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The Principles of Chemistry, Volume I

Note 21 — Chapter VII · MOLECULES AND ATOMS. THE LAWS OF GAY-LUSSAC AND AVOGADRO-GERHARDT

George Kamensky translation

If Be = 9, and beryllium chloride be BeCl2, then for every 9 parts of beryllium there are 71 parts of chlorine, and the molecular weight of BeCl2 = 80; hence the vapour density should be 40 or n40. If Be = 13·5, and beryllium chloride be BeCl3, then to 13·5 of beryllium there are 106·5 of chlorine; hence the molecular weight would be 120, and the vapour density 60 or n60. The composition is evidently the same in both cases, because 9 : 71 ∷ 13·5 : 106·5. Thus, if the symbol of an element designate different atomic weights, apparently very different formulæ may equally well express both the percentage composition of compounds, and those properties which are required by the laws of multiple proportions and equivalents. The chemists of former days accurately expressed the composition of substances, and accurately applied Dalton's laws, by taking H = 1, O = 8, C = 6, Si = 14, &c. The Gerhardt equivalents are also satisfied by them, because O = 16, C = 12, Si = 28, &c., are multiples of them. The choice of one or the other multiple quantity for the atomic weight is impossible without a firm and concrete conception of the molecule and atom, and this is only obtained as a consequence of the law of Avogadro-Gerhardt, and hence the modern atomic weights are the results of this law (see Note 28).

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