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The Principles of Chemistry, Volume I

Note 47 — Chapter V · NITROGEN AND AIR

George Kamensky translation

Different so-called disinfectants purify the air, and prevent the injurious action of certain of its components by changing or destroying them. Disinfection is especially necessary in those places where a considerable amount of volatile substances are evolved into the air, and where organic substances are decomposed; for instance, in hospitals, closets, &c. The numerous disinfectants are of the most varied nature. They may be divided into oxidising, antiseptic, and absorbent substances. To the oxidising substances used for disinfection belong chlorine, and various substances evolving it, because chlorine in the presence of water oxidises the majority of organic substances, and this is why chlorine is used as a disinfectant for Siberian plagues. Further, to this class belong the permanganates of the alkalis and peroxide of hydrogen, as substances easily oxidising matters dissolved in water; these salts are not volatile like chlorine, and therefore act much more slowly, and in a much more limited sphere. Antiseptic substances are those which convert organic substances into such as are little prone to change, and prevent putrefaction and fermentation. They most probably kill the germs of organisms occurring in miasmata. The most important of these substances are creosote and phenol (carbolic acid), which occur in tar, and act in preserving smoked meat. Phenol is a substance little soluble in water, volatile, oily, and having the characteristic smell of smoked objects. Its action on animals in considerable quantities is injurious, but in small quantities, used in the form of a weak solution, it prevents the change of animal matter. The smell of privies, which depends on the change of excremental matter, may be easily removed by means of chlorine or phenol. Salicylic acid, thymol, common tar, and especially its solution in alkalis as proposed by Nensky, &c., are also substances having the same property. Absorbent substances are of no less importance, especially as preventatives, than the preceding two classes of disinfectants, inasmuch as they are innocuous. They are those substances which absorb the odoriferous gases and vapours emitted during putrefaction, which are chiefly ammonia, sulphuretted hydrogen, and other volatile compounds. To this class belong charcoal, certain salts of iron, gypsum, salts of magnesia, and similar substances, as well as peat, mould, and clay. Questions of disinfection and ventilation appertain to the most serious problems of common life and hygiene. These questions are so vast that we are here able only to give a short outline of their nature.

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