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The Principles of Chemistry, Volume I

Note 42 — Chapter XIII · POTASSIUM, RUBIDIUM, CÆSIUM, AND LITHIUM. SPECTRUM ANALYSIS

George Kamensky translation

Bunsen obtained rubidium by distilling a mixture of the tartrate with soot, and Beketoff (1888) by heating the hydroxide with aluminium, 2RbHO + Al = RbAlO2 + H2 + Rb. By the action of 85 grams of rubidium on water, 94,000 heat units are evolved. Setterberg obtained cæsium (1882) by the electrolysis of a fused mixture of cyanide of cæsium and of barium. Winkler (1890) showed that metallic magnesium reduces the hydrates and carbonates of Rb and Cs like the other alkaline metals. N. N. Beketoff obtained them with aluminium (see following note).

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