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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2

Note 453 — Chapter XII · THE COPPER AND SILVER GROUPS (Continued).—THE THEORY OF COMPLEX IONS

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Potassium cyanide is a powerful reducing agent (see p. 89) and is readily oxidized to potassium cyanate. The action, presumably, takes the following course (see Chapters XIV and XV):

2 Cu2+ + 4 HO− + KNC± → 2 Cu+ + 4 HO− + KNC2+ → 2 Cu+ + 2 HO− + KNCO + H2O.

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