II. MATERIAL OBJECTS.—A. MINERAL BODIES. (continued 2)

On the other hand, oil and water will not mix, however much you may stir the two together; and the oil, being the lighter, rises to the top as soon as the fluid is quiet. Nor will quicksilver and water mix, but the quicksilver, being very much heavier than the water, rushes to the bottom of the vessel into which the two are put. Neither will sand nor iron filings mix with water; as heavier bodies, they also sink to the bottom. Nor does powdered ice, though it is water in another shape, mix with ice cold water; as a lighter body it floats at the top.

52. Mixture followed by Increase of Density; Alcohol and Water.

Strong spirit, or alcohol, is a clear transparent fluid which looks like water, but is a very different substance. For example, it boils at a much lower temperature, it burns with a blue flame, it has intoxicating properties, and, like oil, it is very much lighter than water. Hence, if coloured spirit is poured gently upon the surface of water the spirit rests upon the water. Suppose, now, that we take a tall measure graduated into ten equal parts. Fill the lower five with water, and then, very gently, pour in the strongest alcohol, coloured in some way, until the tenth mark is reached. We shall have five volumes of water below, and an equal quantity, or five volumes, of coloured alcohol above. Where the two are in contact, the colour will be 75diffused into the water for a short distance, but not far, showing that only a slight mixture is taking place. This, however, is not because the two fluids mingle with difficulty; for, with slight stirring, they mix completely, and you have a fluid the colour of which is about half as intense as that of the alcohol, and many of the other properties of which are intermediate between those of pure alcohol and those of pure water.

Thus far, nothing further than simple mixture, as when coloured water was added to pure water, seems to have occurred; but, in reality, something more has happened. In the first place, the mixture is a good deal warmer than either of its components; that is to say, heat has been generated. In the second place, if you measure the volume of the whole fluid after it has cooled, it no longer stands at the mark ten, but distinctly lower, or about nine and three-quarters. As the volume of the mixture is less than the sum of the volumes of its two components, it follows that the density of the mixture must be greater than a density midway between that of the water and that of the alcohol. In other words, the molecules in the mixture do not occupy the same space as they did when they were separate. The result is the same as if the ten volumes had been compressed until they occupied only nine and three-quarters; so that the effect is a contraction similar to that which would be brought about by taking away heat from the mixture. In fact, as we have seen, the mixture gives out a quantity of heat.

There is another respect in which the mixture is unlike both its constituents. It both boils and 76freezes at a much lower temperature than water does, and at a higher temperature than alcohol does. In fact pure alcohol has not yet been frozen. If the molecules of the alcohol were merely diffused among those of the water as water is diffused through wet sand, they ought to pass into the gaseous state at the same temperature as that at which alcohol boils; and it would then be very easy to separate alcohol from water by distillation. But the fact is not so; alcohol cannot be obtained free from water by distillation unless something which holds water very strongly, such as quicklime, is added, so as to keep all the water back when the fluid is heated.

Thus alcohol and water, mingled together, give rise to a fluid which is not a mere mixture, the properties of which are known if we know the properties of its components; it is, in strictness, a new body, in which the molecules of the water and those of the alcohol affect one another to a certain extent and modify the pre-existing properties of each.

This effect of different bodies upon one another becomes much more manifest when water is brought into contact with certain solids.

53. Solution; Water Dissolves Salt.

If a spoonful of salt is put into a tumbler of cold water and the water is stirred, the salt swiftly vanishes from view; and, after a time, so far as our sense of vision goes, the water appears to be just what it was before. But if the water in the tumbler at first weighed five ounces and the salt weighed two ounces, the water in the tumbler will now weigh seven ounces; the water will now taste salt, the salt is said to be 77dissolved, and the solution is called brine. Moreover, the solution is said to be saturated, for if you put more salt in it will remain unchanged. Water, in fact, will dissolve two-fifths of its weight of salt and no more. If the brine thus formed is put into a wide dish, so that the water may evaporate; or if it is heated and the water boiled away; as fast as the water diminishes, a quantity of salt, equal to two-fifths of the water which is converted into steam, returns to the solid state and falls to the bottom of the vessel. And when all the water is driven off, the salt which remains will have exactly the weight, and all the other properties which it had before it was dissolved by the water.

