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The Principles of Chemistry, Volume I

Note 79 bis — Chapter XI · THE HALOGENS: CHLORINE, BROMINE, IODINE, AND FLUORINE

George Kamensky translation

The oxidation of iodine by strong nitric acid was discovered by Connell; Millon showed that it is effected, although more slowly, by the action of the hydrates of nitric acid up to HNO3,H2O, but that the solution HNO3,2H2O, and weaker solutions, do not oxidise, but simply dissolve, iodine. The participation of water in reactions is seen in this instance. It is also seen, for example, in the fact that dry ammonia combines directly with iodine—for instance, at 0° forming the compound I2,4NH3—whilst iodide of nitrogen is only formed in presence of water.

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