edible by heating them in an oven until the oxidized fat is neutralized by the heat.
PROTEIDS OR NITROGENOUS FOOD SUBSTANCES
Proteids defined
The food substances which contain nitrogen are commonly called proteids, or, if these compounds are considered together, the name protein may be given the group. Protein is not a single compound, but includes all substances which contain the element nitrogen in such combinations as are available for assimilation in the human body.
Only proteid foods contain nitrogen
Protein is the most important group of nutrients in the animal body. The proteid substances in the body must be formed from proteids taken in the form of food, because only proteid foods contain the element nitrogen. All proteids contain nitrogen, but all nitrogen does not contain protein. All proteids, therefore, are nitrogenous compounds.
Formation of organic nitrogen
The animal body does not possess the power of combining elementary nitrogen with other elements. Bacteria have the power to utilize the nitrogen of the air to form mineral salts or nitrates. Plants have the power to unite the nitrogen derived from these nitrates with carbon, oxygen, and hydrogen. In this way organic nitrogen, or proteids, are formed. The animal body may digest these proteids, however, and transform them into other proteid compounds. All proteids contain carbon, hydrogen, oxygen and nitrogen; most of them contain sulfur, and a few contain phosphorus, iron, copper, and bromid.
The percentage by weight of the various elements which form proteid matter is about as follows:
Carbon ... ...52%
Hydrogen ... ...7%
Oxygen ... ...22%
Nitrogen ... ...16%
Sulfur ... ...2%
Phosphorus ... ...1%
The following table gives three groups of proteid substances:
Simple Proteids Compound Proteids Albuminoids
Albumins Respiratory pigments Collagen
Globulins Gluco Proteids Gelatin
Nucleo albumins Nucleins Elastin
Albuminates Nucleo proteids Reticulin
Coagulated proteids Lecith albumins Keratin
Proteoses (Albumoses)
Peptones
Amido compounds
Besides these real proteids there are a few substances known as amido compounds which exist in small quantities in vegetables, and a number of nitrogenous substances which exist in meat and meat extracts, which are not true proteids, as they have little or no nutritive value, but act as stimulants or irritants in the body.
Ptomains—how formed
Ptomains are another class of substances which are often found in food products. They are formed by the growth of bacteria, and are in reality the nitrogenous waste-products of bacterial life. Ptomains develop in meats and dairy products held in cold storage, and are sometimes the cause of serious poisoning. Nitrogenous waste-products will be further discussed in Lesson VI, under "Metabolism of Proteids." (See p. 209.)
Sources, coagulation and solubility of albumin
Albumin is one of the commonest and simplest forms of proteids known. It is found in the white of eggs, in milk, and in blood. It is coagulated by heat, and by certain chemicals, such as acids, alcohol, and strong alkalis. Albumin is soluble in water and in weak solutions of salt, but it is not soluble in very strong salt solutions.
Sources and properties of globulins
Globulins are much like albumin, but are not soluble in water. They are, however, soluble in dilute salt solutions. Globulins exist in considerable quantities in the yolk of eggs, and in the blood. The globulin in the body could not remain in solution if there were not always present a small quantity of salt in the blood. There are several types of globulins. The fibrinogen of the blood, which coagulates, forming clots, when the blood is exposed to the air, is a globulin. Hemoglobin, which is the chief component of red blood-corpuscles, and which unites with the oxygen in the lungs and carries it to the various tissues of the body, is another form of globulin, and one which contains a considerable amount of iron.
Sources of casein
Casein is the most important proteid substance in milk, and is familiar to all as the curd or white substance of clabbered milk. A related form of vegetable casein is found in leguminous seeds, such as beans and peas.
Sources of proteoses and peptones
Proteoses and peptones are proteids that are formed by the digestion of other proteids. They exist in the alimentary canal in the partly digested food. Peptones are readily soluble, and for this reason are easily absorbed through the walls of the digestive organs. (See Lesson V, "Digestive Organs"—[The Stomach], p. 137; also "Composition of Gastric Juice," p. 147).
MINERAL SALTS IN FOOD
Vegetable mineral salts vs. common table salt
The subject of salt in food has received considerable attention and discussion by scientific investigators, and many theories have been advanced by those interested in hygiene as to the effect of common salt used in food. The tissues and organs of the body contain certain salts, without which life could not exist, but it does not follow that these salts need to be supplied in mineral form. Common table salt is an inorganic substance, while the mineral salts in green and fresh vegetables are organic, and readily convertible, therefore a valuable aid in the digestion of other foods. A diet of sugar, pure oil, and artificially prepared proteids would be absolutely unwholesome and would fail to nourish the body for any length of time because of the lack of mineral salts. Foods containing mineral salts All natural food products, whether of vegetable or animal origin, contain a limited but ever-present amount of mineral salts. This is especially true of milk, eggs, and the seeds and green portion of plants. The amount of salts in the human body is considerable, especially the calcium phosphates of the bones, but the salts that need to be supplied daily in food is small because the salts are not consumed as rapidly as are other elements of nutrition.
Grains deficient in salt
Some grains, especially rice and corn, are somewhat deficient in salts. At the Kansas Experiment Station some pigs were fed exclusively on corn, and others on grain and green forage. At a certain age the pigs were killed, and the bones weighed and tested for strength. The bones of the pigs which had been fed on a corn diet, which is deficient in mineral salts, were about half as heavy and strong as the bones of the pigs fed in a more natural way.