Thus, contact with water has had a very singular effect upon the salt. It appears to have changed one of the properties of the salt, namely, its solidity, but to have left all the rest unaltered. We saw just now that powdered ice does not mix with ice-cold water, but that the fragments of ice remain solid. The moment, however, that the temperature rises, the cohesion, or sticking together of the molecules, which is the characteristic of the solid state, comes to an end; they become loose and free to move, and they mingle with the surrounding water. Or we may say that the ties which held the molecules of the solid together are dissolved, so that the solid water becomes fluid.

The resemblance of this process to the dissolving of salt in water is so obvious that, in common language, it is often said that a lump of salt or of sugar melts away in water; but if you try to make salt fluid by heat, you will have to expose it to a very high 78temperature, so that the conversion of salt from the solid state into the liquid state by solution in cold water is obviously a very different process from liquefaction by heat. Nevertheless the result is the same so far as the condition of the salt is concerned. The cohesion between its molecules is destroyed, and they distribute themselves evenly among the molecules of the water, just as the molecules of steam distribute themselves among the molecules of air. And, when you study chemistry, you will learn how it may be proved that the smallest drop of the solution of salt contains exactly the same proportion of salt as the whole does.

If brine is allowed to evaporate slowly, the molecules of the salt arrange themselves, as the water leaves them, in beautifully regular cubical crystals. You may see them form easily enough if you watch a drop of brine gradually dry up under a microscope. The salt crystals contain nothing but salt. If they are heated till they become red-hot they pass into the fluid state; and when still further heated, the fluid salt becomes a vapour or gas and, as such, flies off into the air, or volatilizes.

Thus we see that when salt and water are brought into contact, the salt undergoes a certain amount of change, while the water does not remain wholly unchanged. For brine no longer boils at 212°, but requires a considerably higher temperature. The salt, as it were, holds the water back, and prevents it from assuming the gaseous state under the same conditions as if it were pure, just as, in the previous case, the water held the alcohol back; or we may say that the force of heat which drives the molecules of liquid water apart, when 79steam is formed, has a greater resistance to overcome when salt is dissolved in the water. And just as the presence of alcohol lowers the freezing point of the water with which it is mixed, so does the presence of salt lower the freezing point of water. Sea water, which is a weak brine, begins to freeze at about 27°; and the ice which is formed is quite pure, while the remainder of the sea water becomes richer in salt.

If we mean by attraction that which opposes any force which tends to separate bodies, then we may say that the molecules of salt and those of water attract one another. And such attraction between molecules of matter of different kinds is called chemical attraction.

54. Quicklime and Water: Plaster of Paris and Water: Combination.

Quicklime is a substance obtained by heating chalk or limestone to redness. When pure, it is a white hard solid which can be made to pass into the liquid and gaseous states only at enormously high temperatures. If a lump of fresh quicklime be placed in a saucer and about one-third of its weight of water poured upon it, there will be a great turmoil, heat will be evolved, the water will disappear, and the lime will crumble down into a soft white powder. This operation is what bricklayers call slaking lime. And if no more water has been added than the proportion mentioned, the pure white powder which results will be solid and dry, the water having, to all appearance, vanished.

In the solution of salt we saw a solid become fluid under the influence of water; in the slaking of lime the fluid water enters into the structure of a solid. 80If more water is added, this solid dissolves or becomes liquid, as the salt did, and the solution is called limewater. By carefully managed evaporation of the water the lime may be recovered in the form of crystals, just as the salt was recovered. But there is this difference, that the salt crystals contain no water, while the lime crystals not only contain water, but contain exactly the same proportion as exists in slaked lime, that is to say, 18 parts water to 56 parts lime.

