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De Re Metallica, Translated from the First Latin Edition of 1556

Note note 24, p. 462 — BOOK X.

Herbert Hoover translation

[24] These nine methods of separating gold from copper are based fundamentally upon the sulphur introduced in each case, whereby the copper is converted into sulphides and separated off as a matte. The various methods are much befogged by the introduction of extraneous ingredients, some of which serve as fluxes, while others would provide metallics in the shape of lead or antimony for collection of the gold, but others would be of no effect, except to increase the matte or slag. Inspection will show that the amount of sulphur introduced in many instances is in so large ratio that unless a good deal of volatilization took place there would be insufficient metallics to collect the gold, if it happened to be in small quantities. In a general way the auriferous button is gradually impoverished in copper [Pg 463]until it is fit for cupellation with lead, except in one case where the final stage is accomplished by amalgamation. The lore of the old refiners was much after the order of that of modern cooks—they treasured and handed down various efficacious recipes, and of those given here most can be found in identical terms in the Probierbüchlein, some editions of which, as mentioned before, were possibly fifty years before De Re Metallica. This knowledge, no doubt, accumulated over long experience; but, so far as we are aware, there is no description of sulphurizing copper for this purpose prior to the publication mentioned.

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