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The Principles of Chemistry, Volume I

Note 4 — Chapter XII · SODIUM

George Kamensky translation

Many observations have been made, but little general information has been obtained from particular cases. In addition to which, the properties of a given salt are changed by the presence of other salts. This takes place not only in virtue of mutual decomposition or formation of double salts capable of separate existence, but is determined by the influence which some salts exert on others, or by forces similar to those which act during solution. Here nothing has been generalised to that extent which would render it possible to predict without previous investigation, if there be no close analogy to help us. Let us state one of these numerous cases: 100 parts of water at 20° dissolve 34 parts of potassium nitrate but on the addition of sodium nitrate the solubility of potassium nitrate increases to 48 parts in 10 of water (Carnelley and Thomson). In general, in all cases of which there are accurate observations it appears that the presence of foreign salts changes the properties of any given salt.

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