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The Principles of Chemistry, Volume II

Note 3 — Chapter XXIII · THE PLATINUM METALS

George Kamensky translation

In characterising the platinum metals according to their relation to the iron metals, it is very important to add two more very remarkable points. The platinum metals are capable of forming a sort of unstable compound with hydrogen; they absorb it and only part with it when somewhat strongly heated. This faculty is especially developed in platinum and palladium, and it is very characteristic that nickel, which exactly corresponds with platinum and palladium in the periodic system, should exhibit the same faculty for retaining a considerable quantity of hydrogen (Graham's and Raoult's experiments). Another characteristic property of the platinum metals consists in their easily giving (like cobalt which forms the cobaltic salts) stable and characteristic saline compounds with ammonia, and like Fe and Co, double salts with the cyanides of the alkali metals, especially in their lower forms of combination. All the above so clearly brings the elements of the iron series in close relation to the platinum metals, that the eighth group acquires as natural a character as can be required, with a certain originality or individuality for each element.

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