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The Principles of Chemistry, Volume I

Note 12 — Chapter III · OXYGEN AND THE CHIEF ASPECTS OF ITS SALINE COMBINATIONS

George Kamensky translation

This reaction is not reversible, and is exothermal—that is, it does not absorb heat, but, on the contrary, evolves 9,713 calories per molecular weight KClO3, equal to 122 parts of salt (according to the determination of Thomsen, who burnt hydrogen in a calorimeter either alone or with a definite quantity of potassium chlorate mixed with oxide of iron). It does not proceed at once, but first forms perchlorate, KClO4 (see Chlorine and Potassium). It is to be remarked that potassium chloride melts at 766°, potassium chlorate at 359°, and potassium perchlorate at 610°. (Concerning the decomposition of KClO3, see Chapter II., Note 47.)

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