The water thus bound up with the lime into a new solid holds on so firmly to the lime that it requires a red heat to separate the two. The lime and the water are said to be chemically combined; and as the proportion of lime and water in slaked lime, or lime crystals, is always the same, they are said to be combined in definite proportions; and the slaked lime receives the special name of hydrate of lime.

Gypsum or Plaster of Paris is a dry white powder. If mixed with a little water it does not slake after the fashion of quick lime, but the mixture soon sets or becomes hard; and, at the same time, the greater part of the water disappears. In fact, it has combined with the plaster of Paris and forms part of another hydrate, in which, when the superfluous moisture dries, not a trace of water is to be seen. It is this property which is taken advantage of when plaster of Paris is used in making casts and moulds. The fluid plaster is poured over and round the body to be cast; as a fluid, it applies itself conveniently to all the inequalities of its surface; and, when it sets, it retains the shape which it has thus acquired. Set plaster of Paris may be perfectly dry; but it nevertheless contains 81between ⅐ and ⅛ of its weight of water, fixed and forming an integral part of the solid hydrate. And if the set plaster is strongly heated, the combined water is driven off and it returns to its original state.

Gypsum is found abundantly in nature, in the shape of beautiful transparent crystals which are called selenite. These crystals have the same composition as set plaster, that is to say, they are hydrates. A thin flake of such a crystal viewed with the highest powers of the microscope appears perfectly homogeneous. Nevertheless, there is good reason for the conclusion that it consists of molecules of water and molecules of gypsum which hold together so strongly that they form a hard brittle glassy solid. Moreover, the molecules of the hydrate itself hold together more strongly in some directions than in others. It is very easy to split the crystals lengthwise; while much more force is needed to cut them crosswise and then they do not split, but break.

Glauber’s salts and Epsom salts are other examples of solids which dissolve in water and separate in the crystalline form as the water evaporates; and which, like lime and gypsum, combine with a definite proportion of water to form crystalline compounds. In fact, each of these glassy brittle solids contains more than half its weight of water.

Thus we see that two bodies, of which water is one, may combine together to give rise to something different from either. And we are thus led to the science of chemistry, which tells us exactly how bodies combine, what comes of their combination, and how compounds may be separated into their constituents.

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55. Mineral bodies may take on definite shapes and grow, or increase in size, by the addition of like parts.

Water and all the other natural bodies which have hitherto been mentioned, are what are called mineral bodies, although, in common use, the term mineral is usually restricted to ores and metals. Now we have repeatedly had occasion to remark that, under certain circumstances, not only water, but many other mineral bodies, assume regular shapes. The most familiar example is that of the beautiful imitation of leaves and foliage which is presented by the ice which forms on a window in winter. But we have also seen that common salt, lime, gypsum, Glauber’s salts and Epsom salts, also assume the crystalline form as they or their compounds with water are deposited from their solutions. And if a drop of solution of Glauber’s salts or of Saltpetre, is allowed to evaporate under the microscope, a wonderful spectacle will be presented. As the salt assumes the solid state, the crystals suddenly appear in the field of view as needles and plates disposed in beautiful patterns, which rival those of hoar frost, though they are quite different from them. In fact, as you will learn if you study crystallography, every crystallizable substance has its proper crystalline forms and never departs from certain strictly related geometrical figures.

A crystal of any of these substances will grow if placed under proper conditions. Thus, if a crystal of common salt is hung by a thread in a saturated solution of salt, which is exposed to the air, so as to allow the water to evaporate slowly, the molecules of the salt which is left behind and can no longer be held 83in solution, deposit themselves on the crystal in regular order and increase its size without changing its form. And, in this way, the small crystal may grow to a great size. The large crystals of sugar candy, which consist of sugar and water deposited from a strong syrup or saturated solution of sugar, grow in the same fashion, upon threads suspended in the evaporating syrup. In this mode of growth you will observe that the enlargement is effected by addition to the outside of the growing body; and moreover the matter which is added, namely, the salt or the sugar, already exists as salt in the brine or as sugar in the syrup.