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The Principles of Chemistry, Volume I

Note 1 — Chapter IV · OZONE AND HYDROGEN PEROXIDE—DALTON'S LAW

George Kamensky translation

This conclusion, deduced by me as far back as 1878 (Moniteur Scientifique) by conceiving the molecules of ozone (see later) as more complex than those of oxygen, and ozone as containing a greater quantity of heat than oxygen, has been proved experimentally by the researches of Mailfert (1880), who showed that the passage of a silent discharge through a litre of oxygen at 0° may form up to 14 milligrams of ozone, and at -30° up to 60 milligrams; but best of all in the determinations of Chappuis and Hautefeuille (1880), who found that at a temperature of -25° a silent discharge converted 20 p.c. of oxygen into ozone, whilst at 20° it was impossible to obtain more than 12 p.c., and at 100° less than 2 p.c. of ozone was obtained.

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