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The Principles of Chemistry, Volume II

Note 7 — APPENDIX III

George Kamensky translation

The greatest brilliancy of the spectrum of argon is obtained at a tension of 3 mm., while for nitrogen it is about 75 mm. (Crookes). In Chapter V., Note 16 bis, it is said that the same blue line observed in the spectrum of argon is also observed in the spectrum of nitrogen. This is a mistake, since there is no coincidence between the blue lines of the argon and nitrogen spectra. However, we may add that for nitrogen the following moderately bright lines are known of wave-lengths 585, 574, 544, 516, 457, 442, 436, and 426, which are repeated in the spectra (red and blue) of argon, judging by Crookes' researches (1895); but it is naturally impossible to assert that there is perfect identity until some special comparative work has been done in this subject, which is very desirable, and more especially for the bluish-violet portion of the spectrum, more particularly between the lines 442–436, as these lines are distinguished by their brilliancy in both the argon and nitrogen spectra. The above-mentioned supposition of argon being polymerised nitrogen (N3), formed from nitrogen (N2), with the evolution of heat, might find some support should it be found after careful comparison that even a limited number of spectral lines coincided.

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