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The Principles of Chemistry, Volume I

Note 17 — Chapter VIII · CARBON AND THE HYDROCARBONS

George Kamensky translation

The electrical furnace is an invention of recent times, and gives the possibility of obtaining a temperature of 3,500°, which is not only not obtainable in ordinary furnaces, but even in the oxyhydrogen flame, whose temperature does not exceed 2,000°. The electrical furnace consists of two pieces of lime, laid one on the other. A cavity is made in the lower piece for the reception of the substance to be melted between two thick electrodes of dense carbon. On passing a current of 70 volts and 450 ampères a temperature of 3,000° is easily obtained. At a temperature of 2,500° (100 ampères and 40 volts) not only do all metals melt, but even lime and magnesia (when placed in the space between the carbon electrodes, i.e. in the voltaic arc) become soft and crystallise on cooling. At 3,000° lime becomes very fluid, metallic calcium partially separates out and a carbon compound, which remains liquid for a long time. At this temperature oxide of uranium is reduced to the suboxide and metal, zirconia and rock crystal fuse and partially volatilise, as also does alumina; platinum, gold, and even carbon distinctly volatilise; the majority of the metals form carbides. At such a temperature also cast iron and carbon give graphite, while according to Rousseau, between 2,000° and 3,000° the diamond passes into graphite and conversely graphite into the diamond, so that this is a kind of reversible reaction.

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