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The Principles of Chemistry, Volume I

Note 30 — Chapter XIV · THE VALENCY AND SPECIFIC HEAT OF THE METALS. MAGNESIUM. CALCIUM, STRONTIUM, BARIUM, AND BERYLLIUM

George Kamensky translation

Magnesium sulphate enters into certain reactions which are proper to sulphuric acid itself. Thus, for instance, if a carefully prepared mixture of equivalent quantities of hydrated magnesium sulphate and sodium chloride be heated to redness, the evolution of hydrochloric acid is observed just as in the action of sulphuric acid on common salt, MgSO4 + 2NaCl + H2O = Na2SO4 + MgO + 2HCl. Magnesium sulphate acts in a similar manner on nitrates, with the evolution of nitric acid. A mixture of it with common salt and manganese peroxide gives chlorine. Sulphuric acid is sometimes replaced by magnesium sulphate in galvanic batteries—for example, in the well-known Meidinger battery. In the above-mentioned reactions we see a striking example of the similarity of the reactions of acids and salts, especially of salts which contain such feeble bases as magnesia.

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