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The Principles of Chemistry, Volume II

Note 23 — Chapter XVII · BORON, ALUMINIUM, AND THE ANALOGOUS METALS OF THE THIRD GROUP

George Kamensky translation

Another direct method for the preparation of pure aluminium compounds consists in the treatment of cryolite containing aluminium fluoride together with sodium fluoride, AlNa3F6. This mineral is exported from Greenland, and is also found in the Urals. It is crushed and heated in reverberatory furnaces with lime, and the resultant mass is treated with water; sodium aluminate is then obtained in solution, and calcium fluoride in the precipitate AlNa3F6 + 3CaO = 3CaF2 + AlNa3O3.

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