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The Principles of Chemistry, Volume II

Note 11 bis — THE PRINCIPLES OF CHEMISTRY

George Kamensky translation

True peroxides (see Note 7), like H2O2, BaO2, S2O7 (Chapter XX.), must not be confused with true saline oxides even if the latter contain much oxygen (for instance, N2O5, CrO3, &c.) although one and the other easily oxidise. The difference between them is seen in their fundamental properties: the saline oxides correspond to water, while the peroxides correspond in their reactions and origin to peroxide of hydrogen. This is clearly seen in the difference between Na2O and Na2O2 (Chapter XII.). Therefore the peroxides should also have their periodicity. An element R, giving a highest degree of oxidation, R2On, may give both a lower degree of oxidation, R2On-m (where m is evidently less than n), and peroxides, R2On+1, R2On+2, or even more oxygen. This class of oxides, to which attention has only recently been turned (Berthelot, Piccini, &c.), may perhaps on further study give the possibility of generalising the capability of the elements to give unstable complex higher forms of combination, such as double salts, and in my opinion should in the near future be the field of new and important discoveries. And in contemporary chemistry, salts, saline oxides, hydrogen compounds, and other combinations of the elements corresponding to them constitute an important and very complex problem for generalisation, which is satisfied by the periodic law in its present form, to which it has risen from its first state, in which it gave the means of foreseeing (see later on) the existence of unknown elements (Ga, Sc, and Ge), their properties, and many details respecting their compounds. Until those improvements in the periodic system which have been proposed by Prof. Flavitzky (of Kazan) and Prof. Harperath (of Cordoba, in the Argentine Republic), Ugo Alvisi (Italy), and others give similar practical results, I think it unnecessary to discuss them further.

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