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The Principles of Chemistry, Volume I

Note 41 — Chapter XI · THE HALOGENS: CHLORINE, BROMINE, IODINE, AND FLUORINE

George Kamensky translation

Owing to the formation of this chlorine dioxide, a mixture of potassium chlorate and sugar is ignited by a drop of sulphuric acid. This property was formerly made use of for making matches, and is now sometimes employed for setting fire to explosive charges by means of an arrangement in which the acid is caused to fall on the mixture at the moment required. An interesting experiment on the combustion of phosphorus under water may be conducted with chlorine dioxide. Pieces of phosphorus and of potassium chlorate are placed under water, and sulphuric acid is poured on to them (through a long funnel); the phosphorus then burns at the expense of the chlorine dioxide.

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