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The Principles of Chemistry, Volume II

Note 13 — Chapter XVII · BORON, ALUMINIUM, AND THE ANALOGOUS METALS OF THE THIRD GROUP

George Kamensky translation

Boron fluoride is frequently evolved on heating certain compounds occurring in nature containing both boron and fluorine. If calcium fluoride is heated with boric anhydride, calcium borate and boron fluoride are formed, and the latter, as a gas, is volatilised: 2B2O3 + 3CaF2 = 2BF3 + Ca3B2O6. The calcium borate, however, retains a certain amount of calcium fluoride.

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