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The Principles of Chemistry, Volume I

Note 30 — Chapter XIII · POTASSIUM, RUBIDIUM, CÆSIUM, AND LITHIUM. SPECTRUM ANALYSIS

George Kamensky translation

The absorptive capacity is the relation between the intensity of the light (of a given wave-length) falling upon and retained by a substance. Bunsen and Roscoe showed by direct experiment that this ratio is a constant quantity for every substance. If A stand for this ratio for a given substance at a given temperature—for instance, for a flame coloured by sodium—and E be the intensity of the light of the same wave-length emitted at the same temperature by the same substance, then Kirchhoff's law, the explanation and deduction of which must be looked for in text-books of physics, states that the fraction A/E is a constant quantity depending on the nature of a substance (as A depends on it) and determined by the temperature and wave-length.

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