Chapter IV · SCIENTIFIC RESEARCHES: SECOND PERIOD. (continued 2)
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In another part of the twelfth memoir, not included in the above summary, Faraday deals with the disruptive discharge, and with the nature of the spark under varying conditions. This is continued on into the thirteenth memoir, read February, 1838, and is extended to the cases of “brush” and “glow” discharges. He discovered the existence of the very remarkable phenomenon of the “dark” discharge near the cathode in rarefied air. He sought to correlate all the various forms of discharge, as showing the essential nature of an electric current. “If a ball be electrified positively,” he says, “in the middle of a room, and be then moved in any direction, effects will be produced, as if a current in the same direction (to use the conventional mode of expression) had existed.” This is the theory of convection currents later adopted by Maxwell, and verified by experiment by Rowland in 1876.
COINAGE OF NEW WORDS.
In the course of this research on induction, Faraday had, as we have seen, been compelled to adopt new ideas, and therefore to adopt new names to denote them. The term dielectric for the medium in or across which the electric forces operate was one of these. As in previous cases, he consulted with his friends as to suitable terms. In this instance the following letter from Whewell explains itself. The letter to which it is a reply has not been preserved, but the reference to Faraday’s objection to the word current may be elucidated by a comparison with what Faraday wrote in criticism of that word on pages 146 and 212.
[Rev. W. Whewell to M. Faraday.]
Trin. Coll., Cambridge, Oct. 14, 1837.
My dear Sir,—I am always glad to hear of the progress of your researches, and never the less so because they require the fabrication of a new word or two. Such a coinage has always taken place at the great epochs of discovery; like the medals that are struck at the beginning of a new reign:—or rather like the change of currency produced by the accession of a new sovereign; for their value and influence consists in their coming into common circulation. I am not sure that I understand the views which you are at present bringing into shape sufficiently well to suggest any such terms as you think you want. I think that if I could have a quarter of an hour’s talk with you I should probably be able to construct terms that would record your new notions, so far as I could be made to understand them better than I can by means of letters: for it is difficult without question and discussion to catch the precise kind of relation which you want to express. However, by way of beginning such a discussion, I would ask you whether you want abstract terms to denote the different and related conditions of the body which exercises and the body which suffers induction? For though both are active and both passive it may still be convenient to suppose a certain ascendancy on one side. If so would two such words as inductricity and inducteity answer your purpose? They are not very monstrous in their form; and are sufficiently distinct. And if you want the corresponding adjectives you may call the one the inductric, and the other the inducteous body. This last word is rather a startling one; but if such relations are to be expressed, terminations are a good artifice, as we see in chemistry: and I have no doubt if you give the world facts and laws which are better expressed with than without such solecisms, they will soon accommodate to the phrases, as they have often done to worse ones. But I am rather in the dark as to whether this is the kind of relation which you want to indicate. If not, the attempt may perhaps serve to shew you where my dulness lies. I do not see my way any better as to the other terms, for I do not catch your objection to current, which appears to me to be capable of jogging on very well from cathode to anode, or vice versa. As for positive and negative, I do not see why cathodic and anodic should not be used, if they will do the service you want of them.
I expect to be in London at the end of the month, and could probably see you for half an hour on the 1st of November, say at 10, 11, or 12. But in the mean time I shall be glad to hear from you whether you can make anything of such conundrums as I have mentioned, and am always yours very truly,
W. Whewell.
M. Faraday Esqre. Royal Institution.
LATERAL ACTIONS OF CURRENT.
