XXVI MICHAEL FARADAY 1791-1867

Born on September 22, 1791, at Newington, Surrey, England, Michael Faraday was the son of a blacksmith. After an early and very elementary education, he was apprenticed in 1805 to a book-binder in whose service he read widely and thus educated himself. Developing an interest in physics, he attended the evening lectures of Sir Humphrey Davy who, in 1813, engaged him as an assistant. Seven years later he wrote a history of electro-magnetism and succeeded, in the same year, in getting a needle to rotate fully around a live wire. In 1823 he liquefied chlorine, an experiment which destroyed the old notion of the permanent distinction between gases and liquids. In 1831 he discovered magneto-electric induction and advanced the conception of “lines of magnetic force.” In 1845, in trying to send polarized rays of light through heavy magnetized glass, he found that the magnet’s action interrupted the passage of the light and that magnetization caused the plane of polarization to rotate. He died August 25, 1867.

ON FLUID CHLORINE[29]

Read March 13, 1823.

It is well known that before the year 1810, the solid substance obtained by exposing chlorine, as usually procured, to a low temperature, was considered as the gas itself reduced into that form; and that Sir Humphrey Davy first showed it to be a hydrate, the pure dry gas not being considerable even at a temperature of 40° F.

I took advantage of the late cold weather to procure crystals of this substance for the purpose of analysis. The results are contained in a short paper in the Quarterly Journal of Science, Vol. XV. Its composition is very nearly 27.7 chlorine, 72.3 water, or 1 proportional of chlorine, and 10 of water.

The President of the Royal Society having honoured me by looking at these conclusions, suggested, that an exposure of the substance to heat under pressure, would probably lead to interesting results; the following experiments were commenced at his request. Some hydrate of chlorine was prepared, and being dried as well as could be by pressure in bibulous paper, was introduced into a sealed glass tube, the upper end of which was then hermetically closed. Being placed in water at 60°, it underwent no change; but when put into water at 100°, the substance fused, the tube became filled with a bright yellow atmosphere, and, on examination, was found to contain two fluid substances: the one, about three-fourths of the whole, was of a faint yellow colour, having very much the appearance of water; the remaining fourth was a heavy bright yellow fluid, lying at the bottom of the former, without any apparent tendency to mix with it. As the tube cooled, the yellow atmosphere condensed into more of the yellow fluid, which floated in a film on the pale fluid, looking very like chloride of nitrogen; and at 70° the pale portion congealed, although even at 32° the yellow portion did not solidify. Heated up to 100° the yellow fluid appeared to boil, and again produced the bright coloured atmosphere.

By putting the hydrate into a bent tube, afterwards hermetically sealed, I found it easy, after decomposing it by a heat of 100°, to distil the yellow fluid to one end of the tube, and so separate it from the remaining portion. In this way a more complete decomposition of the hydrate was effected, and, when the whole was allowed to cool, neither of the fluids solidified at temperatures above 34°, and the yellow portion not even at 0°. When the two were mixed together they gradually combined at temperatures below 60°, and formed the same solid substance as that first introduced. If, when the fluids were separated, the tube was cut in the middle, the parts flew asunder as if with an explosion, the whole of the yellow portion disappeared, and there was a powerful atmosphere of chlorine produced; the pale portion on the contrary remained, and when examined, proved to be a weak solution of chlorine in water, with a little muriatic acid, probably from the impurity of the hydrate used. When that end of the tube in which the yellow fluid lay was broken under a jar of water, there was an immediate production of chlorine gas.

I at first thought that muriatic acid and euchlorine had been formed; then, that two new hydrates of chlorine had been produced; but at last I suspected that the chlorine had been entirely separated from the water by the heat and condensed into a dry fluid by the mere pressure of its own abundant vapour. If that were true, it followed, that chlorine gas, when compressed, should be condensed into the same fluid, and, as the atmosphere in the tube in which the fluid lay was not very yellow at 50° or 60°, it seemed probable that the pressure required was not beyond what could readily be obtained by a condensing syringe. A long tube was therefore furnished with a cap and stop-cock, then exhausted of air and filled with chlorine, and being held vertically with the syringe upwards, air was forced in, which thrust the chlorine to the bottom of the tube, and gave a pressure of about 4 atmospheres. Being now cooled, there was an immediate deposit in films, which appeared to be hydrate, formed by water contained in the gas and vessels, but some of the yellow fluid was also produced. As this however might also contain a portion of the water present, a perfectly dry tub and apparatus were taken, and the chlorine left for some time over a bath of sulphuric acid before it was introduced. Upon throwing in air and giving pressure, there was now no solid film formed, but the clear yellow fluid was deposited, and more abundantly still upon cooling. After remaining some time it disappeared, having gradually mixed with the atmosphere above it, but every repetition of the experiment produced the same results.

