Note 6 — Chapter I

Footnote 6:

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The Chevalier de Dolomieu has imagined an ingenious theory for the solution of siliceous substances in water (Journal de Physique, Mai 1792.). This theory has not been taken up merely at a venture, but is founded upon very accurate and interesting chemical experiments. Hitherto, however, the nature of the siliceous substance is not sufficiently known, to enable us to found, upon chemical principles, the mineral operations of nature. That siliceous substance may be dissolved, or rendered soluble in water, by means of alkaline salt, and that it may be also volatilised by means of the fluor acid, is almost all that we know upon the subject. But this is saying no more in relation to the mineral operations employed upon the siliceous substance, than it would be, in relation to those upon gold, to say that this metal is dissolved by aqua regia.

It is to be admitted, that every simple substance may have its menstruum, by means of which it may be retained with water in a dissolved state; but from this it does not follow, that it is by the means of aqueous solutions of all those mineral bodies, that nature operates the consolidation of bodies, which we find actually accomplished with all those different substances. It is the business of this work to show, that from all appearances in the mineral regions, as well as those upon the surface in the atmosphere, the supposition, of that manner of consolidating bodies by solution, is inconsistent both with natural appearances, and also with chemical principles.

Our ingenious author, who has, with, great diligence as well as an enlightened mind, observed the operations of nature upon the surface of the earth, here says, "ce n'est pas sans étonnement que je remarque depuis long-temps que jamais aucune eau qui coule à la surface de la terre n'attaque le quartz, aucune n'en tient en dissolution, pendant que celles qui circulent intérieurement le corrodent aussi souvent qu'elles le déposent."—How dangerous it is in science for ingenious men to allow themselves to form conclusions, which the principles on which they reason do not strictly warrant, we have a remarkable example in the present case.

M. de Dolomieu sees no corrosion of quartz, or solution of that substance, upon the surface of the earth; from this, then, he concludes, that siliceous substance is not dissolved in that situation of things. On the other hand, he finds siliceous bodies variously concreted among the solid strata of the earth; and, from this he concludes, that siliceous substance has been both dissolved by water in the strata, and also there again concreted and crystallised in having been separated from the water. This is certainly what we all perceive; but we do not all allow ourselves to draw such inconclusive inferences from our premises. Notwithstanding the greatest accuracy of our observations, quartz may be dissolvable in a minute degree by water, upon the surface of this earth; and, all the appearances of siliceous bodies, in the mineral regions, where we cannot immediately see the operation, may be better explained by fusion than by aqueous solution.

But, from his chemical experiments, our author has conjectured that there may be a phlogistic substance, by means of which the siliceous earth is dissolved when in darkness; and that this solvent loses its power, if exposed to the light of day. I have one observation to oppose to this ingenious theory. Under deep black mosses, through which no ray of light can penetrate, every condition for dissolving siliceous bodies should be found, according to the supposition in question; neither will sufficient time be found wanting, in those deep mosses, upon the summits of our mountains; yet, examine the matter of fact? not the smallest solution is to be perceived in the siliceous parts of the stones which are found under those mosses, but every particle of iron is dissolved, so that the surface of every stone is white, and nothing but the siliceous earth of the feld-spar, and perhaps the argillaceous, is left.

Here we have in this author an instructive example: No person, in my opinion, has made such enlightened or scientific experiments, or such judicious observations with regard to the nature of siliceous substance, as a compound thing; no person reasons more distinctly in general, or sees more clearly the importance of his principles; yet, with regard to mineral concretions, how often has he been drawn thus inadvertently into improper generalization! I appeal to the analogy which, in this treatise, he has formed, between the stalactical concretions upon the surface of the earth, and the mineral concretions of siliceous substance. As an example of the great lights, and penetrating genius, of this assiduous studier of nature, I refer to the judicious observations which he has made upon the subject of aluminous earth, in this dissertation.

I am surprised to find this enlightened naturalist seeking, in the origin of this globe of our earth, a general principle of fluidity or solution in water, like the alkahest of the alchymists, by means of which the different substances in the chemical constitution of precious stones might have been united as well as crystallised. One would have thought, that a philosopher, so conversant in the operations of subterraneous fire, would have perceived, that there is but one general principle of fluidity or dissolution, and that this is heat.