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The Principles of Chemistry, Volume I

Note 50 — Chapter I · ON WATER AND ITS COMPOUNDS

George Kamensky translation

This fact, which was established by Gay-Lussac, Pierson, and v. Babo, is confirmed by the latest observations, and enables us to express not only the fall of tension (p - p′) itself, but its ratio to the tension of water ( p - p′ / p ). It is to be remarked that in the absence of any chemical action, the fall of pressure is either very small, or does not exist at all (note 33), and is not proportional to the quantity of the substance added. As a rule, the tension is then equal, according to the law of Dalton, to the sum of the tensions of the substances taken. Hence liquids which are insoluble in each other (for example, water and chloride of carbon) present a tension equal to the sum of their individual tensions, and therefore such a mixture boils at a lower temperature than the more volatile liquid (Magnus, Regnault).

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