Presuming that I had now a right to consider the yellow fluid as pure chlorine in the liquid state, I proceeded to examine its properties, as well as I could when obtained by heat from the hydrate. However obtained, it always appears very limpid and fluid, and excessively volatile at common pressure. A portion was cooled in its tube to 0°; it remained fluid. The tube was then opened, when a part immediately flew off, leaving the rest so cooled by the evaporation as to remain a fluid under the atmospheric pressure. The temperature could not have been higher than 40° in this case; as Sir Humphrey Davy has shown that dry chlorine does not condense at that temperature under common pressure. Another tube was opened at a temperature of 50°; a part of the chlorine volatilised, and cooled the tube so much as to condense the atmospheric vapour on it as ice.

A tube having the water at one end and the chlorine at the other was weighed, and then cut in two; the chlorine immediately flew off, and the loss being ascertained was found to be 1.6 grains: the water left was examined and found to contain some chlorine: its weight was ascertained to be 5.4 grains. These proportions, however, must not be considered as indicative of the true composition of hydrate of chlorine; for, from the mildness of the weather during the time when these experiments were made, it was impossible to collect the crystals of hydrate, press, and transfer them, without losing much chlorine; and it is also impossible to separate the chlorine and water in the tube perfectly, or keep them separate, as the atmosphere within will combine with the water, and gradually reform the hydrate.

Before cutting the tube, another tube had been prepared exactly like it in form and size, and a portion of water introduced into it, as near as the eye could judge, of the same bulk as the fluid chlorine: this water was found to weigh 1.2 grains; a result, which, if it may be trusted, would give the specific gravity of fluid chlorine as 1.33; and from its appearance in, and on water, this cannot be far wrong.

ELECTRICITY FROM MAGNETISM

Read November 24, 1831.

1. The power which electricity of tension possesses of causing an opposite electrical state in its vicinity has been expressed by the general term Induction; which, as it has been received into scientific language, may also, with propriety, be used in the same general sense to express the power which electrical currents may possess of inducing any particular state upon matter in their immediate neighborhood, otherwise indifferent. It is with this meaning that I purpose using it in the present paper.

2. Certain effects of the induction of electrical currents have already been recognized and described: as those of magnetization; Ampère’s experiments of bringing a copper disc near to a flat spiral; his repetition with electro-magnets of Arago’s extraordinary experiments, and perhaps a few others. Still it appeared unlikely that these could be all the effects which induction by currents could produce; especially as, upon dispensing with iron, almost the whole of them disappear, whilst yet an infinity of bodies, exhibiting definite phenomena of induction with electricity of tension still remain to be acted upon by the induction of electricity in motion.

3. Further: whether Ampère’s beautiful theory were adopted, or any other, or whatever reservation were mentally made, still it appeared very extraordinary, that, as every electric current was accompanied by a corresponding intensity of magnetic action at right angles to the current, good conductors of electricity, when placed within the sphere of this action, should not have any current induced through them, or some sensible effect produced equivalent in force to such a current.

4. These considerations, with their consequence, the hope of obtaining electricity from ordinary magnetism, have stimulated me at various times to investigate experimentally the inductive effect of electric currents. I lately arrived at positive results; and not only had my hopes fulfilled, but obtained a key which appeared to me to open out a full explanation of Arago’s magnetic phenomena, and also to discover a new state, which may probably have great influence in some of the most important effects of electric currents.

5. These results I purpose describing, not as they were obtained, but in such a manner as to give the most concise view of the whole.

EVOLUTION OF ELECTRICITY FROM MAGNETISM

27. A welded ring was made of soft round bar-iron, the metal being seven-eighths of an inch in thickness, and the ring six inches in external diameter. Three helices were put round one part of this ring, each containing about twenty-four feet of copper wire one-twentieth of an inch thick; they were insulated from the iron and each other, and superposed in the manner before described (6), occupying about nine inches in length upon the ring. They could be used separately or conjointly; the group may be distinguished by the letter A. On the other part of the ring about sixty feet of similar copper wire in two pieces were applied in the same manner, forming a helix B, which had the same common direction with the helices of A, but being separated from it at each extremity by about half an inch of the uncovered iron.

28. The helix B, was connected by copper wires with a galvanometer three feet from the ring. The helices of A were connected end to end so as to form one common helix, the extremities of which were connected with a battery of ten pairs of plates four inches square. The galvanometer was immediately affected, and to a degree far beyond what has been described when with a battery of tenfold power helices without iron were used (10); but though the contact was continued, the effect was not permanent, for the needle soon came to rest in its natural position, as if quite indifferent to the attached electro-magnetic arrangement. Upon breaking the contact with the battery, the needle was again powerfully deflected, but in the contrary direction to that induced in the first instance.

