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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2

Note 337 — Chapter IX · SYSTEMATIC ANALYSIS FOR THE COMMON METAL IONS. THE IONS OF THE ALKALIES AND OF THE ALKALINE EARTHS. ORDER OF PRECIPITATION OF DIFFICULTLY SOLUBLE SALTS WITH A COMMON ION

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To establish equilibrium, prolonged "digesting" is sometimes required. Double salts, solid solutions and mechanical enclosures are liable to interfere with the completeness of such separations by fractional precipitation. Resolution and reprecipitation will then usually effect a sufficiently accurate separation for most purposes. On account of the possibility of such complications, the conditions for a successful separation, within limits such as those described in the text, must in all cases be investigated.

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