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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2

Note 436 — Chapter XII · THE COPPER AND SILVER GROUPS (Continued).—THE THEORY OF COMPLEX IONS

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The combined concentration of the salts is 0.055 and their degree of ionization may be taken as 87%, the same as the degree of ionization of 0.05 to 0.06 molar KNO3. Then [Cl−] = (0.1 × 1 / 11) × 0.87 = 0.008. [Ag(NH3)2+] = (0.05 × 10 / 11) × 0.87 = 0.04 and x = [Ag+] = 0.00089 (see the method of calculation in the footnote, p. 220).

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