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The Principles of Chemistry, Volume I

Note 6 bis — Chapter II · THE COMPOSITION OF WATER, HYDROGEN

George Kamensky translation

Part of the oxygen will also penetrate through the pores of the tube; but, as was said before, a much smaller quantity than the hydrogen, and as the density of oxygen is sixteen times greater than that of hydrogen, the volume of oxygen which passes through the porous walls will be four times less than the volume of hydrogen (the quantities of gases passing through porous walls are inversely proportional to the square roots of their densities). The oxygen which separates out into the annular space will combine, at a certain fall of temperature, with the hydrogen; but as each volume of oxygen only requires two volumes of hydrogen, whilst at least four volumes of hydrogen will pass through the porous walls for every volume of oxygen that passes, therefore, part of the hydrogen will remain free, and can be collected from the annular space. A corresponding quantity of oxygen remaining from the decomposition of the water can be collected from the internal tube.

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