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The Principles of Chemistry, Volume II

Note 2 bis — Chapter XXII · IRON, COBALT, AND NICKEL

George Kamensky translation

Immense deposits of iron pyrites are known in various parts of Russia. On the river Msta, near Borovitsi, thousands of tons are yearly collected from the detritus of the neighbouring rocks. In the Governments of Toula, Riazan, and in the Donets district continuous layers of pyrites occur among the coal seams. Very thick beds of pyrites are also known in many parts of the Caucasus. But the deposits of the Urals are particularly vast, and have been worked for a long time. Amongst these I will only indicate the deposits on the Soymensky estate near the Kishteimsky works; the Kaletinsky deposits near the Virhny-Isetsky works (containing 1–2 p.c. Cu); on the banks of the river Koushaivi near Koushvi (3–5 p.c. Cu), and the deposits near the Bogoslovsky works (3–5 p.c. Cu). Iron pyrites (especially that containing copper which is extracted after roasting) is now chiefly employed for roasting, as a source of SO2, for the manufacture of chamber sulphuric acid (Vol. I. p. 291), but the remaining oxide of iron is perfectly suitable for smelting into pig iron, although it gives a sulphurous pig iron (the sulphur may be easily removed by subsequent treatment, especially with the aid of ferro-manganese in Bessemer's process). The great technical importance of iron pyrites leads to its sometimes being imported from great distances; for instance, into England from Spain. Besides which, when heated in closed retorts FeS2 gives sulphur, and if allowed to oxidise in damp air, green vitriol, FeSO4.

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