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The Principles of Chemistry, Volume I

Note 35 — Chapter V · NITROGEN AND AIR

George Kamensky translation

For rapid calculation the weight of a litre of air (in a room) in St. Petersburg, may under these conditions (H, t, and f) be obtained by the formula e = 1·20671 + 0·0016 [H1 - 755 + 2·6(18° - t°)] where H1 = H - 0·38f. In determining the weight of small and heavy objects (crucibles, &c. in analysis, and in determining the specific gravities of liquids, &c.) a correction may be introduced for the loss of weight in the air of the room, by taking the weight of a litre of air displaced as 1·2 gram, and consequently 0·0012 gram for every cubic centimetre. But if gases or, in general, large vessels are weighed, and the weighings require to be accurate, it is necessary to take into account all the data for the determination of the density of the air (t, H, and f), because sensitive balances can determine the possible variations of the weight of air, as in the case of a litre the weight of air varies in centigrams, even at a constant temperature, with variations of H and f. Some time ago (1859) I proposed the following method and applied it for this purpose. A large light and closed vessel is taken, and its volume and weight in a vacuum are accurately determined, and verified from time to time. On weighing it we obtain the weight in air of a given density, and by subtracting this weight from its absolute weight and dividing by its volume we obtain the density of the air.

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