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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2

Note 411 — Chapter XI · THE COPPER AND SILVER GROUPS. PRECIPITATION WITH HYDROGEN SULPHIDE

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This proportion of acid, making the concentration of the hydrogen-ion, approximately, [H+] = 0.2, is used, not because it represents the minimum concentration of the hydrogen-ion, which will prevent the precipitation of zinc sulphide in 0.1 molar zinc sulphate solution, but because it represents the practical conditions under which the precipitation of zinc sulphide is avoided, when the copper and arsenic groups are precipitated in qualitative analysis (see p. 213).

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