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The Principles of Chemistry, Volume II

Note 12 — Chapter XIX · PHOSPHORUS AND THE OTHER ELEMENTS OF THE FIFTH GROUP

George Kamensky translation

Besides the hydrates enumerated, a compound, PH3O, should correspond with PH3. This hydrate, which is analogous to hydroxylamine, is not known in a free state, but it is known as triethylphosphine oxide, P(C2H5)3O, which is obtained by the oxidation of triethylphosphine, P(C2H5)3. It must be observed that there may also be lower oxides of phosphorus corresponding with PH3, like N2O and NO, and there are even indications of the formation of such compounds, but the data concerning them cannot be considered as firmly established.

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