The concluding part of the thirteenth memoir, in which these new terms are used, is an exceedingly striking speculation on the lateral or transverse effects of the current. In calling special attention to them, he says: “I refer of course to the magnetic action and its relations; but though this is the only recognised lateral action of the current, there is great reason for believing that others exist and would by their discovery reward a close search for them.” He seems to have had an instinctive perception of something that eluded his grasp. Not until after Maxwell had given mathematical form to Faraday’s own suggestions was this vision to be realised. He is dimly aware that there appears to be a lateral tension or repulsion possessed by the lines of electric inductive action; and onward runs his thought in free speculation:—
When current or discharge occurs between two bodies, previously under inductrical relations to each other, the lines of inductive force will weaken and fade away, and, as their lateral repulsive tension diminishes, will contract and ultimately disappear in the line of discharge. May not this be an effect identical with the attractions of similar currents? i.e. may not the passage of static electricity into current electricity, and that of the lateral tension of the lines of the inductive force into the lateral attraction of lines of similar discharge, have the same relation and dependences, and run parallel to each other?
Series fourteen of the memoirs is on the nature of the electric force and on the relation of the electric and magnetic forces, and comprises an inconclusive inquiry as to a possible relation between specific inductive capacity and axes of crystallisation in crystalline dielectrics—a relation later assumed as true by Maxwell even before it was demonstrated by Von Boltzmann. In this memoir, too, occurs a description of a simple but effective induction balance. Then he asks what happens to insulating substances, such as air or sulphur, when they are put in a place where the magnetic forces are varying; they ought, he thinks, to undergo some state or condition corresponding to the state that causes currents in metals and conductors, and, further, that state ought to be one of tension. “I have,” he says, “by rotating non-conducting bodies near magnetic poles, and poles near them, and also by causing powerful electric currents to be suddenly formed and to cease around and about insulators in various directions, endeavoured to make some such state sensible, but have not succeeded.” In short, he was looking for direct evidence of the existence of what Maxwell called “displacement currents”—evidence which was later found independently by the author and by Röntgen. And, again, there rises in his mind a perception of that electrotonic state which had haunted his earlier researches as a something imposed upon the surrounding medium during the growth or dying of an electric current.
INCESSANT ACTIVITIES.
In these years (1835–1838) Faraday was still indefatigable in his lecture duties. In 1835 he gave four Friday discourses, and in May and June eight afternoon lectures at the Royal Institution on the metals; also a course of fourteen lectures on electricity to the medical students at St. George’s Hospital. In 1836 he published in the Philosophical Magazine a paper on the magnetism of the metals—notable as containing the still unverified speculation that all metals would become magnetic in the same way as iron if only cooled to a sufficiently low temperature—and three other papers, including one on the “passive” state of iron. He gave four Friday discourses and six afternoon lectures on heat. In 1837 also four Friday night discourses and six afternoon lectures were delivered. In 1838 three Friday discourses and eight afternoon lectures on electricity, ending in June with a distinct enunciation of the doctrine of the transformations of “force” (i.e. energy) and its indestructibility, afforded evidence of his industry in this respect. At the same time he was giving scientific advice to the authorities of Trinity House as to their lighthouses.
The laboratory notebook for March to August, 1838, shows a long research, occupying nearly 100 folio pages, on the relation of specific inductive capacity to crystalline structure. This is followed by some experiments upon an electric eel, at the Royal Adelaide Gallery, with some unpublished sketches of the distribution in the water of the currents it emits. He proved, with great satisfaction, that the currents it gave were capable of producing magnetic effects, sparks, and chemical decomposition. These observations were embodied in the fifteenth series of memoirs.
One entry in the laboratory book, of date April 5th, 1838, is of great interest, as showing how his mind ever recurred to the possibility of finding a connection between optical and electric phenomena: “Must try polarized light across a crystalline dielectric under charge. Good reasons perhaps now evident why a non-crystalline dielectric should have no effect.”
Faraday was now feeling greatly the strain of all these years of work, and in 1839 did little research until the autumn. Then he returned to the question of the origin of the electromotive force of the voltaic cell, and by the end of the year completed two long papers on this vexed question; they formed the sixteenth and seventeenth series, and conclude the memoirs of this second period.
THE CONTACT THEORY OF ELECTRICITY.
