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The Principles of Chemistry, Volume I

Note 12 — Chapter VII · MOLECULES AND ATOMS. THE LAWS OF GAY-LUSSAC AND AVOGADRO-GERHARDT

George Kamensky translation

As the density of aqueous vapour remains constant within the limits of experimental accuracy, even at 1,000°, when dissociation has certainly commenced, it would appear that only a very small amount of water is decomposed at these temperatures. If even 10 p.c. of water were decomposed, the density would be 8·57 and the quotient M/D = 2·1, but at the high temperatures here concerned the error of experiment is not greater than the difference between this quantity and 2. And probably at 1,000° the dissociation is far from being equal to 10 p.c. Hence the variation in the vapour density of water does not give us the means of ascertaining the amount of its dissociation.

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