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The History of Chemistry, Volume 1 (of 2)

Volume 1 — CHAPTER VIII. OF THE ATTEMPTS TO ESTABLISH A THEORY IN CHEMISTRY. (continued 2)

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Macquer, conjointly with Baumé, subjected the grains of crude platinum, to which the attention of chemists had been newly drawn, to experiment. Their principle object was to examine its fusibility and ductility. They succeeded in fusing it imperfectly, by means of a burning mirror, and found that the grains thus treated were not destitute of ductility. But upon the whole the experiments of these chemists threw but little light upon the subject. Many years elapsed before chemists were able to work this refractory metal, and to make it into vessels fitted for the uses of the laboratory. For this important improvement, which constitutes an era in chemistry, the chemical world was chiefly indebted to Dr. Wollaston.

In the year 1750 M. Macquer was charged with a commission by the court. There existed at that time in Brittany a man, the Count de la Garaie, who, yielding to a passion for benevolence, had for forty years devoted himself to the service of suffering humanity. He had built an hospital by the side of a chemical laboratory: he took care of the patients in the hospital himself; and treated them with medicines prepared in his laboratory. Some of these were new, and, in his opinion, excellent medicines; and he offered to sell them to government for the service of his hospital. Macquer was charged by government with the examination of these medicines. The project of the Count de la Garaie was to extract the salutary parts of minerals, by a long maceration with neutral salts. Among other things he had prepared a mercurial tincture, by a process which lasted several months: but this tincture was merely a solution of corrosive sublimate in spirit of wine. Such is the history of most of those boasted secrets; sometimes they are chimerical, and sometimes known to all the world, except to those who purchase them.

M. Macquer had the fortune to live at a time when chemistry began to be freed from the reveries of alchymists; but methodical arrangement was a merit still unknown to the elementary chemical books, especially in France, where a residue of Cartesianism added to the natural obscurity of the science, by surcharging it with pretended mechanical explanations. Macquer was the first French chemist who gave to an elementary treatise the same clearness, simplicity, and method, which is to be found in the other branches of science. This was no small merit, and undoubtedly contributed considerably to the rapid improvement of the science which so speedily followed. His elements of chemistry were translated into different languages, especially into English; and long constituted the textbook employed in the different European universities. Dr. Black recommended it for many years in the University of Edinburgh. Indeed, it was only superseded in consequence of the new views introduced into chemistry by Lavoisier, which, requiring a new language to render them intelligible, naturally superseded all the elementary chemical books which had preceded the introduction of that language.

Macquer, during a number of years, delivered regular courses of chemical lectures, conjointly with Baumé. In these courses he preferred that arrangement which appeared to him to require the least preliminary knowledge of chemistry. He described the experiments, stated the facts with clearness and precision, and explained them in the way which appeared to him most plausible, according to the opinions generally received; but without placing much confidence in the accuracy of these explanations. He thought it necessary to theorize a little, to enable his pupils the better to connect the facts and to remember them; and to put an end to that painful state of uncertainty which always results from a collection of facts without any theoretical links to bind them together. When the discoveries of Lavoisier began to shake the foundation of the Stahlian theory, Macquer was old; and it appears from a letter of his, published by Delametherie in the Journal de Physique, that he was alarmed at the prophetic announcements of Lavoisier in the academy that the reign of Phlogiston was drawing towards an end. M. Condorcet assures us that his attachment to theory, by which he means phlogiston, was by no means strong;184 but his own letter to Delametherie rather shows that this statement was not quite correct. How, indeed, could he fail to experience an attachment to opinions which it had been the business of his whole life to inculcate?

Macquer also published a dictionary of chemistry, which was very successful, and which was translated into most of the European languages. This mode of treating chemistry was well suited to a science still in its infancy, and which did not yet constitute a complete whole. It enabled him to discuss the different topics in succession, and independent of each other: and thus to introduce much important matter which could not easily have been introduced into a systematic work on chemistry. The second edition of this dictionary was published just at the time when the gases began to attract the attention of scientific men; when facts began to multiply with prodigious rapidity, and to shake the confidence of chemists in all received theories. He acquitted himself of the difficult task of collecting and stating these new facts with considerable success; and doubtless communicated much new information to his countrymen: for the discoveries connected with the gases originated, and were chiefly made, in England, from which, on account of the revolutionary American war, there was some difficulty of obtaining early information.

