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The Principles of Chemistry, Volume I

Note 51 — Chapter III · OXYGEN AND THE CHIEF ASPECTS OF ITS SALINE COMBINATIONS

George Kamensky translation

That water really is separated in the reaction of acid on alkaline hydrates, may be shown by taking some other intermediate hydrate—for example, alumina—instead of water. Thus, if a solution of alumina in sulphuric acid be taken, it will have, like the acid, an acid reaction, and will therefore colour litmus red. If, on the other hand, a solution of alumina in an alkali—say, potash—be taken, it will have an alkaline reaction, and will turn red litmus blue. On adding the alkaline to the acid solution until neither an alkaline nor an acid reaction is produced, a salt is formed, consisting of sulphuric anhydride and potassium oxide. In this, as in the reaction of hydrates, an intermediate oxide is separated out—namely, alumina. Its separation will be very evident in this case, as alumina is insoluble in water.

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