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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2

Note 59 — Chapter IV · THE THEORY OF IONIZATION; IONIZATION AND ELECTRICAL CONDUCTIVITY

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Or, on the basis of the accepted molecular weights, abnormally high osmotic pressures, abnormally great lowerings of the freezing-point, raisings of the boiling-point, etc., were obtained. Van 't Hoff, originally, on account of these discrepancies, considered this extension of the Avogadro Hypothesis to hold only for the "majority" of substances in solution, not for all (Arrhenius, loc. cit.). It was considered to have universal application (for dilute solutions) only after Arrhenius had explained the exceptions with the aid of his theory of electrolytic dissociation.

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