In the eighth series, completed in April, 1834, on the “Electricity of the Voltaic Pile,” Faraday had dealt with the question—at that time a topic of excited controversy—of the origin of the electromotive force in a cell, Volta, who knew nothing of the chemical actions, ascribed it to the contact of dissimilar metals, whilst Wollaston, Becquerel, and De la Rive considered it the result of chemical actions. The controversy has long ceased to interest the scientific world; for, with the recognition of the principle of the conservation of energy, it became evident that mere contact cannot provide a continuing supply of energy. It would now be altogether dead but for the survival of a belief in the contact theory on the part of one of the most honoured veterans in science. But in the years 1834 to 1840 it was of absorbing interest. Faraday’s work quietly removed the props which supported the older theory, and it crumbled away. He found that the chemical and electrical effects in the cell were proportional one to the other, and inseparable. He discovered a way of making a cell without any metallic contacts. He showed that without chemical action there was no current produced. But his results were ignored for the time. After six years Faraday reopened the question. Again the admirable summary of Professor Tyndall is drawn upon for the following account:—
The memoir on the “Electricity of the Voltaic Pile,” published in 1834, appears to have produced but little impression upon the supporters of the contact theory. These indeed were men of too great intellectual weight and insight lightly to take up, or lightly to abandon, a theory. Faraday therefore resumed the attack in two papers communicated to the Royal Society on February 6 and March 19, 1840. In these papers he hampered his antagonists by a crowd of adverse experiments. He hung difficulty after difficulty about the neck of the contact theory, until in its efforts to escape from his assaults it so changed its character as to become a thing totally different from the theory proposed by Volta. The more persistently it was defended, however, the more clearly did it show itself to be a congeries of devices, bearing the stamp of dialectic skill rather than that of natural truth.
In conclusion, Faraday brought to bear upon it an argument which, had its full weight and purport been understood at the time, would have instantly decided the controversy. “The contact theory,” he urged, “assumes that a force which is able to overcome powerful resistance, as for instance that of the conductors, good or bad, through which the current passes, and that again of the electrolytic action where bodies are decomposed by it, can arise out of nothing; that without any change in the acting matter, or the consumption of any generating force, a current shall be produced which shall go on for ever against a constant resistance, or only be stopped, as in the voltaic trough, by the ruins which its exertion has heaped up in its own course. This would indeed be a creation of power, and is like no other force in nature. We have many processes by which the form of the power may be so changed, that an apparent conversion of one into the other takes place. So we can change chemical force into the electric current, or the current into chemical force. The beautiful experiments of Seebeck and Peltier show the convertibility of heat and electricity; and others by Oersted and myself show the convertibility of electricity and magnetism. But in no case, not even in those of the gymnotus and torpedo, is there a pure creation or a production of power without a corresponding exhaustion of something to supply it.”
In 1839 Faraday gave five Friday discourses and a course of eight afternoon lectures on the non-metallic elements. In 1840 he gave three Friday discourses and seven lectures on chemical affinity. But in the summer came the serious breakdown alluded to on page 75. He did no experimental work after September 14th, nor indeed for nearly two years. Even then it was only a temporary return to research to investigate the source of the electrification produced by steam in the remarkable experiments of Mr. (afterwards Lord) Armstrong. He proved it to be due to friction. This done, he continued to rest from research until the middle of 1844, though he lectured a little for the Royal Institution. In 1841 he gave the juvenile lectures. In 1842 he gave two Friday discourses, one of them being on the lateral discharge in lightning-rods. He also gave the Christmas lectures on electricity.
END OF SECOND ACTIVE PERIOD.
In 1843 he gave three Friday discourses, one of which was on the electricity generated by a jet of steam; and repeated the eight afternoon lectures he had given in 1838. In 1844 he gave eight lectures on heat and two Friday discourses. He also resumed research on the condensation of gases, and vainly tried to liquefy oxygen and hydrogen, though he succeeded with ammonia and nitrous oxide.
During these years of rest he also did a little work for Trinity House, chiefly concerning lighthouses and their ventilation.