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The Principles of Chemistry, Volume I

Note 7 — Chapter VII · MOLECULES AND ATOMS. THE LAWS OF GAY-LUSSAC AND AVOGADRO-GERHARDT

George Kamensky translation

This is not only seen from the above calculations, but may be proved by experiment. A glass tube, divided in the middle by a stopcock, is taken and one portion filled with dry hydrogen chloride (the dryness of the gases is very necessary, because ammonia and hydrogen chloride are both very soluble in water, so that a small trace of water may contain a large amount of these gases in solution) and the other with dry ammonia, under the atmospheric pressure. One orifice (for instance, of that portion which contains the ammonia) is firmly closed, and the other is immersed under mercury, and the cock is then opened. Solid sal-ammoniac is formed, but if the volume of one gas be greater than that of the other, some of the first gas will remain. By immersing the tube in the mercury in order that the internal pressure shall equal the atmospheric pressure, it may easily be shown that the volume of the remaining gas is equal to the difference between the volumes of the two portions of the tube, and that this remaining gas is part of that whose volume was the greater.

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