29. Upon arranging the apparatus so that B should be out of use, the galvanometer be connected with one of the three wires of A (27), and the other two made into a helix through which the current from the trough (28) was passed, similar but rather more powerful effects were produced.

30. When the battery contact was made in one direction, the galvanometer-needle was deflected on the one side; if made in the other direction, the deflection was on the other side. The deflection on breaking the battery contact was always the reverse of that produced by completing it. The deflection on making a battery contact always indicated an induced current in the opposite direction to that from the battery; but on breaking the contact the deflection indicated an induced current in the same direction as that of the battery. No making or breaking of the contact at B side, or in any part of the galvanometer circuit, produced any effect at the galvanometer. No continuance of the battery current caused any deflection of the galvanometer-needle. As the above results are common to all these experiments, and to similar ones with ordinary magnets to be hereafter detailed, they need not be again particularly described.

31. Upon using the power of 100 pairs of plates (10) with this ring, the impulse at the galvanometer, when contact was completed or broken, was so great as to make the needle spin round rapidly four or five times, before the air and terrestrial magnetism could reduce its motion to mere oscillation.

39. But as might be supposed that in all the preceding experiments of this section, it was by some peculiar effect taking place during the formation of the magnet, and not by its mere virtual approximation, that the momentary induced current was excited, the following experiment was made. All the similar ends of the compound hollow helix (34) were bound together by copper wire, forming two general terminations, and these were connected with the galvanometer. The soft iron cylinder (34) was removed, and a cylindrical magnet three-quarters of an inch in diameter and eight inches and a half in length, used instead. One end of this magnet was introduced into the axis of the helix and then, the galvanometer-needle being stationary, the magnet was suddenly thrust in; immediately the needle was deflected in the same direction as if the magnet had been formed by either of the two preceding processes (34, 36). Being left in, the needle resumed its first position, and then the magnet being withdrawn the needle was deflected in the opposite direction. These effects were not great; but by introducing and withdrawing the magnet, so that the impulse each time should be added to those previously communicated to the needle, the latter could be made to vibrate through an arc of 180° or more.

40. In this experiment the magnet must not be passed entirely through the helix, for then a second action occurs. When the magnet is introduced the needle at the galvanometer is deflected in a certain direction; but being in, whether it be pushed quite through or withdrawn, the needle is deflected in a direction the reverse of that previously produced. When the magnet is passed in and through at one continuous motion, the needle moves one way, is then suddenly stopped, and finally moves the other way.

41. If such a hollow helix as that described (34) be laid east and west (or in any other constant position), and a magnet be retained east and west, its marked pole always being one way; then whichever end of the helix the magnet goes in at, and consequently whichever pole of the magnet enters first, still the needle is deflected the same way: on the other hand, whichever direction is followed in withdrawing the magnet, the deflection is constant, but contrary to that due to its entrance.

57. The various experiments of this section prove, I think, most completely the production of electricity from ordinary magnetism. That its intensity should be very feeble and quantity small, cannot be considered wonderful, when it is remembered that like thermo-electricity it is evolved entirely within the substance of metals retaining all their conducting power. But an agent which is conducted along the metallic wires in the manner described; which, whilst so passing possesses the peculiar magnetic actions and force of a current of electricity; which can agitate and convulse the limbs of a frog; and which, finally, can produce a spark by its discharge through charcoal (32), can only be electricity. As all the effects can be produced by ferruginous electro-magnets (34), there is no doubt that arrangements like the magnets of Professors Moll, Henry, Ten Eyke, and others, in which as many as two thousand pounds have been lifted, may be used for these experiments; in which case not only a brighter spark may be obtained, but wires also ignited, and, as the current can pass liquids (23), chemical action be produced. These effects are still more likely to be obtained when the magneto-electric arrangements to be explained in the fourth section are excited by the powers of such apparatus.

58. The similarity of action, almost amounting to identity, between common magnets and either electro-magnets or volta-electric currents, is strikingly in accordance with and confirmatory of M. Ampère’s theory, and furnishes powerful reasons for believing that the action is the same in both cases; but, as a distinction in language is still necessary, I propose to call the agency thus exerted by ordinary magnets, magneto-electric or magnelectric induction (26).

59. The only difference which powerfully strikes the attention as existing between volta-electric and magneto-electric induction, is the suddenness of the former, and the sensible time required by the latter: but even in this early state of investigation there are circumstances which seem to indicate, that upon further inquiry this difference will, as a philosophical distinction, disappear (68).

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