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The Principles of Chemistry, Volume II

Note 35 — Chapter XIX · PHOSPHORUS AND THE OTHER ELEMENTS OF THE FIFTH GROUP

George Kamensky translation

According to Mitscherlich's determination, the vapour density of arsenious anhydride is 199 (H = 1)—that is, it answers to the molecular formula As4O6. Probably this is connected with the fact that the molecule of free arsenic contains As4. V. Meyer and Biltz, however, showed (1889) that at a temperature of about 1,700° the vapour density of arsenic corresponds with the molecule As2, and not As4, as at lower temperatures.

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