Note 56 — CHAP. V.
Reading edition
We will mention one which we do not remember to have seen noticed elsewhere in the case of a disturbance of the equilibrium of heat produced by means purely mechanical, and by a process depending entirely on a certain order and sequence of events, and the operation of known causes. Suppose a quantity of air enclosed in a metallic reservoir, of some good conductor of heat, and suddenly compressed by a piston. After giving time for the heat developed by the condensation to be communicated from the air to the metal which will be thereby more or less raised in temperature above the surrounding atmosphere, let the piston be suddenly retracted and the air restored to its original volume in an instant. The whole apparatus is now precisely in its initial situation, as to the disposition of its material parts, and the whole quantity of heat it contains remains unchanged. But it is evident that the distribution of this heat within it is now very different from what it was before; for the air in its sudden expansion cannot re-absorb in an instant of time all the heat it had parted with to the metal: it will, therefore, have a temperature below that of the general atmosphere, while the metal yet retains one above it. Thus, a subversion of the equilibrium of temperature has been bonâ fide effected. Heat has been driven from the air into the metal, while every thing else remains unchanged.
We have here a means by which, it is evident, heat may be obtained, to any extent, from the air, without fuel. For if, in place of withdrawing the piston and letting the same air expand, within the reservoir, it be allowed to escape so suddenly as not to re-absorb the heat given off, and fresh air be then admitted and the process repeated, any quantity of air may thus be drained of its heat.