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The Principles of Chemistry, Volume I

Note 24 — Chapter X · SODIUM CHLORIDE—BERTHOLLET'S LAWS—HYDROCHLORIC ACID

George Kamensky translation

If MX and NY represent the molecules of two salts, and if there be no third substance present (such as water in a solution), the formation of XY would also be possible; for instance, cyanogen, iodine, &c. are capable of combining with simple haloids, as well as with the complex groups which in certain salts play the part of haloids. Besides which the salts MX and NY or MY with NX may form double salts. If the number of molecules be unequal, or if the valency of the elements or groups contained in them be different, as in NaCl + H2SO4, where Cl is a univalent haloid and SO4 is bivalent, then the matter may be complicated by the formation of other compounds besides MY and NX, and when a solvent participates in the action, and especially if present in large proportion, the phenomena must evidently become still more complex; and this is actually the case in nature. Hence while placing before the reader a certain portion of the existing store of knowledge concerning the phenomena of double saline decompositions, I cannot consider the theory of the subject as complete, and have therefore limited myself to a few data, the completion of which must be sought in more detailed works on the subject of theoretical chemistry, without losing sight of what has been said above.

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