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The Principles of Chemistry, Volume II

Note 7 — Chapter XVII · BORON, ALUMINIUM, AND THE ANALOGOUS METALS OF THE THIRD GROUP

George Kamensky translation

It is evident that, in the presence of basic oxides, water competes with them, which fact in all probability determines both the amount of water in the salts of boric acid as well as their decomposition by an excess of water. In confirmation of the above-mentioned competing action between water and bases, I think it useful to point out that the crystallo-hydrate of borax containing 5H2O may be represented as B(HO)3, or rather as B2(OH)6, with the substitution of one atom of hydrogen by sodium, since Na2B4O7,5H2O = 2B2(OH)5(ONa). The composition of the acid boric salts is very varied, as is seen from the fact that Reychler (1893) obtained (Cs2O)3B2O3, (Rb2O)2B2O3 (corresponding to borax) and (Li2O)B2O3, and that Le Chatelier and Ditte obtained, for CaO, MgO, &c., (RO)B2O3, (RO)23B2O3, (RO)2B2O3, (RO)2B2O3, and even (RO)3B2O3.

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