M. Hellot, who was commissioner of the counsel for dyeing, and chemist to the porcelain manufacture, requested to have M. Macquer for an associate. This request did much honour to Hellot, as he was conscious that the reputation of Macquer as a chemist was superior to his own. Macquer endeavoured, in the first place, to lay down the true principles of the art of dyeing, as the best method of dissipating the obscurity which still hung over it. A great part of his treatise on the art of dyeing silk, published in the collection of the Academy of Sciences, has these principles for its object. He gave processes also for dyeing silk with Prussian blue, and for giving to silk, by means of cochineal, as brilliant a scarlet colour as can be given to woollen cloth by the same dye-stuff. He published nothing on the porcelain manufacture, though he attended particularly to the processes, and introduced several ameliorations. The beautiful porcelain earth at present used at Sevre, was discovered in consequence of a premium which he offered to any person who could point out a clay in every respect proper for making porcelain.

Macquer passed a great part of his life with a brother, whom he affectionately loved: after his death he devoted himself entirely to his wife and two children, whose education he superintended. He was rather averse to society, but conducted himself while in it with much sweetness and affability. He was fond of tranquillity and independence. Though his health had been injured a good many years before his death, the calmness and serenity of his temper prevented strangers from being aware that he was afflicted with any malady. He himself was sensible that his strength was gradually sinking; he predicted his approaching end to his wife, whom he thanked for the happiness which she had spread over his life. He left orders that his body should be opened after his decease, that the cause of his death might be discovered. He died on the 15th of February, 1784. An ossification of the aorta, and several calculous concretions found in the cavities of the heart, had been the cause of the disease under which he had suffered for several years before his death.

These four chemists, of whose lives a sketch has just been given, were the most eminent that France ever produced belonging to the Stahlian school of chemistry. Baron, Malouin, Rouelle senior, Tillet, Cadet, Baumé, Sage, and several others whose names I purposely omit, likewise cultivated chemistry, during that period, with assiduity and success; and were each of them the authors of papers which deserve attention, but which it would be impossible to particularize without swelling this work into a size greatly beyond its proper limits.

Hilaire-Marin Rouelle, who was born at Caen in 1718, was, however, too eminent a chemist to be passed over in silence. His elder brother, William Francis, was a member of the Academy of Sciences, and demonstrator to Macquer, who gave lectures in the Jardin du Roi. At the death of Macquer, in 1770, Hilaire-Marin Rouelle succeeded him. He devoted the whole of his time and money to this situation, and quite altered the nature of the experimental course of chemistry given in the Jardin du Roi. He was in some measure the author of the chemistry of animal bodies, at least in France. When he published his experiments on the salts of urine, and of blood, he had scarcely any model; and though he committed some considerable mistakes, he ascertained several essential and important facts, which have been since fully confirmed by more modern experimenters. He died on the 7th of April, 1779, aged sixty-one years. His temper was peculiar, and he was too honest and too open for the situation in which he was placed, and for a state of society in which every thing was carried by intrigue and finesse. This is the reason why, in France, his reputation was lower than it ought to have been. It accounts, too, for his never becoming a member of the Academy of Sciences, nor of any of the other numerous academies which at that time swarmed in France. Nothing is more common than to find these unjust decisions raise or depress men of science far above or far below their true standard. Romé de Lisle, the first person who commenced the study of crystals, and placed that study in a proper point of view, was a man of the same stamp with the younger Rouelle, and never on that account, became a member of any academy, or acquired that reputation during his lifetime, to which his laborious career justly entitled him. It would be an easy, though an invidious task, to point out various individuals, especially in France, whose reputation, in consequence of accidental and adventitious circumstances, rose just as much above their deserts, as those of Rouelle, and Romé de Lisle were sunk below.

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